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1. 发明授权

US08153705B2 Silyl esters, their use in binder systems and paint compositions and a process for production thereof 有权
标题翻译：甲硅烷基酯，它们在粘合剂体系和涂料组合物中的用途及其制备方法
公开(公告)号：US08153705B2
公开(公告)日：2012-04-10
申请号：US10555857
申请日：2004-05-07
申请人： Michel Gillard , Marcel Vos
发明人： Michel Gillard , Marcel Vos
IPC分类号： C09D5/16 , C09D5/14 , C08K5/53
CPC分类号： C09D5/1675 , C07F7/188 , C08G77/38 , C09D5/1656 , C09D5/1687
摘要： A hydrolysable paint composition comprising organosilyl esters. The organosilyl esters are used in paint formulations which require hydrolysis of one or more of the components of the paint in use. The organosilylesters of the invention may also independently be film forming. The organosilyl ester may be the ester of a carboxylic, sulphonic or phosphoric acid. The binder systems of the invention can be used in paint compositions, such as self-polishing antifouling paints.
摘要翻译：包含有机甲硅烷基酯的可水解涂料组合物。有机甲硅烷基酯用于需要在使用中水解一种或多种涂料组分的油漆配方中。本发明的有机甲硅烷基酯还可以独立地成膜。有机甲硅烷基酯可以是羧酸，磺酸或磷酸的酯。本发明的粘合剂体系可以用于涂料组合物中，例如自抛光防污涂料。

2. 发明授权

US07902313B2 Process for the preparation of poly(silyl ester)s, and their uses 有权
标题翻译：制备聚（甲硅烷基酯）的方法及其用途
公开(公告)号：US07902313B2
公开(公告)日：2011-03-08
申请号：US10550834
申请日：2004-03-26
申请人： Marcel Vos , Mark Plehiers , Michel Gillard
发明人： Marcel Vos , Mark Plehiers , Michel Gillard
IPC分类号： C08G77/04 , C08G77/06 , C08G77/14 , C08G77/22 , C08G75/00 , C08G79/02
CPC分类号： C08G77/48 , C08G77/38 , C08G77/392 , C08G77/395
摘要： The present invention provides a process for the preparation of poly(silyl ester)s comprising a structural unit of the formula (I) wherein the process comprises the step of reacting a polyacid of formula (II) with a polyacyloxysilyl derivative of formula (III) while removing the formed acid group(s) of formula R7Z(O)OH (IV). R9Z(O)OH (V), and R8Z(O)OH (VI) from the system.
摘要翻译：本发明提供了制备包含式（I）结构单元的聚（甲硅烷基酯）的方法，其中该方法包括使式（II）的多元酸与式（III）的聚酰氧基甲硅烷基衍生物反应的步骤，同时除去形成的式R7Z（O）OH（IV）的酸基团。 R9Z（O）OH（V）和R8Z（O）OH（VI））。

3. 发明申请

US20100136344A1 PRIMER COMPOSITION 审中-公开
标题翻译：主要成分
公开(公告)号：US20100136344A1
公开(公告)日：2010-06-03
申请号：US12451407
申请日：2008-05-09
申请人： Gerard Geels , Michel Gillard , Albert Dirk Broek
发明人： Gerard Geels , Michel Gillard , Albert Dirk Broek
IPC分类号： B32B15/04 , B05D3/06 , B32B9/04 , B32B27/38 , B32B27/40 , B32B27/36 , B32B27/30 , C09D163/00
CPC分类号： C09D5/002 , B05D3/065 , B05D7/54 , B05D7/546 , C08K3/22 , C09D5/08 , C09D7/61 , Y10T428/31511 , Y10T428/31551 , Y10T428/31678 , Y10T428/31786 , Y10T428/31935
摘要： A primer coating composition for a metal substrate is described. The primer has a suitable binder and is characterized in that there is at least one semiconductor photocatalyst dispersed throughout the primer coating composition. A process of coating a metal substrate is also described. The invention extends to the use of a semiconductor photocatalyst as a top-coat to primer adhesion promoter or as a primer to top-coat delamination inhibitor in a primer coating composition.
摘要翻译：描述了用于金属基底的底漆涂料组合物。底漆具有合适的粘合剂，其特征在于，在底漆涂料组合物中分散有至少一种半导体光催化剂。还描述了涂覆金属基底的方法。本发明延伸到使用半导体光催化剂作为底漆粘合促进剂的顶涂层或作为底漆涂料组合物中的顶涂分层抑制剂的底漆。

4. 发明授权

US07122692B2 Process for the preparation of organosilylated carboxylate monomers, and their use in antifouling coatings 有权
标题翻译：用于制备有机甲硅烷基化羧酸酯单体的方法及其在防污涂料中的应用
公开(公告)号：US07122692B2
公开(公告)日：2006-10-17
申请号：US10490126
申请日：2002-09-19
申请人： Mark Plehiers , Marcel Vos , Michel Gillard
发明人： Mark Plehiers , Marcel Vos , Michel Gillard
IPC分类号： C07F7/02 , C07F7/04 , C07F7/08 , C07F7/18
CPC分类号： C07F7/1896
摘要： Process for the preparation of organosilylated carboxylate monomers comprising the step of reacting an acyloxysilane with an unsaturated carboxylic acid, the monomers and their use as comonomer unit in the binder of antifouling coating compositions.
摘要翻译：制备有机甲硅烷基化羧酸酯单体的方法包括使酰氧基硅烷与不饱和羧酸反应的步骤，单体及其作为防污涂料组合物粘合剂中共聚单体的用途。

5. 发明授权

US07118621B2 Organo-functional polysiloxanes 有权
标题翻译：有机官能聚硅氧烷
公开(公告)号：US07118621B2
公开(公告)日：2006-10-10
申请号：US10512903
申请日：2003-04-30
申请人： Roy Gerritsen , Sibel Mill , Michel Gillard , Gerard De Vries
发明人： Roy Gerritsen , Sibel Mill , Michel Gillard , Gerard De Vries
IPC分类号： C09D183/06 , C09D183/07 , C09D183/08 , C07F7/08 , C08G77/18 , C08G77/26 , C08G77/28
CPC分类号： C09D183/04 , C08G77/38 , C08G77/388 , C08G77/42 , C08L63/00 , C08L83/00 , C09D163/00 , Y10T428/31612 , Y10T428/31663
摘要： The present invention relates to an organo-functional polysiloxane of formula (1) wherein each R1 is independently selected from alkyl or aryl radicals, each R2 is independently selected from hydrogen, alkyl or aryl radicals, n is selected so that the molecular weight for the organo-functional polysiloxane is in the range of from 400 to 10,000, R3 is a bivalent radical or —O—W—(X)z is hydroxy or alkoxy, z is 1, 2 or 3 and X is a reactive functional group for reacting with amine radicals and wherein 0 to 90% of —O—R3—(X)z is hydroxy or alkoxy
摘要翻译：本发明涉及式（1）的有机官能聚硅氧烷，其中每个R 1独立地选自烷基或芳基，每个R 2独立地选自氢，烷基或芳基，n选择为使得有机官能聚硅氧烷的分子量在400至10,000的范围内，R 3是二价基团或-OW-（X） Z是羟基或烷氧基，z是1,2或3，X是与胺基反应的反应性官能团，其中0-90％的-OR 3 - （X）Z是羟基或烷氧基

6. 发明申请

US20050131099A1 Paint compositions comprising esters of rosin and process of production thereof 失效
标题翻译：包含松香酯的油漆组合物及其生产方法
公开(公告)号：US20050131099A1
公开(公告)日：2005-06-16
申请号：US10492766
申请日：2002-10-25
申请人： Michel Gillard , Marcel Vos
发明人： Michel Gillard , Marcel Vos
IPC分类号： C09D193/04 , C09D5/16 , C09D7/12 , C09D183/04 , C08K3/00 , C08K5/24
CPC分类号： C09D5/1637 , C09D5/1656
摘要： A paint composition comprising silylesters of rosin. Silylesters of rosin are used in self-polishing antifouling paints alone or in combination with other binder components. A process is also defined for the addition of silyl esters to paint compositions.
摘要翻译：包含松香的硅烷酯的涂料组合物。松香的硅烷酯单独使用在自抛光防污涂料中或与其它粘合剂组分组合使用。还定义了一种用于向涂料组合物中加入甲硅烷基酯的方法。

7. 发明申请

US20050042379A1 Reactive diluents and coatings comprising them 审中-公开
标题翻译：包含它们的活性稀释剂和涂层
公开(公告)号：US20050042379A1
公开(公告)日：2005-02-24
申请号：US10502682
申请日：2003-01-28
申请人： Evarardus Oostveen , John Weijnen , Jacco Haveren , Michel Gillard
发明人： Evarardus Oostveen , John Weijnen , Jacco Haveren , Michel Gillard
IPC分类号： C08K5/103 , C09D7/00 , C09D167/08 , C07H13/02 , B05D3/02
CPC分类号： C09D167/08 , C08K5/103 , C09D7/20 , C08L2666/28
摘要： The invention relates to the use of a fatty acid modified carbohydrate obtainable by reaction of: (i) at least one carbohydrate or an acyl ester thereof; and (ii) a fatty acid, an alkyl ester thereof or a derivative thereof as a reactive diluent in a coating. The invention further relates to a coating which includes at least one binder and, as a reactive diluent, a fatty acid modified carbohydrate obtainable by reaction of (i) at least one carbohydrate or an acyl ester thereof; and (ii) a fatty acid, an alkyl ester thereof or a derivative thereof.
摘要翻译：本发明涉及通过以下反应获得的脂肪酸修饰的碳水化合物的用途：（i）至少一种碳水化合物或其酰基酯; 和（ii）在涂层中作为反应性稀释剂的脂肪酸，其烷基酯或其衍生物。本发明还涉及包含至少一种粘合剂和作为反应性稀释剂的脂肪酸修饰碳水化合物的涂层，所述碳水化合物可通过（i）至少一种碳水化合物或其酰基酯的反应获得; 和（ii）脂肪酸，其烷基酯或其衍生物。

8. 发明授权

US06710117B2 Marine paint compositions 失效
标题翻译：海洋油漆成分
公开(公告)号：US06710117B2
公开(公告)日：2004-03-23
申请号：US10204491
申请日：2003-01-13
申请人： Michel Gillard , Marcel Vos , Jos G. M. Prinsen
发明人： Michel Gillard , Marcel Vos , Jos G. M. Prinsen
IPC分类号： C08L3300
CPC分类号： C09D5/1668 , C08L39/00 , C09D143/00 , C08L2666/04 , C08L2666/28
摘要： Marine paint composition comprising: a first polymer comprising from 20 to 70 wt % of monomer units A of at least one hydrolysable either tin or silicium ester of an olefinically unsaturated carboxylic acid or salt of copper, zinc, calcium of an olefinically unsaturated carboxylic acid, the balance being monomer units C selected from the group consisting of esters of ethylenically unsaturated carboxylic acids with C1-C18 alcohols, styrene, alpha-methyl styrene, vinyl toluenes, and mixtures thereof; a second polymer comprising from 5 to 40 wt % of at least one monomer B selected from the group consisting of the N-vinyl lactam monomers of general formula CH2═CH—NR′″″—CO—R′, the N-vinyl amides of general formula CH2═CH—N—CO—R″, the monomer of general formula CH2═CR′″—COO—R″″—NR′″″—CO—R′, the monomers of general formula CH2═CR′″—COO—R″″—N—CO—R″, 2-pyrrolidone-1-isoprenyl ketone, and mixtures thereof, wherein R′ is a n-alkylidene radical having 2 to 8 carbon atoms, R″ is selected from the group consisting of alkyl, cycloalkyl, aryl, alkylaryl and arylalkyl radicals having a maximum of 18 carbon atoms, R′″ is H or CH3, R″″ is a n-alkylidene radical having from 1 to 8 carbon atoms, R′″″ is H or R″, the balance being monomer units C selected from the group consisting of esters of ethylenically unsaturated carboxylic acids with C1-C18 alcohols, styrene, alpha-methyl styrene, vinyl toluenes, and mixtures thereof; at least one antifoulant; the ratio of the first polymer comprising monomer units A to the second polymer comprising monomer units B being of from 95:5 to 10:90.
摘要翻译：海洋涂料组合物，其包含：包含20至70重量％的至少一种可水解的烯属不饱和羧酸的锡或硅酸酯或烯属不饱和羧酸的铜，锌，钙的盐的单体单元A的第一聚合物，余量为选自烯键式不饱和羧酸与C 1 -C 18醇的酯，苯乙烯，α-甲基苯乙烯，乙烯基甲苯及其混合物的单体单元C; 包含5至40重量％的至少一种单体B的第二聚合物，所述单体选自通式为CH 2 = CH-NR“' - CO-R'的N-乙烯基内酰胺单体，N- 通式为CH2 = CH-N-CO-R“的乙烯基酰胺，通式CH 2 = CR”'-COO-R“' - NR”' - CO-R'的单体，通式CH 2 = CR“' - COO-R”' - N-CO-R“，2-吡咯烷酮-1-异戊二烯基酮及其混合物的单体，其中R'是具有 2至8个碳原子，R“选自具有最多18个碳原子的烷基，环烷基，芳基，烷基芳基和芳基烷基，R”'是H或CH 3，R“'是具有1至8个碳原子的正亚烷基，R“”是H或R“，余量为选自烯键式不饱和羧酸与C 1 -C 18醇的酯，苯乙烯，α-甲基苯乙烯，乙烯基甲苯及其混合物; 至少一种防污剂; 包含单体单元A的第一聚合物与包含单体单元B的第二聚合物的比例为95:5至10:90。

9. 外观设计

USD457855S1 Tire tread 失效
公开(公告)号：USD457855S1
公开(公告)日：2002-05-28
申请号：US29139918
申请日：2001-04-09
申请人： Christian Jean-Marie Roger Bawin , Hervé Marcel Henri Beauguitte , Jean-Michel Gillard
设计人： Christian Jean-Marie Roger Bawin , Hervé Marcel Henri Beauguitte , Jean-Michel Gillard

10. 外观设计

USD425457S Tire tread 失效
公开(公告)号：USD425457S
公开(公告)日：2000-05-23
申请号：US103665
申请日：1999-04-20
申请人： Jean-Michel Gillard , Georges Gaston Feider
设计人： Jean-Michel Gillard , Georges Gaston Feider

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