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1. 发明授权

US07732559B2 Method of making halophthalic acids and halophthalic anhydrides 有权
标题翻译：制备卤代邻苯二甲酸和卤代邻苯二甲酸酐的方法
公开(公告)号：US07732559B2
公开(公告)日：2010-06-08
申请号：US12175502
申请日：2008-07-18
申请人： Robert Edgar Colborn , David Bruce Hall , Peter Alois Koch , Bernd Volker Demuth , Thomas Wessel , Karl Ernst Mack , Prashant Anil Tatake , Uptal Mahendra Vakil , Shyamal Bhaskar Gondkar , John Edward Pace , Kwang Woong Won
发明人： Robert Edgar Colborn , David Bruce Hall , Peter Alois Koch , Bernd Volker Demuth , Thomas Wessel , Karl Ernst Mack , Prashant Anil Tatake , Uptal Mahendra Vakil , Shyamal Bhaskar Gondkar , John Edward Pace , Kwang Woong Won
IPC分类号： C08G73/33
CPC分类号： C07C51/265 , C07C63/68
摘要： A method of preparing a halophthalic acid is disclosed which comprises the steps of contacting in a liquid phase reaction mixture at least one halogen-substituted ortho-xylene with oxygen and acetic acid at a temperature in a range between about 120° C. and about 220° C. in the presence of a catalyst system yielding a product mixture comprising less than 10 percent halogen-substituted ortho-xylene starting material, a halophthalic acid product, and less than about 10,000 ppm halobenzoic acid and less than about 1000 ppm halophthalide by-products based on a total amount of halophthalic acid present in the product mixture. In addition methods for the preparation of halophthalic anhydride, and recovery of high purity acetic acid from an aqueous acetic acid stream comprising HCl, which is generated during the preparation of the halophthalic acid are also disclosed.
摘要翻译：公开了一种制备卤代邻苯二甲酸的方法，其包括以下步骤：在液相反应混合物中使至少一种卤素取代的邻二甲苯与氧和乙酸在约120℃至约220℃的温度下接触在催化剂体系的存在下，产生包含小于10％的卤素取代的邻二甲苯原料，卤代邻苯二甲酸产物和小于约10,000ppm的卤代苯甲酸和小于约1000ppm的卤代苯甲酸副产物的产物混合物，基于产物混合物中存在的卤代邻苯二甲酸的总量的产物。另外还公开了制备卤代邻苯二甲酸酐的方法，以及在制备卤代邻苯二甲酸期间产生的包含HCl的乙酸水溶液中回收高纯度乙酸。

2. 发明授权

US07491855B2 Integrated process for the production of bisphenol A from cumene hydroperoxide 有权
标题翻译：由氢过氧化枯烯生产双酚A的综合工艺
公开(公告)号：US07491855B2
公开(公告)日：2009-02-17
申请号：US10250114
申请日：2003-06-04
申请人： Pramod Shankar Kumbhar , Jegadeesh Thampi , Bharat Singh , John W. Fulmer , Prashant Anil Tatake
发明人： Pramod Shankar Kumbhar , Jegadeesh Thampi , Bharat Singh , John W. Fulmer , Prashant Anil Tatake
IPC分类号： C07C39/16
CPC分类号： C07C37/20 , C07C37/08 , Y02P20/125 , Y02P20/52 , C07C39/04 , C07C39/16
摘要： Use of a specific combination of catalysts for the first and second steps of the process for the conversion of CHP to BPA provides high yields of BPA and low impurity yields, without a requirement for the intermediate purification steps. In the first step, CHP is cleaved in the presence of an acid treated clay such as acid treated Montmorillonite clay to produce phenol and acetone. In the second step, the phenol and acetone produced is reacted, preferably without intermediate purification, in the presence of a cation exchange resin catalyst that includes a cation exchange resin and a mercaptan or mercaptoalkanoic acid promoter to produce BPA.
摘要翻译：用于将CHP转化为BPA的方法的第一和第二步骤的特定的催化剂组合的使用提供了高产率的BPA和低杂质产率，而不需要中间纯化步骤。在第一步中，CHP在酸处理的粘土如酸处理的蒙脱石粘土存在下裂解，以产生苯酚和丙酮。在第二步中，所生产的苯酚和丙酮优选不经中间纯化，在包含阳离子交换树脂和硫醇或巯基链烷酸促进剂以产生BPA的阳离子交换树脂催化剂的存在下反应。

3. 发明授权

US07541489B2 Method of making halophthalic acids and halophthalic anhydrides 有权
标题翻译：制备卤代邻苯二甲酸和卤代邻苯二甲酸酐的方法
公开(公告)号：US07541489B2
公开(公告)日：2009-06-02
申请号：US11170708
申请日：2005-06-29
申请人： Robert Edgar Colborn , David Bruce Hall , Peter Alois Koch , Bernd Volker Demuth , Thomas Wessel , KarlErnst Mack , Prashant Anil Tatake , Utpal Mahendra Vakil , Shyamal Bhaskar Gondkar , John Edward Pace , Kwang Woong Won
发明人： Robert Edgar Colborn , David Bruce Hall , Peter Alois Koch , Bernd Volker Demuth , Thomas Wessel , KarlErnst Mack , Prashant Anil Tatake , Utpal Mahendra Vakil , Shyamal Bhaskar Gondkar , John Edward Pace , Kwang Woong Won
IPC分类号： C07C51/16
CPC分类号： C07C51/265 , C07C63/68
摘要： A method of preparing a halophthalic acid is disclosed which comprises the steps of contacting in a liquid phase reaction mixture at least one halogen-substituted ortho-xylene with oxygen and acetic acid at a temperature in a range between about 120° C. and about 220° C. in the presence of a catalyst system yielding a product mixture comprising less than 10 percent halogen-substituted ortho-xylene starting material, a halophthalic acid product, and less than about 10,000 ppm halobenzoic acid and less than about 1000 ppm halophthalide by-products based on a total amount of halophthalic acid present in the product mixture. In addition methods for the preparation of halophthalic anhydride, and recovery of high purity acetic acid from an aqueous acetic acid stream comprising HCl, which is generated during the preparation of the halophthalic acid are also disclosed.
摘要翻译：公开了一种制备卤代邻苯二甲酸的方法，其包括以下步骤：在液相反应混合物中使至少一种卤素取代的邻二甲苯与氧和乙酸在约120℃至约220℃的温度下接触在催化剂体系的存在下，产生包含小于10％的卤素取代的邻二甲苯原料，卤代邻苯二甲酸产物和小于约10,000ppm的卤代苯甲酸和小于约1000ppm的卤代苯甲酸副产物的产物混合物，基于产物混合物中存在的卤代邻苯二甲酸的总量的产物。另外还公开了制备卤代邻苯二甲酸酐的方法，以及在制备卤代邻苯二甲酸期间产生的包含HCl的乙酸水溶液中回收高纯度乙酸。

4. 发明授权

US07109385B2 Process for producing phenol 有权
标题翻译：苯酚生产工艺
公开(公告)号：US07109385B2
公开(公告)日：2006-09-19
申请号：US11092078
申请日：2005-03-29
申请人： Prashant Anil Tatake , Pramod Shankar Kumbhar , Bharat Singh , John William Fulmer , Sabyasachi Mandal , Arun N. Kumar , Rupesh Pawar
发明人： Prashant Anil Tatake , Pramod Shankar Kumbhar , Bharat Singh , John William Fulmer , Sabyasachi Mandal , Arun N. Kumar , Rupesh Pawar
IPC分类号： C07C37/08
CPC分类号： C07C37/08 , C07C39/04
摘要： A process for producing a phenol product generally comprises a first step comprising reacting in a first reactor a feed stream comprising cumene hydroperoxide and water with an acid catalyst to produce an effluent comprising the phenol product, acetone, and at least 1% by weight residual cumene hydroperoxide, and a second step comprising passing the effluent into a second reactor and decomposing the residual cumene hydroperoxide, wherein during said process the ratio of phenol to acetone is maintained at a molar ratio of greater than 1:1, and wherein the water in each of the first and second steps is present in an amount more than 0 and less than or equal to 5 weight percent based on the total weight of the feed stream or effluent, and wherein the process is continuous.
摘要翻译：一种生产酚产物的方法通常包括第一步骤，包括在第一反应器中使含有氢过氧化枯烯和水的进料流与酸催化剂反应以产生包含苯酚产物，丙酮和至少1重量％的残余枯烯的流出物氢过氧化物，第二步骤包括使流出物流入第二反应器并分解残留的氢过氧化枯烯，其中在所述方法期间，苯酚与丙酮的比例保持在大于1:1的摩尔比，并且其中每个基于进料流或流出物的总重量，第一步和第二步的存在量大于0且小于或等于5重量％，并且其中该方法是连续的。

5. 发明申请

US20080275211A1 METHOD OF MAKING HALOPHTHALIC ACIDS AND HALOPHTHALIC ANHYDRIDES 有权
标题翻译：制备半胱氨酸和半胱氨酸的方法
公开(公告)号：US20080275211A1
公开(公告)日：2008-11-06
申请号：US12175502
申请日：2008-07-18
申请人： Robert Edgar Colborn , David Bruce Hall , Peter Alois Koch , Bernd Volker Demuth , Thomas Wessel , Karl Ernst Mack , Prashant Anil Tatake , Utpal Mahendra Vakil , Shyamal Bhaskar Gondkar , John Edward Pace , Kwang Woong Won
发明人： Robert Edgar Colborn , David Bruce Hall , Peter Alois Koch , Bernd Volker Demuth , Thomas Wessel , Karl Ernst Mack , Prashant Anil Tatake , Utpal Mahendra Vakil , Shyamal Bhaskar Gondkar , John Edward Pace , Kwang Woong Won
IPC分类号： C08G73/10 , C07D307/77
CPC分类号： C07C51/265 , C07C63/68
摘要： A method of preparing a halophthalic acid is disclosed which comprises the steps of contacting in a liquid phase reaction mixture at least one halogen-substituted ortho-xylene with oxygen and acetic acid at a temperature in a range between about 120° C. and about 220° C. in the presence of a catalyst system yielding a product mixture comprising less than 10 percent halogen-substituted ortho-xylene starting material, a halophthalic acid product, and less than about 10,000 ppm halobenzoic acid and less than about 1000 ppm halophthalide by-products based on a total amount of halophthalic acid present in the product mixture. In addition methods for the preparation of halophthalic anhydride, and recovery of high purity acetic acid from an aqueous acetic acid stream comprising HCl, which is generated during the preparation of the halophthalic acid are also disclosed.
摘要翻译：公开了一种制备卤代邻苯二甲酸的方法，其包括以下步骤：在液相反应混合物中使至少一种卤素取代的邻二甲苯与氧和乙酸在约120℃至约220℃的温度下接触在催化剂体系的存在下，产生包含小于10％的卤素取代的邻二甲苯原料，卤代邻苯二甲酸产物和小于约10,000ppm的卤代苯甲酸和小于约1000ppm的卤代苯甲酸副产物的产物混合物，基于产物混合物中存在的卤代邻苯二甲酸的总量的产物。另外还公开了制备卤代邻苯二甲酸酐的方法，以及在制备卤代邻苯二甲酸期间产生的包含HCl的乙酸水溶液中回收高纯度乙酸。

6. 发明授权

US07154010B2 Integrated process for the production of bisphenol A from cumene hydroperoxide 有权
标题翻译：由氢过氧化枯烯生产双酚A的综合工艺
公开(公告)号：US07154010B2
公开(公告)日：2006-12-26
申请号：US10250107
申请日：2003-06-04
申请人： Pramod Shankar Kumbhar , Jegadeesh Thampi , Bharat Singh , John W. Fulmer , Prashant Anil Tatake
发明人： Pramod Shankar Kumbhar , Jegadeesh Thampi , Bharat Singh , John W. Fulmer , Prashant Anil Tatake
IPC分类号： C07C36/16
CPC分类号： C07C37/20 , C07C37/08 , C07C45/53 , Y02P20/125 , Y02P20/52 , C07C39/04 , C07C39/16 , C07C49/08
摘要： Use of a specific combination of catalysts for the first and second steps of the process for the conversion of CHP to BPA provides high yields of BPA and low impurity yields, without a requirement for the intermediate purification steps. In the first step, CHP is cleaved in the presence of a sulfated metal oxide catalyst such as sulfated Zirconia to produce phenol and acetone. In the second step, the phenol and acetone produced is reacted, preferably without intermediate purification, in the presence of a cation exchange resin catalyst that includes a cation exchange resin and a mercaptan or mercaptoalkanoic acid promoter to produce BPA.
摘要翻译：用于将CHP转化为BPA的方法的第一和第二步骤的特定的催化剂组合的使用提供了高产率的BPA和低杂质产率，而不需要中间纯化步骤。在第一步中，CHP在硫酸化金属氧化物催化剂如硫酸化氧化锆存在下裂解，生成苯酚和丙酮。在第二步中，所生产的苯酚和丙酮优选不经中间纯化，在包含阳离子交换树脂和硫醇或巯基链烷酸促进剂以产生BPA的阳离子交换树脂催化剂的存在下反应。

7. 发明授权

US06486365B1 Production and purification of phenol: hydroxyacetone removal by hydrotalcite 有权
标题翻译：苯酚的生产和纯化：通过水滑石除去羟基丙酮
公开(公告)号：US06486365B1
公开(公告)日：2002-11-26
申请号：US10063258
申请日：2002-04-04
申请人： John W. Fulmer , Bharat Singh , Pramod Kumbhar , Prashant Anil Tatake , Umesh Hasyagar
发明人： John W. Fulmer , Bharat Singh , Pramod Kumbhar , Prashant Anil Tatake , Umesh Hasyagar
IPC分类号： C07C3708
CPC分类号： C07C37/86 , C07C2521/10 , C07C39/04
摘要： A process for converting carbonyl-type impurities contained in a phenolic solvent to high-boiling derivatives is provided by contacting the phenolic solvent with a hydrotalcite-type material (HTM). The phenol can be separated from the high-boiling derivatives using conventional separation techniques, such as distillation, so the invention also provides a process for separating carbonyl-type impurities, such as hydroxyacetone (HA), from a phenolic solvent. The process can be applied in the conventional industrial process for converting cumene to phenol to remove carbonyl-type impurities from the phenol product. A process and a facility for producing purified phenol by converting cumene to phenol are provided. In the conversion of cumene to phenol, the phenol often contains carbonyl-type impurities. The phenol and carbonyl-type impurities are reacted in the presence of an HTM to produce phenol and high-boiling derivatives. The phenol may be further purified using conventional separation techniques, such as distillation, to remove the high-boiling derivatives.
摘要翻译：通过使酚类溶剂与水滑石类材料（HTM）接触来提供将酚类溶剂中所含的羰基型杂质转化成高沸点衍生物的方法。苯酚可以使用常规的分离技术如蒸馏从高沸点衍生物中分离，因此本发明还提供了从酚类溶剂中分离羰基型杂质如羟基丙酮（HA）的方法。该方法可用于将异丙基苯转化为苯酚以从苯酚产物中除去羰基型杂质的常规工业方法。提供了通过将异丙基苯转化成苯酚来生产纯化苯酚的方法和设备。在异丙苯转化为苯酚时，苯酚常含有羰基型杂质。苯酚和羰基型杂质在HTM存在下反应生成苯酚和高沸点衍生物。可以使用常规分离技术如蒸馏进一步纯化苯酚，以除去高沸点衍生物。

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