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1. 发明授权

US07732559B2 Method of making halophthalic acids and halophthalic anhydrides 有权
标题翻译：制备卤代邻苯二甲酸和卤代邻苯二甲酸酐的方法
公开(公告)号：US07732559B2
公开(公告)日：2010-06-08
申请号：US12175502
申请日：2008-07-18
申请人： Robert Edgar Colborn , David Bruce Hall , Peter Alois Koch , Bernd Volker Demuth , Thomas Wessel , Karl Ernst Mack , Prashant Anil Tatake , Uptal Mahendra Vakil , Shyamal Bhaskar Gondkar , John Edward Pace , Kwang Woong Won
发明人： Robert Edgar Colborn , David Bruce Hall , Peter Alois Koch , Bernd Volker Demuth , Thomas Wessel , Karl Ernst Mack , Prashant Anil Tatake , Uptal Mahendra Vakil , Shyamal Bhaskar Gondkar , John Edward Pace , Kwang Woong Won
IPC分类号： C08G73/33
CPC分类号： C07C51/265 , C07C63/68
摘要： A method of preparing a halophthalic acid is disclosed which comprises the steps of contacting in a liquid phase reaction mixture at least one halogen-substituted ortho-xylene with oxygen and acetic acid at a temperature in a range between about 120° C. and about 220° C. in the presence of a catalyst system yielding a product mixture comprising less than 10 percent halogen-substituted ortho-xylene starting material, a halophthalic acid product, and less than about 10,000 ppm halobenzoic acid and less than about 1000 ppm halophthalide by-products based on a total amount of halophthalic acid present in the product mixture. In addition methods for the preparation of halophthalic anhydride, and recovery of high purity acetic acid from an aqueous acetic acid stream comprising HCl, which is generated during the preparation of the halophthalic acid are also disclosed.
摘要翻译：公开了一种制备卤代邻苯二甲酸的方法，其包括以下步骤：在液相反应混合物中使至少一种卤素取代的邻二甲苯与氧和乙酸在约120℃至约220℃的温度下接触在催化剂体系的存在下，产生包含小于10％的卤素取代的邻二甲苯原料，卤代邻苯二甲酸产物和小于约10,000ppm的卤代苯甲酸和小于约1000ppm的卤代苯甲酸副产物的产物混合物，基于产物混合物中存在的卤代邻苯二甲酸的总量的产物。另外还公开了制备卤代邻苯二甲酸酐的方法，以及在制备卤代邻苯二甲酸期间产生的包含HCl的乙酸水溶液中回收高纯度乙酸。

2. 发明申请

US20080275211A1 METHOD OF MAKING HALOPHTHALIC ACIDS AND HALOPHTHALIC ANHYDRIDES 有权
标题翻译：制备半胱氨酸和半胱氨酸的方法
公开(公告)号：US20080275211A1
公开(公告)日：2008-11-06
申请号：US12175502
申请日：2008-07-18
申请人： Robert Edgar Colborn , David Bruce Hall , Peter Alois Koch , Bernd Volker Demuth , Thomas Wessel , Karl Ernst Mack , Prashant Anil Tatake , Utpal Mahendra Vakil , Shyamal Bhaskar Gondkar , John Edward Pace , Kwang Woong Won
发明人： Robert Edgar Colborn , David Bruce Hall , Peter Alois Koch , Bernd Volker Demuth , Thomas Wessel , Karl Ernst Mack , Prashant Anil Tatake , Utpal Mahendra Vakil , Shyamal Bhaskar Gondkar , John Edward Pace , Kwang Woong Won
IPC分类号： C08G73/10 , C07D307/77
CPC分类号： C07C51/265 , C07C63/68
摘要： A method of preparing a halophthalic acid is disclosed which comprises the steps of contacting in a liquid phase reaction mixture at least one halogen-substituted ortho-xylene with oxygen and acetic acid at a temperature in a range between about 120° C. and about 220° C. in the presence of a catalyst system yielding a product mixture comprising less than 10 percent halogen-substituted ortho-xylene starting material, a halophthalic acid product, and less than about 10,000 ppm halobenzoic acid and less than about 1000 ppm halophthalide by-products based on a total amount of halophthalic acid present in the product mixture. In addition methods for the preparation of halophthalic anhydride, and recovery of high purity acetic acid from an aqueous acetic acid stream comprising HCl, which is generated during the preparation of the halophthalic acid are also disclosed.
摘要翻译：公开了一种制备卤代邻苯二甲酸的方法，其包括以下步骤：在液相反应混合物中使至少一种卤素取代的邻二甲苯与氧和乙酸在约120℃至约220℃的温度下接触在催化剂体系的存在下，产生包含小于10％的卤素取代的邻二甲苯原料，卤代邻苯二甲酸产物和小于约10,000ppm的卤代苯甲酸和小于约1000ppm的卤代苯甲酸副产物的产物混合物，基于产物混合物中存在的卤代邻苯二甲酸的总量的产物。另外还公开了制备卤代邻苯二甲酸酐的方法，以及在制备卤代邻苯二甲酸期间产生的包含HCl的乙酸水溶液中回收高纯度乙酸。

3. 发明授权

US07541489B2 Method of making halophthalic acids and halophthalic anhydrides 有权
标题翻译：制备卤代邻苯二甲酸和卤代邻苯二甲酸酐的方法
公开(公告)号：US07541489B2
公开(公告)日：2009-06-02
申请号：US11170708
申请日：2005-06-29
申请人： Robert Edgar Colborn , David Bruce Hall , Peter Alois Koch , Bernd Volker Demuth , Thomas Wessel , KarlErnst Mack , Prashant Anil Tatake , Utpal Mahendra Vakil , Shyamal Bhaskar Gondkar , John Edward Pace , Kwang Woong Won
发明人： Robert Edgar Colborn , David Bruce Hall , Peter Alois Koch , Bernd Volker Demuth , Thomas Wessel , KarlErnst Mack , Prashant Anil Tatake , Utpal Mahendra Vakil , Shyamal Bhaskar Gondkar , John Edward Pace , Kwang Woong Won
IPC分类号： C07C51/16
CPC分类号： C07C51/265 , C07C63/68
摘要： A method of preparing a halophthalic acid is disclosed which comprises the steps of contacting in a liquid phase reaction mixture at least one halogen-substituted ortho-xylene with oxygen and acetic acid at a temperature in a range between about 120° C. and about 220° C. in the presence of a catalyst system yielding a product mixture comprising less than 10 percent halogen-substituted ortho-xylene starting material, a halophthalic acid product, and less than about 10,000 ppm halobenzoic acid and less than about 1000 ppm halophthalide by-products based on a total amount of halophthalic acid present in the product mixture. In addition methods for the preparation of halophthalic anhydride, and recovery of high purity acetic acid from an aqueous acetic acid stream comprising HCl, which is generated during the preparation of the halophthalic acid are also disclosed.
摘要翻译：公开了一种制备卤代邻苯二甲酸的方法，其包括以下步骤：在液相反应混合物中使至少一种卤素取代的邻二甲苯与氧和乙酸在约120℃至约220℃的温度下接触在催化剂体系的存在下，产生包含小于10％的卤素取代的邻二甲苯原料，卤代邻苯二甲酸产物和小于约10,000ppm的卤代苯甲酸和小于约1000ppm的卤代苯甲酸副产物的产物混合物，基于产物混合物中存在的卤代邻苯二甲酸的总量的产物。另外还公开了制备卤代邻苯二甲酸酐的方法，以及在制备卤代邻苯二甲酸期间产生的包含HCl的乙酸水溶液中回收高纯度乙酸。

4. 发明授权

US06649773B2 Method for the manufacture of halophthalic acids and anhydrides 有权
标题翻译：卤代邻苯二甲酸和酸酐的制备方法
公开(公告)号：US06649773B2
公开(公告)日：2003-11-18
申请号：US10063114
申请日：2002-03-22
申请人： Robert Edgar Colborn , David Bruce Hall , Peter Koch , Gerald Oeckel
发明人： Robert Edgar Colborn , David Bruce Hall , Peter Koch , Gerald Oeckel
IPC分类号： C07D20948
CPC分类号： C07C51/265 , C07C63/68
摘要： A method for the manufacture of halophthalic acid by liquid phase oxidation of halo-ortho-xylene is disclosed. The halophthalic acid may be dehydrated to form halophthalic anhydride which is useful in the synthesis of polyetherimide.
摘要翻译：公开了通过卤代邻二甲苯的液相氧化制备卤代邻苯二甲酸的方法。卤代邻苯二甲酸可以被脱水以形成可用于合成聚醚酰亚胺的卤代邻苯二甲酸酐。

5. 发明授权

US06657067B2 Method for the manufacture of chlorophthalic anhydride 有权
标题翻译：氯邻苯二甲酸酐的制备方法
公开(公告)号：US06657067B2
公开(公告)日：2003-12-02
申请号：US10063112
申请日：2002-03-22
申请人： Robert Edgar Colborn , David Bruce Hall , Peter Koch , Gerald Oeckel
发明人： Robert Edgar Colborn , David Bruce Hall , Peter Koch , Gerald Oeckel
IPC分类号： C07D49302
CPC分类号： C07C51/265 , C07C63/68
摘要： A method for the manufacture of chlorophthalic acid by liquid phase oxidation of chloro-ortho-xylene is disclosed. The chlorophthalic acid may be dehydrated to form chlorophthalic anhydride which is useful in the synthesis of polyetherimide.
摘要翻译：公开了通过氯代邻二甲苯的液相氧化制备氯代邻苯二甲酸的方法。氯代邻苯二甲酸可以脱水形成氯代邻苯二甲酸酐，其可用于聚醚酰亚胺的合成。

6. 发明授权

US06657068B2 Liquid phase oxidation of halogenated ortho-xylenes 有权
标题翻译：卤化邻二甲苯的液相氧化
公开(公告)号：US06657068B2
公开(公告)日：2003-12-02
申请号：US10063113
申请日：2002-03-22
申请人： Robert Edgar Colborn , David Bruce Hall , Peter Koch , Gerald Oeckel
发明人： Robert Edgar Colborn , David Bruce Hall , Peter Koch , Gerald Oeckel
IPC分类号： C07D20948
CPC分类号： C07C51/265 , C07C51/56 , C07C63/68
摘要： A method for the manufacture of halophthalic acid by liquid phase oxidation of halo-ortho-xylene is disclosed. The halophthalic acid may be dehydrated to form halophthalic anhydride which is useful in the synthesis of polyetherimide.
摘要翻译：公开了通过卤代邻二甲苯的液相氧化制备卤代邻苯二甲酸的方法。卤代邻苯二甲酸可以被脱水以形成可用于合成聚醚酰亚胺的卤代邻苯二甲酸酐。

7. 发明授权

US08278383B2 Methods of preparing polymer-organoclay composites and articles derived therefrom 有权
标题翻译：制备聚合物 - 有机粘土复合材料及其衍生物的方法
公开(公告)号：US08278383B2
公开(公告)日：2012-10-02
申请号：US13430801
申请日：2012-03-27
申请人： Kwok Pong Chan , Sarah Elizabeth Genovese , Erik C. Hagberg , David Bruce Hall , John Lester Maxam , Tara J. Mullen , Roy Ray Odle , Albert Santo Stella , James Mitchell White
发明人： Kwok Pong Chan , Sarah Elizabeth Genovese , Erik C. Hagberg , David Bruce Hall , John Lester Maxam , Tara J. Mullen , Roy Ray Odle , Albert Santo Stella , James Mitchell White
IPC分类号： C08K9/04 , C08K3/34
CPC分类号： C08F2/44
摘要： A method for preparing a polymer-organoclay composite composition comprises combining a solvent and an unexfoliated organoclay to provide a first mixture, wherein the unexfoliated organoclay comprises alternating inorganic silicate layers and organic layers, and has an initial spacing between the silicate layers; exposing the first mixture to an energized condition of a sufficient intensity and duration to increase the initial spacing of the inorganic silicate layers, to provide a second mixture; contacting the second mixture with a polymer composition so that the polymer composition fills at least one region located between at least one pair of silicate layers, wherein the polymer composition is at least partially soluble in the solvent; and removing at least a portion of the solvent from the second mixture, wherein the inorganic silicate layers remain separated by the polymer after removal of the solvent.
摘要翻译：一种制备聚合物 - 有机粘土复合材料组合物的方法，包括将溶剂和未剥离的有机粘土组合以提供第一混合物，其中未剥离的有机粘土包含交替的无机硅酸盐层和有机层，并且在硅酸盐层之间具有初始间隔; 将第一混合物暴露于足够强度和持续时间的通电状态以增加无机硅酸盐层的初始间隔，以提供第二混合物; 使所述第二混合物与聚合物组合物接触，使得所述聚合物组合物填充位于至少一对硅酸盐层之间的至少一个区域，其中所述聚合物组合物至少部分地可溶于所述溶剂中; 以及从所述第二混合物中除去至少一部分所述溶剂，其中在去除所述溶剂之后，所述无机硅酸盐层保持被所述聚合物分离。

8. 发明申请

US20110212314A1 METHODS OF PREPARING POLYMER-ORGANOCLAY COMPOSITES AND ARTICLES DERIVED THEREFROM 有权
标题翻译：制备聚合物 - 组织复合材料的方法及其衍生物
公开(公告)号：US20110212314A1
公开(公告)日：2011-09-01
申请号：US13044866
申请日：2011-03-10
申请人： Kwok Pong Chan , Sarah Elizabeth Genovese , Erik C. Hagberg , David Bruce Hall , John Lester Maxam , Tara J. Mullen , Roy Ray Odle , Albert Santo Stella , James Mitchell White
发明人： Kwok Pong Chan , Sarah Elizabeth Genovese , Erik C. Hagberg , David Bruce Hall , John Lester Maxam , Tara J. Mullen , Roy Ray Odle , Albert Santo Stella , James Mitchell White
IPC分类号： B32B5/00 , C08J3/28 , C08K5/50 , C08K5/3417
CPC分类号： C08F2/44
摘要： A method for preparing a polymer-organoclay composite composition comprises combining a solvent and an unexfoliated organoclay to provide a first mixture, wherein the unexfoliated organoclay comprises alternating inorganic silicate layers and organic layers, and has an initial spacing between the silicate layers; exposing the first mixture to an energized condition of a sufficient intensity and duration to increase the initial spacing of the inorganic silicate layers, to provide a second mixture; contacting the second mixture with a polymer composition so that the polymer composition fills at least one region located between at least one pair of silicate layers, wherein the polymer composition is at least partially soluble in the solvent; and removing at least a portion of the solvent from the second mixture, wherein the inorganic silicate layers remain separated by the polymer after removal of the solvent.
摘要翻译：一种制备聚合物 - 有机粘土复合材料组合物的方法，包括将溶剂和未剥离的有机粘土组合以提供第一混合物，其中未剥离的有机粘土包含交替的无机硅酸盐层和有机层，并且在硅酸盐层之间具有初始间隔; 将第一混合物暴露于足够强度和持续时间的通电状态以增加无机硅酸盐层的初始间隔，以提供第二混合物; 使所述第二混合物与聚合物组合物接触，使得所述聚合物组合物填充位于至少一对硅酸盐层之间的至少一个区域，其中所述聚合物组合物至少部分地可溶于所述溶剂中; 以及从所述第二混合物中除去至少一部分所述溶剂，其中在去除所述溶剂之后，所述无机硅酸盐层保持被所述聚合物分离。

9. 发明授权

US07999024B2 Method of purifying a polymer 有权
标题翻译：纯化聚合物的方法
公开(公告)号：US07999024B2
公开(公告)日：2011-08-16
申请号：US11766937
申请日：2007-06-22
申请人： David Bruce Hall
发明人： David Bruce Hall
IPC分类号： C08G73/10 , C08F6/16
CPC分类号： C08F6/02 , C08G65/46 , C08G73/1046 , C08G73/105 , C08G73/1064 , C08G75/20 , C08G75/23 , C08L2205/05
摘要： A method for purifying a polymer comprising providing a first mixture comprising at least one solvent and at least one polymeric material, diluting the first mixture with veratrole to produce a second mixture in which the polymeric material is substantially dissolved at a temperature less than 100° C., performing at least one step selected from (i) contacting the second mixture with an aqueous wash solution, and (ii) filtering the second mixture.
摘要翻译：一种纯化聚合物的方法，包括提供包含至少一种溶剂和至少一种聚合物材料的第一混合物，将第一混合物用藜芦醇稀释以产生其中聚合物材料在低于100℃的温度下基本上溶解的第二混合物执行至少一个步骤，其选自（i）使第二混合物与水性洗涤溶液接触，和（ii）过滤第二混合物。

10. 发明申请

US20080319210A1 METHOD FOR PURIFYING DIANHYDRIDES 有权
标题翻译：纯化二氢呋喃的方法
公开(公告)号：US20080319210A1
公开(公告)日：2008-12-25
申请号：US12202529
申请日：2008-09-02
申请人： Albert Santo Stella , David Bruce Hall
发明人： Albert Santo Stella , David Bruce Hall
IPC分类号： C07D405/12
CPC分类号： C07D407/12
摘要： A method for purifying dianhydrides is provided. In one aspect, purified oxybisphthalic anhydrides, intermediates useful in the preparation of polyetherimides are provided. In one embodiment, a first solution containing a dianhydride compound, a solvent, and a phase transfer catalyst is contacted with a solid inorganic adsorbent material having a total pore volume of about 0.5 milliliters/gram or greater and a cumulative pore volume distribution of about 20 percent or greater of particles having a pore diameter in a range between about 3 nanometers and about 20 nanometers. The solution containing the dianhydride compound is then separated from the solid inorganic adsorbent material to provide a purified dianhydride compound which is substantially free of the phase transfer catalyst. The purification technique is especially valuable for preparing high purity oxybisphthalic anhydrides, such as 4,4′-oxybisphthalic anhydride (4,4′-ODPA), which are substantially free of residual phase transfer catalyst.
摘要翻译：提供了一种纯化二酸酐的方法。在一个方面，提供了纯的氧化双邻苯二甲酸酐，可用于制备聚醚酰亚胺的中间体。在一个实施方案中，将含有二酐化合物，溶剂和相转移催化剂的第一溶液与总孔体积为约0.5毫升/克或更大并且累积孔体积分布约为20的固体无机吸附材料接触百分比或更大的具有在约3纳米和约20纳米之间的孔径的颗粒。然后将含有二酐化合物的溶液与固体无机吸附材料分离，得到基本上不含相转移催化剂的纯化二酐化合物。纯化技术对于制备基本上不含残余相转移催化剂的4,4'-氧双苯二甲酸酐（4,4'-ODPA）的高纯度羟基双苯酐具有特别的价值。

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