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1. 发明申请

US20090306309A1 POLYPHENYLENE SULFIDE RESIN COMPOSITION 有权
标题翻译：聚苯乙烯树脂组合物
公开(公告)号：US20090306309A1
公开(公告)日：2009-12-10
申请号：US12542942
申请日：2009-08-18
申请人： Atsushi Ishio , Kei Saitoh , Sadayuki Kobayashi
发明人： Atsushi Ishio , Kei Saitoh , Sadayuki Kobayashi
IPC分类号： C08L77/06
CPC分类号： C08L81/02 , C08L77/00 , C08L2666/20
摘要： A process for producing a polyphenylene sulfide resin composition includes melt-kneading about 99 to about 60 wt % of a polyphenylene sulfide resin (a) and about 1 to about 40 wt % of a polyamide resin (b), and about 0.1 to 10 parts by weight of a compatibilizing agent (c) per 100 parts by weight in total of the polyphenylene sulfide resin (a) and the polyamide resin (b), using a double screw extruder with two or more kneading portions at a temperature of the range from a melting peak temperature of the polyphenylene sulfide resin+10° C. to a melting peak temperature of the polyphenylene sulfide resin+70° C., wherein the polyamide resin (b) is excluded nylon 46 and has a relative viscosity of 1.5 or more measuring in concentrated sulfuric acid at a concentration of 1% and at 25° C., wherein the compatibilizing agent (c) is a compound having one or more types of groups selected from epoxy groups, amino group and isocyanate group, and wherein the resin composition has a morphology that the polyphenylene sulfide resin (a) in the resin composition forms a sea phase while the polyamide resin (b) in the resin composition forms an island phase, and the number average dispersed particle size of the polyamide resin (b) is kept at less than about 500 nm after the resin composition is melted and allowed to reside at 300° C. for 30 minutes.
摘要翻译：聚苯硫醚树脂组合物的制造方法包括熔融捏合约99〜约60重量％的聚苯硫醚树脂（a）和约1〜约40重量％的聚酰胺树脂（b），以及约0.1〜10重量份的相容剂（c）相对于聚苯硫醚树脂（a）和聚酰胺树脂（b）的总计100重量份，使用具有两个或更多个捏合部分的双螺杆挤出机，温度范围为聚苯硫醚树脂的熔融峰值温度+10℃至聚苯硫醚树脂的熔融峰温度+ 70℃，其中聚酰胺树脂（b）不含尼龙46，相对粘度为1.5以上在浓硫酸浓度为1％和25℃下测量，其中相容剂（c）是具有一个或多个选自环氧基，氨基和异氰酸酯基团的基团的化合物，并且其中树脂组成具有形态学树脂组合物中的聚苯硫醚树脂（a）形成海相，而树脂组合物中的聚酰胺树脂（b）形成岛相，并且聚酰胺树脂（b）的数均分散粒径保持在较小在树脂组合物熔融之后约为500nm，并在300℃下放置30分钟。

2. 发明授权

US08076423B2 Polyphenylene sulfide resin composition 有权
标题翻译：聚苯硫醚树脂组合物
公开(公告)号：US08076423B2
公开(公告)日：2011-12-13
申请号：US12542942
申请日：2009-08-18
申请人： Atsushi Ishio , Kei Saitoh , Sadayuki Kobayashi
发明人： Atsushi Ishio , Kei Saitoh , Sadayuki Kobayashi
IPC分类号： C08G69/46 , C08L83/16
CPC分类号： C08L81/02 , C08L77/00 , C08L2666/20
摘要： A process for producing a polyphenylene sulfide resin composition includes melt-kneading about 99 to about 60 wt % of a polyphenylene sulfide resin (a) and about 1 to about 40 wt % of a polyamide resin (b), and about 0.1 to 10 parts by weight of a compatibilizing agent (c) per 100 parts by weight in total of the polyphenylene sulfide resin (a) and the polyamide resin (b), using a double screw extruder with two or more kneading portions at a temperature of the range from a melting peak temperature of the polyphenylene sulfide resin+10° C. to a melting peak temperature of the polyphenylene sulfide resin+70° C., wherein the polyamide resin (b) is excluded nylon 46 and has a relative viscosity of 1.5 or more measuring in concentrated sulfuric acid at a concentration of 1% and at 25° C., wherein the compatibilizing agent (c) is a compound having one or more types of groups selected from epoxy groups, amino group and isocyanate group, and wherein the resin composition has a morphology that the polyphenylene sulfide resin (a) in the resin composition forms a sea phase while the polyamide resin (b) in the resin composition forms an island phase, and the number average dispersed particle size of the polyamide resin (b) is kept at less than about 500 nm after the resin composition is melted and allowed to reside at 300° C. for 30 minutes.
摘要翻译：聚苯硫醚树脂组合物的制造方法包括熔融捏合约99〜约60重量％的聚苯硫醚树脂（a）和约1〜约40重量％的聚酰胺树脂（b），以及约0.1〜10重量份的相容剂（c）相对于聚苯硫醚树脂（a）和聚酰胺树脂（b）的总计100重量份，使用具有两个或更多个捏合部分的双螺杆挤出机，温度范围为聚苯硫醚树脂的熔融峰值温度+10℃至聚苯硫醚树脂的熔融峰温度+ 70℃，其中聚酰胺树脂（b）不含尼龙46，相对粘度为1.5以上在浓硫酸浓度为1％和25℃下测量，其中相容剂（c）是具有一个或多个选自环氧基，氨基和异氰酸酯基团的基团的化合物，并且其中树脂组成具有形态学树脂组合物中的聚苯硫醚树脂（a）形成海相，而树脂组合物中的聚酰胺树脂（b）形成岛相，并且聚酰胺树脂（b）的数均分散粒径保持在较小在树脂组合物熔融之后约为500nm，并在300℃下放置30分钟。

3. 发明申请

US20070265375A1 Polyphenylene sulfide resin composition 审中-公开
标题翻译：聚苯硫醚树脂组合物
公开(公告)号：US20070265375A1
公开(公告)日：2007-11-15
申请号：US11662907
申请日：2005-07-08
申请人： Atsushi Ishio , Kei Saitoh , Sadayuki Kobayashi
发明人： Atsushi Ishio , Kei Saitoh , Sadayuki Kobayashi
IPC分类号： C08L81/02 , C08L77/00
CPC分类号： C08L81/02 , C08L77/00 , C08L2666/20
摘要： A polyphenylene sulfide resin composition including 99 to 60 wt % of a polyphenylene sulfide resin (a) and 1 to 40 wt % of a polyamide resin (b), wherein the polyphenylene sulfide resin (a) forms a sea phase while the polyamide resin (b) forms an island phase, and that the number average dispersed particle size of the polyamide resin (b) is less than 500 nm; and a polyphenylene sulfide resin composition, wherein a compound having one or more types of groups selected from epoxy group, amino group and isocyanate group is added by 0.1 to 10 parts by weight per 100 parts by weight in total of the polyphenylene sulfide resin (a) and the polyamide resin (b), as a compatibilizing agent (c).
摘要翻译： 1.一种聚苯硫醚树脂组合物，其中，所述聚苯硫醚树脂（a）为99〜60重量％，聚酰胺树脂（b）为1〜40重量％，聚酰胺树脂（a） b）形成岛相，并且聚酰胺树脂（b）的数均分散粒径小于500nm; 和聚苯硫醚树脂组合物，其中具有一个或多个选自环氧基，氨基和异氰酸酯基团的基团的化合物的加入量相对于聚苯硫醚树脂的总量为100重量份（a ）和聚酰胺树脂（b）作为相容剂（c）。

4. 发明授权

US08338547B2 Polymer alloy and production method thereof 有权
标题翻译：聚合物合金及其制备方法
公开(公告)号：US08338547B2
公开(公告)日：2012-12-25
申请号：US12680436
申请日：2008-09-18
申请人： Hiroshi Takahashi , Sadayuki Kobayashi
发明人： Hiroshi Takahashi , Sadayuki Kobayashi
IPC分类号： C08G75/14 , C08L81/04 , B29K67/00 , B29K101/12 , B29K81/00
CPC分类号： C08J3/005 , C08J3/28 , C08L77/00 , C08L79/08 , Y10T428/31786
摘要： To provide a structure material having excellent mechanical characteristics and a functional material having excellent regularity, provided are a polymer alloy which is composed of at least two components of thermoplastic resins and of which the structure can be controlled finely and evenly dispersed and a production method of the polymer alloy. With respect to a polymer alloy composed of at least two or more components of thermoplastic resins, a precursor (A) of at least one thermoplastic resin among the thermoplastic resin components composing the polymer alloy is chemically reacted in the co-presence of the remaining thermoplastic resin component (B1) and/or a precursor (B2) of the thermoplastic resin component to induce spinodal decomposition, so that it is made possible to obtain a polymer alloy having excellent regularity and of which the structure is finely controllable and the structure is evenly dispersed.
摘要翻译：为了提供具有优异机械特性的结构材料和具有优异规则性的功能材料，提供了由热塑性树脂的至少两种组分组成并且其结构可以精细均匀分散的聚合物合金和制备方法聚合物合金。对于由至少两种以上的热塑性树脂成分构成的聚合物合金，构成聚合物合金的热塑性树脂成分中的至少一种热塑性树脂的前体（A）在剩余的热塑性树脂的共存下进行化学反应树脂成分（B1）和/或热塑性树脂成分的前体（B2）引起旋节状分解，使得可以获得具有优异规则性并且其结构精细可控且结构均匀的聚合物合金分散

5. 发明申请

US20110269907A1 RESIN COMPOSITION AND MOLDED ARTICLE MADE THEREOF 有权
标题翻译：树脂组合物及其制品
公开(公告)号：US20110269907A1
公开(公告)日：2011-11-03
申请号：US13180031
申请日：2011-07-11
申请人： Sadanori KUMAZAWA , Akiyoshi Tamai , Hiroyuki Ohme , Sadayuki Kobayashi
发明人： Sadanori KUMAZAWA , Akiyoshi Tamai , Hiroyuki Ohme , Sadayuki Kobayashi
IPC分类号： C08L51/04 , C08L69/00 , C08L27/06 , C08L33/12 , C08L23/12 , C08L23/06 , C08L67/04 , C08L25/04
CPC分类号： C08L51/006 , C08K5/092 , C08L23/0853 , C08L25/12 , C08L33/06 , C08L33/12 , C08L35/06 , C08L51/04 , C08L53/00 , C08L55/02 , C08L67/04 , C08L2666/02 , C08L2666/04 , C08L2666/24 , C08L2666/14
摘要： A resin composition is described that is excellent in strength, impact resistance, heat resistance and moldability, while further allowing for a reduction in the amount of CO2 needed for its production. The resin composition includes a styrene-based resin (A), an aliphatic polyester (B) and at least one species selected from a compatibilizer (C) and a dicarboxylic anhydride (D), wherein the compatibilizer is preferably at least one species selected from:(C-1) a methyl methacrylate polymer; (C-2) a vinyl-based polymer to which an epoxy unit or acid anhydride unit is copolymerized; (C-3) a graft polymer in which a methyl methacrylate unit is grafted to a rubbery polymer; and (C-4) a block copolymer having a polylactide segment and a vinyl-based polymer segment.
摘要翻译：描述了强度，耐冲击性，耐热性和成型性优异的树脂组合物，同时进一步允许其生产所需的二氧化碳的量的减少。树脂组合物包括苯乙烯类树脂（A），脂肪族聚酯（B）和选自增容剂（C）和二羧酸酐（D）中的至少一种，其中相容剂优选为选自以下的至少一种：：（C-1）甲基丙烯酸甲酯聚合物; （C-2）共聚有环氧单元或酸酐单元的乙烯基类聚合物; （C-3）接枝聚合物，其中甲基丙烯酸甲酯单元接枝到橡胶状聚合物上; 和（C-4）具有聚丙交酯链段和乙烯基类聚合物链段的嵌段共聚物。

6. 发明申请

US20070225450A1 Polymer alloy 失效
标题翻译：聚合物合金
公开(公告)号：US20070225450A1
公开(公告)日：2007-09-27
申请号：US11802762
申请日：2007-05-24
申请人： Sadayuki Kobayashi , Jiro Kumaki
发明人： Sadayuki Kobayashi , Jiro Kumaki
IPC分类号： C08L67/00
CPC分类号： C08L67/02 , C08J3/005 , C08L69/00 , C08L81/02 , C08L2666/18
摘要： This invention is a method for manufacturing a polymer alloy, by making at least two resins used as components miscible, and inducing the spinodal decomposition for causing phase separation, for forming a co-continuous structure with a wavelength of concentration fluctuation of 0.001 to 1 μm or a dispersed structure with a distance between particles of 0.001 to 1 μm. This invention is also a polymer alloy manufactured by the method. The polymer alloy of this invention can provide a molded article, film, fibers and the like respectively with excellent mechanical properties at high productivity.
摘要翻译：本发明是一种制造聚合物合金的方法，通过使至少两种树脂用作可混溶的组分，并引起旋节分解以引起相分离，形成波长为0.001至1μm的共连续结构或具有0.001至1μm的颗粒之间的距离的分散结构。本发明也是通过该方法制造的聚合物合金。本发明的聚合物合金可以分别以高生产率提供优异的机械性能的模塑制品，薄膜，纤维等。

7. 发明授权

US06813827B2 Manufacturing system for small planing watercrafts 失效
标题翻译：小型飞船制造系统
公开(公告)号：US06813827B2
公开(公告)日：2004-11-09
申请号：US10308383
申请日：2002-12-03
申请人： Masatoshi Murakami , Sadayuki Kobayashi , Takanori Suzuki , Yasuo Torii , Atsushi Takahashi
发明人： Masatoshi Murakami , Sadayuki Kobayashi , Takanori Suzuki , Yasuo Torii , Atsushi Takahashi
IPC分类号： B23P2100
CPC分类号： B23P21/004 , B63B9/00 , B63B9/06 , Y10T29/49829 , Y10T29/53365
摘要： A small planing watercraft manufacturing system includes a hull loading station, an engine mounting station, an adhesive applying station, a deck assembling station, a clamping station, a curing station and a watercraft unloading station that are disposed in a closed loop-shaped travel path in the order named with the hull loading station and the watercraft unloading station located adjacent to each other. By virtue of the closed loop-shaped travel path, the manufacturing system requires only a small space for installation thereof, can be constructed at a relatively low equipment cost and is able to produce small planing watercrafts with increased efficiencies.

8. 发明申请

US20120202944A1 POLYLACTIC ACID STEREOCOMPLEX, METHOD FOR PRODUCTION THEREOF, AND NUCLEATING AGENT FOR POLYLACTIC ACID RESIN 有权
标题翻译：聚酸酯立体异构体，其生产方法和聚氨酯树脂的核化剂
公开(公告)号：US20120202944A1
公开(公告)日：2012-08-09
申请号：US13390747
申请日：2010-08-19
申请人： Shinichiro Ochiai , Tatsuya Takamoto , Sadayuki Kobayashi
发明人： Shinichiro Ochiai , Tatsuya Takamoto , Sadayuki Kobayashi
IPC分类号： C08L67/04
CPC分类号： C08L67/04 , B29C47/0004 , B29C47/6056 , B29C47/6087 , B29C47/92 , B29C2947/92695 , B29C2947/92704 , B29C2947/92714 , C08J3/005 , C08J2367/04 , C08K5/0008 , C08K5/0016 , C08K5/0083 , C08L2205/02 , Y10T428/2982 , C08L2666/18
摘要： A polylactic acid stereocomplex has a crystal melting peak temperature of 215° C. or more, wherein the crystal melting peak is a single peak and has a peak half width of 12° C. or less, and a crystal melting enthalpy of 60 J/g or more as measured by differential scanning calorimetry. The polylactic acid stereocomplex has a high melting point, good heat resistance, and a high level of mechanical properties and chemical resistance. The method for producing a polylactic acid stereocomplex includes chaotic mixing of 30 to 70 parts by weight of (A) poly-L-lactic acid and 30 to 70 parts by weight of (B) poly-D-lactic acid based on 100 parts by weight of the total of (A) poly-L-lactic acid and (B) poly-D-lactic acid.
摘要翻译：聚乳酸立体络合物的结晶熔融峰温度为215℃以上，其中，结晶熔融峰为单峰，半峰宽为12℃以下，结晶熔融焓为60J / g或更高，通过差示扫描量热法测量。聚乳酸立体络合物具有高熔点，良好的耐热性和高水平的机械性能和耐化学性。聚乳酸立体络合物的制造方法包括：（A）聚-L-乳酸30〜70重量份，（B）聚-D-乳酸30〜70重量份混合混合，100重量份（A）聚-L-乳酸和（B）聚-D-乳酸的总重量。

9. 发明申请

US20100273944A1 THERMOPLASTIC RESIN COMPOSITION, PRODUCTION METHOD THEREOF, AND MOLDED ARTICLE 有权
标题翻译：热塑性树脂组合物，其制造方法和模制品
公开(公告)号：US20100273944A1
公开(公告)日：2010-10-28
申请号：US12293697
申请日：2007-03-22
申请人： Sadayuki Kobayashi , Daisuke Sato , Masaru Akita , Hiroshi Jinnai , Takashi Inoue
发明人： Sadayuki Kobayashi , Daisuke Sato , Masaru Akita , Hiroshi Jinnai , Takashi Inoue
IPC分类号： C08L81/04 , C08L77/00 , C08L25/06 , C08L69/00
CPC分类号： C08J3/203 , B29C47/0021 , B29C47/38 , B29C47/402 , C08L51/06 , C08L77/00 , C08L77/02 , C08L101/00 , C08L101/02 , C08L2666/24
摘要： A thermoplastic resin composition includes a thermoplastic resin (A) and a reactive functional group-containing resin (B), which has a specific structure in the morphology of the resin composition observed by transmission electron microscopy tomography, and the relaxation time T1C of each carbon nucleus by the solid NMR measurement of the thermoplastic resin composition containing a polyamide resin is kept in a specific range. The composition is excellent in the balance between contradictory properties such as impact resistance and heat resistance, remarkably exhibits a peculiar viscoelastic behavior not observed in the conventional polymeric materials, and is remarkably excellent in impact energy absorbing performance and vibration energy absorbing performance at the time of high-speed deformation.
摘要翻译：热塑性树脂组合物包括热塑性树脂（A）和含有反应性官能团的树脂（B），其具有通过透射电子显微镜断层摄影观察到的树脂组合物的形态的特定结构，并且各碳的弛豫时间T1C 通过含有聚酰胺树脂的热塑性树脂组合物的固体NMR测定将核保持在特定范围内。该组合物在抗冲击性和耐热性等相互矛盾的性质之间的平衡优异，显着地表现出在常规聚合物材料中未观察到的特有的粘弹性行为，并且在冲击能量吸收性能和振动能量吸收性能方面显着优异高速变形。

10. 发明申请

US20100216946A1 POLYMER ALLOY AND PRODUCTION METHOD THEREOF 有权
标题翻译：聚合物合金及其生产方法
公开(公告)号：US20100216946A1
公开(公告)日：2010-08-26
申请号：US12680436
申请日：2008-09-18
申请人： Hiroshi Takahashi , Sadayuki Kobayashi
发明人： Hiroshi Takahashi , Sadayuki Kobayashi
IPC分类号： C08L77/00 , C08L81/04 , C08L33/04
CPC分类号： C08J3/005 , C08J3/28 , C08L77/00 , C08L79/08 , Y10T428/31786
摘要： To provide a structure material having excellent mechanical characteristics and a functional material having excellent regularity, provided are a polymer alloy which is composed of at least two components of thermoplastic resins and of which the structure can be controlled finely and evenly dispersed and a production method of the polymer alloy. With respect to a polymer alloy composed of at least two or more components of thermoplastic resins, a precursor (A) of at least one thermoplastic resin among the thermoplastic resin components composing the polymer alloy is chemically reacted in the co-presence of the remaining thermoplastic resin component (B1) and/or a precursor (B2) of the thermoplastic resin component to induce spinodal decomposition, so that it is made possible to obtain a polymer alloy having excellent regularity and of which the structure is finely controllable and the structure is evenly dispersed.
摘要翻译：为了提供具有优异机械特性的结构材料和具有优异规则性的功能材料，提供了由热塑性树脂的至少两种组分组成并且其结构可以精细均匀分散的聚合物合金和制备方法聚合物合金。对于由至少两种以上的热塑性树脂成分构成的聚合物合金，构成聚合物合金的热塑性树脂成分中的至少一种热塑性树脂的前体（A）在剩余的热塑性树脂的共存下进行化学反应树脂成分（B1）和/或热塑性树脂成分的前体（B2）引起旋节状分解，使得可以获得具有优异规则性并且其结构精细可控且结构均匀的聚合物合金分散

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