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1. 发明授权

US07056997B2 Catalyst composition and olefin polymerization using same 失效
公开(公告)号：US07056997B2
公开(公告)日：2006-06-06
申请号：US11138089
申请日：2005-05-26
申请人： Brooke L. Small , Angel Jose Marcucci
发明人： Brooke L. Small , Angel Jose Marcucci
IPC分类号： C08F4/44 , B01J31/23
CPC分类号： B01J31/18 , B01J31/1815 , B01J31/2204 , B01J31/24 , B01J2231/122 , B01J2231/20 , B01J2531/56 , B01J2531/62 , B01J2531/72 , C07F11/005 , C08F4/63912 , C08F4/6392 , C08F10/02 , C08F110/02 , C08F210/16 , C08F2420/02 , C08F4/63904 , C08F2500/02 , C08F2500/23 , C08F210/14 , C08F4/69224 , C08F10/00 , C08F4/69232
摘要： Novel metal complexes, particularly chromium complexes, which contain at least one tridentate ligand are disclosed and prepared. Olefins, particularly ethylene, can be reacted to form butene and/or other homo- or co-oligomers and/or polymers with high α-olefin concentrations by contacting a metal catalyst which contains a transition metal, particularly chromium, complexes having per metal atom at least one tridentate ligand with N, O, or N and O coordinating sites.

2. 发明授权

US06911506B2 Catalyst composition and olefin polymerization using same 失效
公开(公告)号：US06911506B2
公开(公告)日：2005-06-28
申请号：US10013144
申请日：2001-12-10
申请人： Brooke L. Small , Angel Jose Marcucci
发明人： Brooke L. Small , Angel Jose Marcucci
IPC分类号： C07F11/00 , C08F4/60 , C08F4/62 , C08F4/6392 , C08F4/659 , C08F4/68 , C08F4/685 , C08F4/69 , C08F10/02 , C08F110/02 , C08F210/16 , C08F4/44 , B01J31/23
CPC分类号： B01J31/18 , B01J31/1815 , B01J31/2204 , B01J31/24 , B01J2231/122 , B01J2231/20 , B01J2531/56 , B01J2531/62 , B01J2531/72 , C07F11/005 , C08F4/63912 , C08F4/6392 , C08F10/02 , C08F110/02 , C08F210/16 , C08F2420/02 , C08F4/63904 , C08F2500/02 , C08F2500/23 , C08F210/14 , C08F4/69224 , C08F10/00 , C08F4/69232
摘要： Novel metal complexes, particularly chromium complexes, which contain at least one tridentate ligand are disclosed and prepared. Olefins, particularly ethylene, can be reacted to form butene and/or other homo- or co-oligomers and/or polymers with high α-olefin concentrations by contacting a metal catalyst which contains a transition metal, particularly chromium, complexes having per metal atom at least one tridentate ligand with N, O, or N and O coordinating sites.

3. 发明申请

US20150166429A1 Method for Making Polyalphaolefins Using Aluminum Halide Catalyzed Oligomerization of Olefins 有权
标题翻译：使用卤化铝催化低聚烯烃制备聚α-烯烃的方法
公开(公告)号：US20150166429A1
公开(公告)日：2015-06-18
申请号：US14132208
申请日：2013-12-18
申请人： Jeffery C. Gee , Brooke L. Small , Kenneth D. Hope , Robert C. Coffin , Steven M. Bischof
发明人： Jeffery C. Gee , Brooke L. Small , Kenneth D. Hope , Robert C. Coffin , Steven M. Bischof
IPC分类号： C07C2/24 , C07C9/00 , C07C11/02 , C07C5/05
CPC分类号： C10G50/02 , C07C2/22 , C07C2527/125 , C07C2527/126 , C10G50/00 , C10G69/126 , C10G2300/1088 , C10G2400/10 , C10G2400/22 , C08F210/14 , C08F4/14 , C08F8/48 , C08F4/005 , C08F2/02 , C07C11/02
摘要： The present application relates to method for oligomerizing olefin or for producing polyalphaolefin utilizing catalyst mixtures comprising aluminum halides and an organic liquid carrier. A process comprising contacting 1) a catalyst mixture comprising i) an aluminum trihalide and ii) an organic liquid carrier comprising first olefins, wherein the organic liquid carrier first olefins comprise at least 60 mole % 1,2-disubstituted olefins, trisubstituted olefins, or any combination thereof; and 2) a monomer comprising second olefins to form an oligomer product. An oligomer product produced by the process comprising contacting 1) a catalyst mixture comprising i) an aluminum trihalide and ii) an organic liquid carrier comprising first olefins, wherein the organic liquid carrier olefins comprise at least 75 mole % 1,2-disubstituted olefins, trisubstituted olefins, or any combination thereof; and 2) a monomer comprising second olefins to form an oligomer product.
摘要翻译：本申请涉及使用包含卤化铝和有机液体载体的催化剂混合物使烯烃低聚或用于生产聚α-烯烃的方法。一种方法，其包括使1）催化剂混合物，其包含i）三卤化铝和ii）包含第一烯烃的有机液体载体，其中所述有机液体载体第一烯烃包含至少60摩尔％的1,2-二取代烯烃，三取代的烯烃或其任何组合; 和2）包含第二烯烃的单体以形成低聚物产物。通过该方法生产的低聚物产物包括：1）催化剂混合物，其包含i）三卤化铝和ii）包含第一烯烃的有机液体载体，其中所述有机液体载体烯烃包含至少75摩尔％的1,2-二取代的烯烃，三取代烯烃，或其任何组合; 和2）包含第二烯烃的单体以形成低聚物产物。

4. 发明授权

US08334420B2 Olefin oligomerization catalysts and methods of using same 有权
标题翻译：烯烃低聚催化剂及其使用方法
公开(公告)号：US08334420B2
公开(公告)日：2012-12-18
申请号：US12116365
申请日：2008-05-07
申请人： Brooke L. Small , Jeffery C. Gee
发明人： Brooke L. Small , Jeffery C. Gee
IPC分类号： C07C2/32 , C07C2/08 , C07F9/28 , B01J31/22
CPC分类号： C07F9/46 , B01J31/143 , B01J31/188 , B01J2231/20 , B01J2531/62 , C07C2/36 , C07C2531/24 , C07F11/00 , C07C11/02
摘要： A metal complex comprising a metal compound complexed to a heteroatomic ligand, the metal complex having Structure X: wherein R1, R2, R3, and R4 are each independently an alkyl group, a cycloalkyl group, a substituted cycloalkyl group, an aromatic group, or a substituted aromatic group, R1c, R2c, R3c, R4c, and R5c are each independently hydrogen or an alkyl group, and MXp comprises a group IVB, VB, or VIB metal. A metal complex comprising a metal compound complexed to a diphosphino aminyl ligand comprising at least two diphosphino aminyl moieties and a linking group linking each aminyl nitrogen atom of the diphosphino aminyl moieties.
摘要翻译：包含与杂原子配体络合的金属化合物的金属络合物，具有结构X的金属络合物：其中R 1，R 2，R 3和R 4各自独立地为烷基，环烷基，取代的环烷基，芳族基团或取代的芳族基团，R1c，R2c，R3c，R4c和R5c各自独立地为氢或烷基，MXp包含IVB，VB或VIB族金属。一种金属络合物，其包含与二膦基乙炔基配体络合的金属化合物，其包含至少两个二膦酰乙烯基部分和连接二膦酰乙烯基部分的每个亚氨基氮原子的连接基团。

5. 发明授权

US08329608B2 Methods of preparation of an olefin oligomerization catalyst 有权
标题翻译：制备烯烃低聚催化剂的方法
公开(公告)号：US08329608B2
公开(公告)日：2012-12-11
申请号：US12057853
申请日：2008-03-28
申请人： Ronald D. Knudsen , Bruce E. Kreischer , Ronald G. Abbott , Steven D. Bridges , Brooke L. Small
发明人： Ronald D. Knudsen , Bruce E. Kreischer , Ronald G. Abbott , Steven D. Bridges , Brooke L. Small
IPC分类号： B01J21/00 , B01J23/00 , B01J25/00 , B01J29/00 , B01J31/00 , B01J37/00 , C08F4/02 , C08F4/60
CPC分类号： B01J31/143 , B01J31/0244 , B01J31/2226 , B01J2231/20 , B01J2531/62 , C07C2/32 , C07C11/02
摘要： A method of making a catalyst for use in oligomerizing an olefin, comprising a chromium-containing compound, a pyrrole-containing compound, a metal alkyl, a halide-containing compound, and optionally a solvent, the method comprising abating all or a portion of water, acidic protons, or both from a composition comprising the chromium-containing compound, a composition comprising the pyrrole-containing compound, a composition comprising a non-metal halide-containing compound, a composition comprising the solvent, or combinations thereof prior to contact thereof with a composition comprising a metal halide-containing compound.
摘要翻译：一种制备用于低聚烯烃的催化剂的方法，包括含铬化合物，含吡咯的化合物，金属烷基，含卤化合物和任选的溶剂，所述方法包括减少全部或部分包含含铬化合物的组合物，包含含吡咯的化合物的组合物，包含非金属卤化物的化合物的组合物，包含溶剂的组合物或其接触前的组合的组合物，水，酸性质子或两者其包含含有金属卤化物的化合物的组合物。

6. 发明授权

US07728160B2 Diimine metal complexes, methods of synthesis, and methods of using in oligomerization and polymerization 有权
标题翻译：二亚胺金属络合物，合成方法以及在低聚反应中使用的方法
公开(公告)号：US07728160B2
公开(公告)日：2010-06-01
申请号：US11852796
申请日：2007-09-10
申请人： Brooke L. Small , Michael Carney
发明人： Brooke L. Small , Michael Carney
IPC分类号： C07F15/02 , C07F15/04 , C07F15/06
CPC分类号： C07F15/025
摘要： Novel α-diimine metal complexes, particularly iron complexes are disclosed. The α-diimine metal complexes are produced by forming one of the α-diimine metal complex imine bonds in the presence of a metal salt or an α-acylimine metal complex. α-diimine metal complexes having two different α-diimine nitrogen groups may be produced. The α-diimine metal complexes are useful for polymerizing or oligomerizing olefins.
摘要翻译：公开了新的α-二亚胺金属络合物，特别是铁络合物。通过在金属盐或α-酰亚胺金属络合物的存在下形成α-二亚胺金属络合物亚胺键之一来制备α-二亚胺金属络合物。可以制备具有两个不同的α-二亚胺氮基团的α-二亚胺金属络合物。 α-二亚胺金属络合物可用于烯烃的聚合或低聚。

7. 发明授权

US07297806B2 Manufacture of alpha-olefins 有权
标题翻译： α-烯烃的制造
公开(公告)号：US07297806B2
公开(公告)日：2007-11-20
申请号：US10235443
申请日：2002-09-05
申请人： Maurice S. Brookhart, III , Brooke L. Small
发明人： Maurice S. Brookhart, III , Brooke L. Small
IPC分类号： B01J31/00 , B01J37/00
CPC分类号： C07D213/53 , C07C2/32 , C07C2531/22 , C07F15/02 , C07F15/025 , C08F10/00 , C08F4/7042
摘要： Alpha-olefin are manufactured in high yield and with very high selectivity by contacting ethylene with an iron complex of a selected 2,6-pyridinedicarboxaldehyde bisimine or a selected 2,6-diacylpyridine bisimine, and in some cases a selected activator compound such as an alkyl aluminum compound. Novel bisimines and their iron complexes are also disclosed. The α-olefin are useful as monomers and chemical intermediates.
摘要翻译：通过使乙烯与选择的2,6-吡啶二甲醛双亚胺或选择的2,6-二酰基吡啶双亚胺的铁络合物接触，以高产率和非常高的选择性制备α-烯烃，并且在一些情况下选择的活化剂化合物例如烷基铝化合物。还公开了新型双亚胺及其铁络合物。 α-烯烃可用作单体和化学中间体。

8. 发明授权

US07223893B2 Linear alpha-olefin dimers possessing substantial linearity 有权
标题翻译：线性α-烯烃二聚体具有很大的线性
公开(公告)号：US07223893B2
公开(公告)日：2007-05-29
申请号：US10056137
申请日：2002-01-24
申请人： Brooke L. Small , Eduardo J Baralt
发明人： Brooke L. Small , Eduardo J Baralt
IPC分类号： C07C13/00
CPC分类号： C07C2/32 , C07C11/02 , C07C2531/22 , C07C2531/26
摘要： Linear 1-butene dimers and other linear alpha-olefin dimers are manufactured in high yield and with high selectivity by coupling of alpha-olefins. The coupling is accomplished by contacting alpha olefins with an iron-based catalyst activated with an aluminum-based co-catalyst. The catalyst is structured to preclude formation of multiple dimer products, and the byproducts of the olefin coupling consist almost exclusively of methyl branched olefin dimers. The dimers have potentially diverse use in areas stretching form pharmaceuticals to plastics. Linear 1-butene dimers may be particularly useful in the production of plasticizer alcohols which may in turn be used to manufacture high quality plastics with reduced leaching.
摘要翻译：线性1-丁烯二聚体和其它直链α-烯烃二聚体以高产率和高选择性通过α-烯烃的偶联制备。通过使α-烯烃与用铝基助催化剂活化的铁基催化剂接触来实现偶合。该催化剂被构造成排除多个二聚体产物的形成，并且烯烃偶联的副产物几乎完全由甲基支链烯烃二聚体组成。二聚体在从药物到塑料中拉伸的领域中具有潜在的多种用途。线性1-丁烯二聚体可以特别用于生产增塑剂醇，其可以用于制造具有减少浸出的高质量塑料。

9. 发明授权

US06911505B2 Selective isomerization and linear dimerization of olefins using cobalt catalysts 失效
标题翻译：使用钴催化剂选择性异构化和烯烃线性二聚
公开(公告)号：US06911505B2
公开(公告)日：2005-06-28
申请号：US10264730
申请日：2002-10-04
申请人： Brooke L. Small
发明人： Brooke L. Small
IPC分类号： C07C11/02 , C07C11/107 , C10G50/00 , C08F4/44
CPC分类号： C10G50/00 , C07C11/02 , C07C11/107 , Y10S526/901
摘要： Processes for the production of alpha-olefins, including dimerization and isomerization of olefins using a cobalt catalyst complex are provided herein. The olefins so produced are useful as monomers in further polymerization reactions and are useful as chemical intermediates.
摘要翻译：本文提供了使用钴催化剂复合物生产α-烯烃的方法，包括烯烃的二聚和异构化。如此生产的烯烃可用作进一步聚合反应中的单体，并且可用作化学中间体。

10. 发明授权

US6103946A Manufacture of .alpha.-olefins 失效
标题翻译： α-烯烃的制造
公开(公告)号：US6103946A
公开(公告)日：2000-08-15
申请号：US005965
申请日：1998-01-12
申请人： Maurice S. Brookhart, III , Brooke L. Small
发明人： Maurice S. Brookhart, III , Brooke L. Small
IPC分类号： C07B61/00 , C07C2/32 , C07C11/02 , C07D213/53 , C07F15/02 , C08F4/44 , C08F10/00 , C07C2/02
CPC分类号： C07D213/53 , C07C2/32 , C07F15/02 , C07F15/025 , C08F10/00 , C07C2531/22
摘要： Alpha-olefins are manufactured in high yield and with very high selectivity by contacting ethylene with an iron complex of a selected 2,6-pyridinedicarboxaldehyde bisimine or a selected 2,6-diacylpyridine bisimine, and in some cases a selected activator compound such as an alkyl aluminum compound. Novel bisimines and their iron complexes are also disclosed. The .alpha.-olefins are useful as monomers and chemical intermediates.
摘要翻译：通过使乙烯与选择的2,6-吡啶二甲醛双亚胺或选择的2,6-二酰基吡啶双亚胺的铁络合物接触，以高产率和非常高的选择性制备α-烯烃，并且在一些情况下选择的活化剂化合物如烷基铝化合物。还公开了新型双亚胺及其铁络合物。 α-烯烃可用作单体和化学中间体。

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