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1. 发明授权

US4980453A Macrocyclic oligomers containing spiro(bis)indane moietes 失效
标题翻译：含有螺（双）茚满的大环低聚物
公开(公告)号：US4980453A
公开(公告)日：1990-12-25
申请号：US146154
申请日：1988-01-20
申请人： Daniel J. Brunelle , Thomas L. Guggenheim , James A. Cella , Thomas L. Evans , Luca P. Fontana , Gary R. Faler , James M. Fukuyama , Eugene P. Boden , Jonathan D. Rich , Thomas G. Shannon , Sharon J. McCormick , Philip J. McDermott , Alice M. Colley , Joseph W. Guiles
发明人： Daniel J. Brunelle , Thomas L. Guggenheim , James A. Cella , Thomas L. Evans , Luca P. Fontana , Gary R. Faler , James M. Fukuyama , Eugene P. Boden , Jonathan D. Rich , Thomas G. Shannon , Sharon J. McCormick , Philip J. McDermott , Alice M. Colley , Joseph W. Guiles
IPC分类号： C08G64/06 , C08G65/40 , C08G75/23
CPC分类号： C08G75/23 , C08G64/06 , C08G65/4081
摘要： Macrocyclic oligomers, including polycarbonates, polyesters, polyamides, polyimides, polyetherketones and polyethersulfones, are conveniently prepared from various spiro(bis)indane compounds, especially the 6,6'-difunctional 3,3',3'-tetramethylspiro(bis)indanes. The macrocyclic oligomers may be conveniently converted to linear polymers.
摘要翻译：大环低聚物，包括聚碳酸酯，聚酯，聚酰胺，聚酰亚胺，聚醚酮和聚醚砜，可以方便地由各种螺（双）二氢化茚化合物，特别是6,6'-二官能3,3'，3'-四甲基螺（双）二氢化茚制备。大环低聚物可以方便地转化为线性聚合物。

2. 再颁专利

USRE34431E Macrocyclic oligomers containing spiro(bis)indane moieties 失效
标题翻译：含有螺（双）二氢化茚部分的大环低聚物
公开(公告)号：USRE34431E
公开(公告)日：1993-11-02
申请号：US915381
申请日：1992-05-08
申请人： Daniel J. Brunelle , Thomas L. Guggenheim , James A. Cella , Thomas L. Evans , Luca P. Fontana , Gary R. Faler , James M. Fukuyama , Eugene P. Boden , Jonathan D. Rich , Thomas G. Shannon , Sharon J. McCormick , Philip J. McDermott , Alice M. Colley , Joseph W. Guiles
发明人： Daniel J. Brunelle , Thomas L. Guggenheim , James A. Cella , Thomas L. Evans , Luca P. Fontana , Gary R. Faler , James M. Fukuyama , Eugene P. Boden , Jonathan D. Rich , Thomas G. Shannon , Sharon J. McCormick , Philip J. McDermott , Alice M. Colley , Joseph W. Guiles
IPC分类号： C08G63/193 , C08G64/06 , C08G64/18 , C08G65/40 , C08G65/48 , C08G69/26 , C08G73/10 , C08G75/23 , C08G63/00 , C07D231/00 , C07F7/04 , C08G69/42
CPC分类号： C08G63/193 , C08G64/06 , C08G64/183 , C08G65/4081 , C08G65/48 , C08G69/26 , C08G73/10 , C08G75/23
摘要： Macrocyclic oligomers, including polycarbonates, polyesters, polyamides, polyimides, polyetherketones and polyethersulfones, are conveniently prepared from various spiro(bis)indane compounds, especially the 6,6'-difunctional 3,3',3'-tetramethylspiro(bis)indanes. The macrocyclic oligomers may be conveniently converted to linear polymers.

3. 发明授权

US4864034A Spiro(bis)indane bis-oxyphthalic acids and functional derivatives thereof 失效
标题翻译：螺（双）茚并二氧邻苯二甲酸及其官能衍生物
公开(公告)号：US4864034A
公开(公告)日：1989-09-05
申请号：US146155
申请日：1988-01-20
申请人： James A. Cella , Gary R. Faler
发明人： James A. Cella , Gary R. Faler
IPC分类号： C07C63/49 , C07C63/72 , C07C65/26 , C07C69/92 , C07C233/65 , C07C235/46 , C07D209/48 , C07D307/89 , C08G73/10 , C08G73/14
CPC分类号： C07D209/48 , C07C233/65 , C07C63/49 , C07C63/72 , C07C65/26 , C08G73/10 , C08G73/14
摘要： Spiro(bis)indane bis-oxyphthalic acid bisimides are prepared by the reaction of a nitro- or halo-substituted phthalimide with a salt of a 6,6'-dihydroxy-3,3,3'3'-tetramethylspiro(bis)indane. The bisimides may be converted to the corresponding dianhydrides, which react with diamines to form polyetherimides, or to the free tetracarboxylic acids or their salts, esters or amides.

4. 发明授权

US5414057A Redistribution of organic polycarbonate compositions 失效
标题翻译：有机聚碳酸酯组合物的再分布
公开(公告)号：US5414057A
公开(公告)日：1995-05-09
申请号：US159691
申请日：1993-12-01
申请人： Allen J. Campbell , David M. Dardaris , Gary R. Faler , Patrick J. McCloskey , Thomas L. Evans
发明人： Allen J. Campbell , David M. Dardaris , Gary R. Faler , Patrick J. McCloskey , Thomas L. Evans
IPC分类号： C08G64/42 , C08F283/02
CPC分类号： C08G64/42
摘要： A process for the redistribution of an organic polycarbonate composition. The process involves melt equilibrating a starting polycarbonate composition (which may be a single polycarbonate or a mixture of polycarbonates, and may be or include recycled polycarbonate) having an initial weight average molecular weight in the presence of a carbonate redistribution catalyst and in the absence of branching agents, under conditions such that a redistributed polycarbonate composition is formed having a weight average molecular weight different from, and typically lower than, the initial weight.
摘要翻译：一种有机聚碳酸酯组合物再分配的方法。该方法包括在碳酸盐再分布催化剂的存在下熔融平衡起始聚碳酸酯组合物（其可以是单一聚碳酸酯或聚碳酸酯的混合物，并且可以是或包括再循环的聚碳酸酯），其具有初始重均分子量，支化剂，在形成重新分布的聚碳酸酯组合物的条件下，其重均分子量不同于并且通常低于初始重量。

5. 发明授权

US4895919A Spirobiindane copolysiloxanecarbonates and method for their preparation 失效
标题翻译：螺环丁烷共聚硅氧烷碳酸酯及其制备方法
公开(公告)号：US4895919A
公开(公告)日：1990-01-23
申请号：US254742
申请日：1988-10-07
申请人： Gary R. Faler , David M. Dardaris , Donald G. LeGrand
发明人： Gary R. Faler , David M. Dardaris , Donald G. LeGrand
IPC分类号： C08G64/00 , C08G64/08 , C08G64/18 , C08G77/42 , C08G77/448
CPC分类号： C08G77/448 , C08G64/085
摘要： Copolysiloxanecarbonate compositions are prepared by the reaction of a carbonate precursor such as phosgene with a mixture of bisphenols including a spirobiindane bisphenol, at least one of said bisphenols containing polydiorganosiloxane moieties. The reaction may take place in one step or sequentially. The products are characterized by low processing temperature, low orientational birefringence and high ductility.

6. 发明授权

US4766254A Method for maximizing yield and purity of bisphenol A 失效
标题翻译：双酚A的产率和纯度最大化的方法
公开(公告)号：US4766254A
公开(公告)日：1988-08-23
申请号：US104602
申请日：1987-10-05
申请人： Gary R. Faler , Michael J. Cipullo
发明人： Gary R. Faler , Michael J. Cipullo
IPC分类号： C07C39/16 , C07C27/00 , C07C37/82 , C07C37/88 , C07C67/00 , C07C37/68
CPC分类号： C07C37/82
摘要： Product losses and color formation are sometimes encountered in the synthesis of bisphenol A from phenol and acetone in the presence of a cation exchange resin, particularly in the crude product stream from which bisphenol A has been separated via its phenol adduct. Such losses are suppressed and the crude product stream stabilized and decolorized by contact with an anion exchange resin.

7. 发明授权

US06525164B2 Methods for converting linear polyesters to macrocyclic oligoester compositions and macrocyclic oligoesters 有权
标题翻译：将线性聚酯转化为大环低聚酯组合物和大环低聚酯的方法
公开(公告)号：US06525164B2
公开(公告)日：2003-02-25
申请号：US09945233
申请日：2001-08-31
申请人： Gary R. Faler
发明人： Gary R. Faler
IPC分类号： C08G6378
CPC分类号： C08G63/81 , C08G63/183 , C08G63/78 , C08G63/85 , Y02P20/582
摘要： Macrocyclic oligoesters and compositions comprising macrocyclic oligoesters are prepared from intermediate molecular weight polyesters. In one embodiment, a diol is contacted with a dicarboxylic acid or a dicarboxylate in the presence of a catalyst to produce a composition comprising a hydroxyalkyl-tenninated polyester oligomer. The hydroxyalkyl-terminated polyester oligomer is heated to produce a composition comprising an intermediate molecular weight polyester which preferably has a molecular weight between about 20,000 Daltons and about 70,000 Daltons. The intermediate molecular weight polyester is heated and a solvent is added prior to or during the heating process to produce a composition comprising a macrocyclic oligoester. An optional step is to separate the macrocyclic oligoester from the composition comprising the macrocyclic oligoester.
摘要翻译：大环低聚物和包含大环低聚酯的组合物由中等分子量聚酯制备。在一个实施方案中，二醇在催化剂存在下与二羧酸或二羧酸酯接触以制备包含羟基烷基聚酯低聚物的组合物。加热羟基烷基封端的聚酯低聚物以产生包含中等分子量聚酯的组合物，其优选具有约20,000道尔顿和约70,000道尔顿之间的分子量。加热中分子量聚酯并在加热过程之前或期间加入溶剂以产生包含大环低聚酯的组合物。任选的步骤是将大环寡聚酯与包含大环低聚酯的组合物分离。

8. 发明授权

US5142086A Method for making organic carbonates 失效
公开(公告)号：US5142086A
公开(公告)日：1992-08-25
申请号：US678411
申请日：1991-04-01
申请人： Joseph A. King, Jr. , Terry E. Krafft , Gary R. Faler
发明人： Joseph A. King, Jr. , Terry E. Krafft , Gary R. Faler
IPC分类号： B01J31/04 , C07B61/00 , C07C68/00 , C07C69/96
CPC分类号： C07C68/005 , Y02P20/584
摘要： A method for making diphenyl carbonate free of color bodies is provided by reacting an organic hydroxy compound, such as phenol with carbon monoxide and oxygen in the presence of an effective amount of a palladium catalyst, in the form of a palladium material which is used in combination with a quaternary ammonium salt, an inorganic cocatalyst, such as cobalt diacetate and an organic cocatalyst such as benzophenone or 1,10-phenanthroline. Recycling of catalyst values is also provided.

9. 发明授权

US4791234A Substantially pure spirobiindane bisphenols and method for their preparation 失效
标题翻译：基本纯粹的螺二茚二酚双酚及其制备方法
公开(公告)号：US4791234A
公开(公告)日：1988-12-13
申请号：US917644
申请日：1986-10-10
申请人： Gary R. Faler , Jerry C. Lynch
发明人： Gary R. Faler , Jerry C. Lynch
IPC分类号： B01J27/08 , B01J27/00 , B01J31/00 , B01J31/02 , C07B61/00 , C07C27/00 , C07C37/14 , C07C39/17 , C07C39/42 , C07C67/00 , C08G64/06 , C07C39/12
CPC分类号： C08G64/06
摘要： Spirobiindane bisphenols of high purity, suitable for conversion to high molecular weight polycarbonates, are prepared by reacting a bisphenol or 4-isopropenylphenol with a metal halide Lewis acid or an alkanesulfonic acid, followed by removing impurities including phenols, 1-(4-hydroxyphenyl)indanols and the like. A step of purification by precipitation with water from a methanol-methylene chloride solution is included.

10. 发明授权

US4424283A Catalyst for synthesizing bisphenol and method for making same 失效
标题翻译：合成双酚的催化剂及其制备方法
公开(公告)号：US4424283A
公开(公告)日：1984-01-03
申请号：US342435
申请日：1982-01-25
申请人： Gary R. Faler , Geroge R. Loucks
发明人： Gary R. Faler , Geroge R. Loucks
IPC分类号： B01J31/10 , C07C37/20 , B01J20/26 , B01J39/20
CPC分类号： B01J31/10 , C07C37/20 , B01J2231/347
摘要： A sulfonated organic polymer, such as a sulfonated polystyrene ion-exchange resin is provided having organic mercaptan groups attached to backbone sulfone radicals by covalent nitrogen-sulfur linkages. A method for making such sulfonated organic polymer is also provided. The ion-exchange resin can be used to effect phenol-ketone condensation in the synthesis of bisphenols.
摘要翻译：提供磺化有机聚合物，例如磺化聚苯乙烯离子交换树脂，其具有通过共价氮 - 硫键连接到主链基团上的有机硫醇基团。还提供了制备这种磺化有机聚合物的方法。离子交换树脂可用于在双酚的合成中进行酚 - 酮缩合。

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