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1. 发明申请

US20130158215A1 MODIFIED ZIEGLER-NATTA CATALYST SYSTEMS 审中-公开
标题翻译：改性ZIEGLER-NATTA催化剂体系
公开(公告)号：US20130158215A1
公开(公告)日：2013-06-20
申请号：US13698025
申请日：2011-05-19
申请人： Elsa Martigny , Vincent Monteil , Roger Spitz , Aurélien Vantomme
发明人： Elsa Martigny , Vincent Monteil , Roger Spitz , Aurélien Vantomme
IPC分类号： C08F4/685 , C08F210/16 , C08F10/02 , C08F4/646 , C08F4/68
CPC分类号： C08F4/685 , C08F4/646 , C08F4/68 , C08F10/00 , C08F10/02 , C08F210/16 , C08F210/14 , C08F2500/23 , C08F4/02 , C08F4/657
摘要： This invention relates to modified Ziegler-Natta catalyst systems that have an excellent activity in homo- or co-polymerisation of ethylene and alpha-olefins and are able to produce polymers having reduced molecular weight distribution and improved incorporation of hexene with respect to conventional Ziegler-Natta catalyst systems.
摘要翻译：本发明涉及在乙烯和α-烯烃的均聚或共聚合中具有优异活性的改性齐格勒 - 纳塔催化剂体系，并且能够生产具有降低的分子量分布和改进己烯掺入的聚合物相对于常规的齐格勒 - 纳塔催化剂体系。

2. 发明授权

US07094854B2 Ethylene/butadiene copolymers, catalytic system and process for the synthesis thereof 有权
标题翻译：乙烯/丁二烯共聚物，催化体系及其合成方法
公开(公告)号：US07094854B2
公开(公告)日：2006-08-22
申请号：US11106619
申请日：2005-04-15
申请人： Vincent Monteil , Roger Spitz , Christophe Boisson
发明人： Vincent Monteil , Roger Spitz , Christophe Boisson
IPC分类号： C08F236/06
CPC分类号： C08F10/00 , C08F210/02 , C08F236/06 , C08F4/52 , C08F232/00 , C08F2500/01
摘要： Disclosed are ethylene and butadiene copolymers and a catalytic system usable for the synthesis of these copolymers. The copolymers have a molar content of units resulting from butadiene of ≧8%, said units comprising trans-1,2 cyclohexane linkages, and a number-average molecular mass Mn of ≧40,000 g/mol. The catalytic system includes: (i) an organometallic complex represented by one of the following formulae A or B: where Ln represents a lanthanide and X a halogen, where, in the formula A, two ligand molecules Cp1 and Cp2 each consisting of a fluorenyl group, are attached to Ln, where, in the formula B, a ligand molecule consisting of two fluorenyl groups Cp1 and Cp2, joined together by a bridge P of formula MR2, where M is an element of column IVa and R is an alkyl with 1 to 20 carbon atoms, is attached to Ln, and (ii) a co-catalyst selected from an alkylmagnesium, an alkyllithium, an alkylaluminium, a Grignard reagent, or a mixture of these constituents. The (co-catalyst/organometallic complex) molar ratio falls within a range of from 1 to 8.
摘要翻译：公开了乙烯和丁二烯共聚物和可用于合成这些共聚物的催化体系。共聚物具有由丁二烯> 8％产生的单元的摩尔含量，所述单元包含反式-1,2-环己烷键，且数均分子量Mn> 40,000g / mol。催化体系包括：（i）由下式A或B之一表示的有机金属络合物：其中Ln表示镧系元素，X为卤素，其中在式A中，两个配体分子Cp 1 和由芴基组成的Cp 2 2连接到Ln，其中在式B中，由两个芴基Cp 1和Cp 2组成的配体分子，其中M是式IVa的元素，其中M是第IVa列的元素，R是具有1至20个碳原子的烷基，连接到Ln的桥P上，和（ii）选自烷基镁，烷基锂，烷基铝，格氏试剂或这些组分的混合物的助催化剂。（助催化剂/有机金属络合物）摩尔比在1〜8的范围内。

3. 发明申请

US20060160969A1 Catalytic system for obtaining conjugated diene/monoolefin copolymers and these copolymers 有权
标题翻译：用于获得共轭二烯/单烯烃共聚物和这些共聚物的催化体系
公开(公告)号：US20060160969A1
公开(公告)日：2006-07-20
申请号：US11350754
申请日：2006-02-10
申请人： Christophe Boisson , Vincent Monteil , Roger Spitz
发明人： Christophe Boisson , Vincent Monteil , Roger Spitz
IPC分类号： C08F4/44 , B01J31/00
CPC分类号： C08F210/00 , C08F210/02 , C08F210/06 , C08F210/14 , C08F210/16 , C08F236/04 , Y10S526/943 , C08F4/52 , C08F236/06
摘要： A catalytic system usable for the copolymerization of at least one conjugated diene and at least one monoolefin, a process for preparing this catalytic system, a process for preparing a copolymer of a conjugated diene and at least one monoolefin using said catalytic system, and said copolymer are described. This catalytic system includes: (i) an organometallic complex represented by the following formula: {[P(Cp)(Fl)Ln(X)(Lx)}p (1) where Ln represents a lanthanide atom to which is attached a ligand molecule comprising cyclopentadienyl Cp and fluorenyl Fl groups linked to one another by a bridge P of the formula MR1R2, M is an element from column IVa of Mendeleev's periodic table and R1 and R2 each represent alkyl groups of 1 to 20 carbon atoms or cycloalkyl or phenyl groups of 6 to 20 carbon atoms, X represents a halogen atom, L represents an optional complexing molecule, such as an ether, and optionally a substantially less complexing molecule, such as toluene, p is a natural integer greater than or equal to 1 and x is greater than or equal to 0, and (ii) a co-catalyst selected from alkylmagnesiums, alkyllithiums, alkylaluminums, Grignard reagents and mixtures of these constituents.
摘要翻译：一种可用于共聚二烯和至少一种单烯烃的催化体系，该催化体系的制备方法，使用所述催化体系制备共轭二烯和至少一种单烯烃的共聚物的方法，所述共聚物被描述。该催化体系包括：（i）由下式表示的有机金属络合物：<？in-line-formula description =“In-line formula”end =“lead”？> {[P（Cp）（Fl）Ln （1）<？in-line-formula description =“In-line Formulas”end =“tail”？>其中Ln表示（x）（L x x）连接有配体分子的镧系元素原子，该配体分子包含通过式MR 1的桥P彼此连接的环戊二烯基Cp和芴基F 1基团，M是 Mendeleev的元素周期表IVa的元素和R 1和R 2各自表示1-20个碳原子的烷基或6-20个碳原子的环烷基或苯基， X表示卤素原子，L表示任选的络合分子，例如醚，以及任选的基本上较少络合的分子如甲苯，p是大于或等于1的自然整数，x大于或等于0 ，和（ii）助催化剂，选自烷基镁，烷基锂，烷基铝，格氏试剂和这些组分的混合物。

4. 发明申请

US20050239639A1 Ethylene/butadiene copolymers, catalytic system and process for the synthesis thereof 有权
标题翻译：乙烯/丁二烯共聚物，催化体系及其合成方法
公开(公告)号：US20050239639A1
公开(公告)日：2005-10-27
申请号：US11106619
申请日：2005-04-15
申请人： Vincent Monteil , Roger Spitz , Christophe Boisson
发明人： Vincent Monteil , Roger Spitz , Christophe Boisson
IPC分类号： C08F210/12 , C08F10/00 , C08F210/02 , C08F236/06 , B01J31/00 , C08F4/44
CPC分类号： C08F10/00 , C08F210/02 , C08F236/06 , C08F4/52 , C08F232/00 , C08F2500/01
摘要： Disclosed are ethylene and butadiene copolymers and a catalytic system usable for the synthesis of these copolymers. The copolymers have a molar content of units resulting from butadiene of ≧8%, said units comprising trans-1,2 cyclohexane linkages, and a number-average molecular mass Mn of ≧40,000 g/mol. The catalytic system includes: (i) an organometallic complex represented by one of the following formulae A or B: where Ln represents a lanthanide and X a halogen, where, in the formula A, two ligand molecules Cp1 and Cp2 each consisting of a fluorenyl group, are attached to Ln, where, in the formula B, a ligand molecule consisting of two fluorenyl groups Cp1 and Cp2, joined together by a bridge P of formula MR2, where M is an element of column IVa and R is an alkyl with 1 to 20 carbon atoms, is attached to Ln, and (ii) a co-catalyst selected from an alkylmagnesium, an alkyllithium, an alkylaluminium, a Grignard reagent, or a mixture of these constituents. The (co-catalyst/organometallic complex) molar ratio falls within a range of from 1 to 8.
摘要翻译：公开了乙烯和丁二烯共聚物和可用于合成这些共聚物的催化体系。共聚物具有由丁二烯> 8％产生的单元的摩尔含量，所述单元包含反式-1,2-环己烷键，且数均分子量Mn> 40,000g / mol。催化体系包括：（i）由下式A或B之一表示的有机金属络合物：其中Ln表示镧系元素，X为卤素，其中在式A中，两个配体分子Cp 1 和由芴基组成的Cp 2 2连接到Ln，其中在式B中，由两个芴基Cp 1和Cp 2组成的配体分子，其中M是式IVa的元素，其中M是第IVa列的元素，R是具有1至20个碳原子的烷基，连接到Ln的桥P上，和（ii）选自烷基镁，烷基锂，烷基铝，格氏试剂或这些组分的混合物的助催化剂。（助催化剂/有机金属络合物）摩尔比在1〜8的范围内。

5. 发明授权

US08039565B2 Catalytic system for obtaining conjugated diene/mono-olefin copolymers and these copolymers 有权
标题翻译：用于获得共轭二烯/单烯烃共聚物和这些共聚物的催化体系
公开(公告)号：US08039565B2
公开(公告)日：2011-10-18
申请号：US12453333
申请日：2009-05-07
申请人： Christophe Boisson , Vincent Monteil , Roger Spitz
发明人： Christophe Boisson , Vincent Monteil , Roger Spitz
IPC分类号： C08F4/52 , C08F236/04 , C08F236/06 , B01J31/22
CPC分类号： C08F210/00 , C08F210/02 , C08F210/06 , C08F210/14 , C08F210/16 , C08F236/04 , Y10S526/943 , C08F4/52 , C08F236/06
摘要： A catalytic system usable for the copolymerization of at least one conjugated diene and at least one monoolefin, a process for preparing this catalytic system, a process for preparing a copolymer of a conjugated diene and at least one monoolefin using said catalytic system, and said copolymer are described. This catalytic system includes: (i) an organometallic complex represented by the following formula: {[P(Cp)(Fl)Ln(X)(LX)}p (1) where Ln represents a lanthanide atom to which is attached a ligand molecule comprising cyclopentadienyl Cp and fluorenyl Fl groups linked to one another by a bridge P of the formula MR1R2, M is an element from column IVa of Mendeleev's periodic table and R1 and R2 each represent alkyl groups of 1 to 20 carbon atoms or cycloalkyl or phenyl groups of 6 to 20 carbon atoms, X represents a halogen atom, L represents an optional complexing molecule, such as an ether, and optionally a substantially less complexing molecule, such as toluene, p is a natural integer greater than or equal to 1 and x is greater than or equal to 0, and (ii) a co-catalyst selected from alkylmagnesiums, alkyllithiums, alkylaluminums, Grignard reagents and mixtures of these constituents.
摘要翻译：一种可用于共聚二烯和至少一种单烯烃的催化体系，该催化体系的制备方法，使用所述催化体系制备共轭二烯和至少一种单烯烃的共聚物的方法，所述共聚物被描述。该催化体系包括：（i）由下式表示的有机金属络合物：{[P（Cp）（Fl）Ln（X）（LX）} p（1）其中Ln表示连接有配体的镧系元素包含通过式MR1R2的桥P彼此连接的环戊二烯基Cp和芴基F1基团的分子，M是门多列夫元素周期表第IVa列的元素，R 1和R 2各自表示1-20个碳原子的烷基或环烷基或苯基 6至20个碳原子的基团，X表示卤素原子，L表示任选的络合分子，例如醚，以及任选的基本上较少络合的分子，例如甲苯，p是大于或等于1的天然整数， x大于或等于0，和（ii）选自烷基镁，烷基锂，烷基铝，格氏试剂和这些组分的混合物的助催化剂。

6. 发明申请

US20090270578A1 Catalytic system for obtaining conjugated diene/mono-olefin copolymers and these copolymers 有权
标题翻译：用于获得共轭二烯/单烯烃共聚物和这些共聚物的催化体系
公开(公告)号：US20090270578A1
公开(公告)日：2009-10-29
申请号：US12453333
申请日：2009-05-07
申请人： Christophe Boisson , Vincent Monteil , Roger Spitz
发明人： Christophe Boisson , Vincent Monteil , Roger Spitz
IPC分类号： C08F236/04
CPC分类号： C08F210/00 , C08F210/02 , C08F210/06 , C08F210/14 , C08F210/16 , C08F236/04 , Y10S526/943 , C08F4/52 , C08F236/06
摘要： A catalytic system usable for the copolymerization of at least one conjugated diene and at least one monoolefin, a process for preparing this catalytic system, a process for preparing a copolymer of a conjugated diene and at least one monoolefin using said catalytic system, and said copolymer are described. This catalytic system includes: (i) an organometallic complex represented by the following formula: {[P(Cp)(Fl)Ln(X)(LX)}p (1) where Ln represents a lanthanide atom to which is attached a ligand molecule comprising cyclopentadienyl Cp and fluorenyl Fl groups linked to one another by a bridge P of the formula MR1R2, M is an element from column IVa of Mendeleev's periodic table and R1 and R2 each represent alkyl groups of 1 to 20 carbon atoms or cycloalkyl or phenyl groups of 6 to 20 carbon atoms, X represents a halogen atom, L represents an optional complexing molecule, such as an ether, and optionally a substantially less complexing molecule, such as toluene, p is a natural integer greater than or equal to 1 and x is greater than or equal to 0, and (ii) a co-catalyst selected from alkylmagnesiums, alkyllithiums, alkylaluminums, Grignard reagents and mixtures of these constituents.
摘要翻译：一种可用于共聚二烯和至少一种单烯烃的催化体系，该催化体系的制备方法，使用所述催化体系制备共轭二烯和至少一种单烯烃的共聚物的方法，所述共聚物被描述。该催化体系包括：（i）由下式表示的有机金属络合物：{[P（Cp）（Fl）Ln（X）（LX）} p（1）其中Ln表示连接有配体的镧系元素包含通过式MR1R2的桥P彼此连接的环戊二烯基Cp和芴基F1基团的分子，M是门多列夫元素周期表第IVa列的元素，R 1和R 2各自表示1-20个碳原子的烷基或环烷基或苯基 6至20个碳原子的基团，X表示卤素原子，L表示任选的络合分子，例如醚，以及任选的基本上较少络合的分子，例如甲苯，p是大于或等于1的天然整数， x大于或等于0，和（ii）选自烷基镁，烷基锂，烷基铝，格氏试剂和这些组分的混合物的助催化剂。

7. 发明申请

US20110301295A1 NOVEL COPOLYMERS WITH POLAR AND NON-POLAR OLEFIN BLOCKS 有权
标题翻译：具有极性和非极性烯烃嵌段的新型共聚物
公开(公告)号：US20110301295A1
公开(公告)日：2011-12-08
申请号：US13126369
申请日：2009-10-27
申请人： Christophe Navarro , Alexandra Leblanc , Vincent Monteil , Roger Spitz , Christophe Boisson , Jean-Pierre Broyer
发明人： Christophe Navarro , Alexandra Leblanc , Vincent Monteil , Roger Spitz , Christophe Boisson , Jean-Pierre Broyer
IPC分类号： C08F299/00 , C08F2/02 , C08F2/04 , C08F4/80
CPC分类号： C08F210/02 , C08F297/00 , C08F297/02 , C08F297/08 , C08L53/00 , C08F4/80 , C08L2666/02 , C08F220/12 , C08F212/08 , C08F220/14
摘要： The present invention relates to copolymers with polar and non-polar olefin blocks with a variable polar monomer content of 0.1 mol % to 99.9 mol %. The invention also relates to a method for obtaining copolymers with olefin blocks and vinyl polar monomer blocks, said method using a single-component catalytic system made up of an organometallic complex containing a metal belonging to groups VIII to X. Said organometallic complex is advantageously active in the medium without adding cocatalyst.
摘要翻译：本发明涉及具有0.1mol％至99.9mol％可变极性单体含量的极性和非极性烯烃嵌段的共聚物。本发明还涉及一种用烯烃嵌段和乙烯基极性单体嵌段获得共聚物的方法，所述方法使用由含有属于VIII至X族的金属的有机金属络合物组成的单组分催化体系。所述有机金属络合物有利地是活性的在不添加助催化剂的介质中。

8. 发明授权

US08796403B2 Copolymers with polar and non-polar olefin blocks 有权
标题翻译：具有极性和非极性烯烃嵌段的共聚物
公开(公告)号：US08796403B2
公开(公告)日：2014-08-05
申请号：US13126369
申请日：2009-10-27
申请人： Christophe Navarro , Alexandra Leblanc , Vincent Monteil , Roger Spitz , Christophe Boisson , Jean-Pierre Broyer
发明人： Christophe Navarro , Alexandra Leblanc , Vincent Monteil , Roger Spitz , Christophe Boisson , Jean-Pierre Broyer
IPC分类号： C08F4/80 , C08F220/10 , C08F210/00
CPC分类号： C08F210/02 , C08F297/00 , C08F297/02 , C08F297/08 , C08L53/00 , C08F4/80 , C08L2666/02 , C08F220/12 , C08F212/08 , C08F220/14
摘要： The present invention relates to copolymers with polar and non-polar olefin blocks with a variable polar monomer content of 0.1 mol % to 99.9 mol %. The invention also relates to a method for obtaining copolymers with olefin blocks and vinyl polar monomer blocks, said method using a single-component catalytic system made up of an organometallic complex containing a metal belonging to groups VIII to X. Said organometallic complex is advantageously active in the medium without adding cocatalyst.
摘要翻译：本发明涉及具有0.1mol％至99.9mol％可变极性单体含量的极性和非极性烯烃嵌段的共聚物。本发明还涉及一种用烯烃嵌段和乙烯基极性单体嵌段获得共聚物的方法，所述方法使用由含有属于VIII至X族的金属的有机金属络合物组成的单组分催化体系。所述有机金属络合物有利地是活性的在不添加助催化剂的介质中。

9. 发明授权

US07547654B2 Catalytic system for obtaining conjugated diene/monoolefin copolymers and these copolymers 有权
标题翻译：用于获得共轭二烯/单烯烃共聚物和这些共聚物的催化体系
公开(公告)号：US07547654B2
公开(公告)日：2009-06-16
申请号：US11350754
申请日：2006-02-10
申请人： Christophe Boisson , Vincent Monteil , Roger Spitz
发明人： Christophe Boisson , Vincent Monteil , Roger Spitz
IPC分类号： B01J31/22 , C08F4/52
CPC分类号： C08F210/00 , C08F210/02 , C08F210/06 , C08F210/14 , C08F210/16 , C08F236/04 , Y10S526/943 , C08F4/52 , C08F236/06
摘要： A catalytic system usable for the copolymerization of at least one conjugated diene and at least one monoolefin, a process for preparing this catalytic system, a process for preparing a copolymer of a conjugated diene and at least one monoolefin using said catalytic system, and said copolymer are described. This catalytic system includes: (i) an organometallic complex represented by the following formula: {[P(Cp)(Fl)Ln(X)(Lx)}p (1) where Ln represents a lanthanide atom to which is attached a ligand molecule comprising cyclopentadienyl Cp and fluorenyl Fl groups linked to one another by a bridge P of the formula MR1R2, M is an element from column IVa of Mendeleev's periodic table and R1 and R2 each represent alkyl groups of 1 to 20 carbon atoms or cycloalkyl or phenyl groups of 6 to 20 carbon atoms, X represents a halogen atom, L represents an optional complexing molecule, such as an ether, and optionally a substantially less complexing molecule, such as toluene, p is a natural integer greater than or equal to 1 and x is greater than or equal to 0, and (ii) a co-catalyst selected from alkylmagnesiums, alkyllithiums, alkylaluminums, Grignard reagents and mixtures of these constituents.
摘要翻译：一种可用于共聚二烯和至少一种单烯烃的催化体系，该催化体系的制备方法，使用所述催化体系制备共轭二烯和至少一种单烯烃的共聚物的方法，所述共聚物被描述。该催化体系包括：（i）由下式表示的有机金属络合物：<？in-line-formula description =“In-line formula”end =“lead”？> {[P（Cp）（Fl）Ln X）（Lx）} p（1）<？in-line-formula description =“In-line Formulas”end =“tail”？>其中Ln表示连接有包含环戊二烯基Cp和芴基的配体分子的镧系元素原子 Fl基团通过式MR1R2的桥P彼此连接，M是门多列夫元素周期表第IVa列的元素，R 1和R 2各自表示1至20个碳原子的烷基或6至20个碳的环烷基或苯基原子，X表示卤素原子，L表示任选的络合分子，例如醚，以及任选的基本上较少络合的分子，例如甲苯，p是大于或等于1的自然整数，x大于或等于至0，和（ii）选自烷基镁，烷基锂，烷基铝，格氏试剂及其混合物的助催化剂 ese成分。

10. 发明授权

US08138112B2 Controlled distribution of active sites in ziegler-natta catalyst systems 失效
标题翻译：活性位点在齐格勒 - 纳塔催化剂体系中的控制分布
公开(公告)号：US08138112B2
公开(公告)日：2012-03-20
申请号：US12296957
申请日：2007-04-04
申请人： David Ribour , Roger Spitz , Jerome Gromada , Christophe Boisson
发明人： David Ribour , Roger Spitz , Jerome Gromada , Christophe Boisson
IPC分类号： B01J31/14
CPC分类号： C08F10/00 , C08F110/02 , C08F110/06 , C08F210/16 , C08F2410/01 , C08F4/657 , C08F4/6574 , C08F2500/04 , C08F2500/15 , C08F210/14
摘要： The present invention provides a method for improving and controlling the activity of Ziegler-Natta catalyst systems.
摘要翻译：本发明提供了改善和控制齐格勒 - 纳塔催化剂体系的活性的方法。

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