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1. 发明授权

US06451930B1 Topcoat with improved adhesive qualities 失效
标题翻译：面漆具有改善的粘合性质
公开(公告)号：US06451930B1
公开(公告)日：2002-09-17
申请号：US09524830
申请日：2000-03-14
申请人： John W. Burgman , David C. Martin , Soner Kilic , Jane N. Valenta
发明人： John W. Burgman , David C. Martin , Soner Kilic , Jane N. Valenta
IPC分类号： C08G7718
CPC分类号： C08G18/6295 , C09D175/04 , C09D201/025 , C09D201/10 , C08L2666/16
摘要： A film-forming composition, typically a topcoat, having improved adhesion to certain commercially available adhesives. The composition includes a curable film-forming polymer, typically an acrylic and/or a polyester polymer, with carbamate and/or urea groups. The composition further includes a material containing one or more hydrolyzable silyl groups. The hydrolyzable silyl group-containing material optionally can be a polymeric or oligomeric. Also disclosed are a method of applying the above-described film-forming composition to a substrate and the coated article prepared by such a method.
摘要翻译：一种成膜组合物，通常为顶涂层，具有改进的粘合性。该组合物包括具有氨基甲酸酯和/或脲基团的可固化成膜聚合物，通常为丙烯酸和/或聚酯聚合物。组合物还包含含有一个或多个可水解甲硅烷基的材料。可水解的含甲硅烷基的材料任选地可以是聚合的或低聚的。还公开了将上述成膜组合物施用于通过这种方法制备的基材和涂布制品的方法。

2. 发明授权

US08513321B2 Dual cure coating compositions, methods of coating a substrate, and related coated substrates 有权
标题翻译：双重固化涂料组合物，涂布基材的方法和相关的涂布基材
公开(公告)号：US08513321B2
公开(公告)日：2013-08-20
申请号：US12940317
申请日：2010-11-05
申请人： David C. Martin , Brian K. Rearick , Christina A. Winters , Mary Ann Fuhry , Cynthia Kutchko
发明人： David C. Martin , Brian K. Rearick , Christina A. Winters , Mary Ann Fuhry , Cynthia Kutchko
IPC分类号： C08F2/52 , C08F2/42 , C08J3/28
CPC分类号： C09D4/00
摘要： Disclosed herein are dual cure coating compositions that include (a) a melamine-group containing polyethylenically unsaturated compound and (b) an acrylate-containing compound different from (a), wherein the acrylate-containing compound is present at a level sufficient to provide a cured coating layer having a glass transition temperature of 100° C. or below and a crosslink density of 20.0 mmoles/cc or below. Also disclosed are related multi-component composite coatings, coated substrates, and methods for coating a substrate.
摘要翻译：本文公开了双重固化涂料组合物，其包含（a）含三聚氰胺基团的多烯属不饱和化合物和（b）不同于（a）的含丙烯酸酯化合物，其中含丙烯酸酯化合物的含量足以提供玻璃化转变温度为100℃以下，交联密度为20.0毫摩尔/ cc以下的固化涂层。还公开了相关的多组分复合涂层，涂覆的基底和用于涂覆基底的方法。

3. 发明申请

US20120178893A1 SUBSTITUTED 3,4-PROPYLENEDIOXYTHIOPHENE MONOMERS AND 3,4-PROPYLENEDIOXYTHIOPHENE-BASED CROSSLINKERS AND POLYMERS THEREOF 失效
标题翻译：取代的3,4-丙烯基二甲苯单体和基于3,4-丙烯二氧基聚苯乙烯的交联剂及其聚合物
公开(公告)号：US20120178893A1
公开(公告)日：2012-07-12
申请号：US13215321
申请日：2011-08-23
申请人： David C. Martin , Kathleen E. Feldman
发明人： David C. Martin , Kathleen E. Feldman
IPC分类号： C08G75/06 , C08G77/28 , C07F7/18 , C07D495/04 , C07H15/26
CPC分类号： C07D495/04 , C08G61/126 , C08G2261/1424 , C08G2261/145 , C08G2261/44
摘要： Substituted 3,4-propylenedioxythiophene monomers may be prepared by reacting 3-allyl-3,4-dihydro-2H-thieno[3,4-b][1,4]dioxepine or 3,3-diallyl-3,4-dihydro-2H-thieno[3,4-b][1,4]dioxepine with a thiol having a hydrocarbyl moiety optionally containing one or more heteroatom-containing functional groups under radical addition conditions under radical addition conditions. Such monomers may be used in homo- or copolymerization processes to obtain thiophene-type polymers containing substituents (which may bear functional groups such as silane, thiol, hydroxyl, carboxylic acid, amine, sugar groups, polyoxyalkylene, and the like). Crosslinkers useful for introducing crosslinking into thiophene-type polymers may be prepared by reacting 3-allyl-3,4-dihydro-2H-thieno[3,4-b][1,4]dioxepine with a compound having two or more thiol groups under radical addition conditions.
摘要翻译：取代的3,4-亚丙二氧基噻吩单体可以通过使3-烯丙基-3,4-二氢-2H-噻吩并[3,4-b] [1,4]二氧杂环庚三烯或3,3-二烯丙基-3,4-二氢 -2H-噻吩并[3,4-b] [1,4]二氧杂环庚烯与在自由基加成条件下具有任选含有一个或多个含杂原子的官能团的烃基部分的硫醇。这些单体可用于均聚或共聚方法以获得含有取代基（可含有官能团如硅烷，硫醇，羟基，羧酸，胺，糖基，聚氧化烯等）的噻吩型聚合物。用于将交联引入噻吩型聚合物中的交联剂可以通过使3-烯丙基-3,4-二氢-2H-噻吩并[3,4-b] [1,4]二氧杂环庚烯与具有两个或更多个硫醇基的化合物根本添加条件。

4. 发明申请

US20110257504A1 BIOLOGICALLY INTEGRATED ELECTRODE DEVICES 审中-公开
标题翻译：生物集成电极装置
公开(公告)号：US20110257504A1
公开(公告)日：2011-10-20
申请号：US13085060
申请日：2011-04-12
申请人： Jeffrey L. Hendricks , Sarah Richardson-Burns , David C. Martin
发明人： Jeffrey L. Hendricks , Sarah Richardson-Burns , David C. Martin
IPC分类号： A61B5/04 , A61N1/362 , A61N1/36 , A61N1/39 , A61F11/04 , A61F9/08 , C08G75/06 , A61K38/43 , A61K47/34 , A61K31/7088 , A61K38/02 , A61K35/00 , A61K35/34 , A61K35/30 , A61K35/12 , A61K35/28 , C12N5/071 , B32B3/10 , H01B1/12 , A61N1/05
CPC分类号： A61B5/0408 , A61B2562/0217 , A61B2562/125 , A61N1/05 , A61N1/0531 , A61N1/0534 , A61N1/0536 , Y10T428/24355
摘要： Bioelectrodes having enhanced biocompatible and biomimetic features are provided. Methods of making and using the bioelectrodes are further provided. A biologically integrated bioelectrode device and method for detecting electronic signals using a bioelectrode comprising a first electrically conductive substrate and a biological component. The bioelectrode also comprises a conductive polymer electrically coupling the first electrically conductive substrate and the biological component to define a bioelectrode. The bioelectrode can transmit or receive an electrical signal between the electrically conductive substrate and the biological component and conductive polymer.
摘要翻译：提供具有增强的生物相容性和仿生特征的生物电极。进一步提供制造和使用生物电极的方法。一种生物集成生物电极装置和方法，用于使用包括第一导电基底和生物成分的生物电极检测电子信号。生物电极还包括导电聚合物，其电耦合第一导电基底和生物组分以限定生物电极。生物电极可以在导电基底和生物组分和导电聚合物之间传输或接收电信号。

5. 发明授权

US07708908B2 Carboxylic acid-modified EDOT for bioconjugation 有权
标题翻译：用于生物共轭的羧酸改性的EDOT
公开(公告)号：US07708908B2
公开(公告)日：2010-05-04
申请号：US12038138
申请日：2008-02-27
申请人： Jinsang Kim , Jae Cheol Cho , Laura K. Povlich , David C. Martin
发明人： Jinsang Kim , Jae Cheol Cho , Laura K. Povlich , David C. Martin
IPC分类号： H01B1/12 , C08G75/00 , C07D333/10 , G01N31/00
CPC分类号： C07D495/04
摘要： An electroconductive carboxylic acid functionalized monomer corresponding to Formula (I), wherein A represents a hydrogen or a carboxyl group. Polymerized monomers of Formula (I) conjugated with a biomolecule result in conjugated PEDOT polymers of Formula (III) wherein A is a hydrogen or a carboxylic acid group and B is a biomolecule selected from the group consisting of a peptide, a protein, a lipid, a carbohydrate and a polynucleotide. The biomolecule conjugated polymers can be disposed onto an electrically conductive substrate wherein the substrate has a first layer of PEDOT polymerized on a surface of the substrate and a second layer of biomolecule conjugated PEDOT polymer of Formula (III) polymerized on the first layer of PEDOT. The first and second layers form a charge transport material in electrical communication with the conductive substrate. The electrically conductive substrate further comprises a dopant.
摘要翻译：对应于式（I）的导电羧酸官能化单体，其中A表示氢或羧基。与生物分子缀合的式（I）的聚合单体导致式（III）的共轭PEDOT聚合物，其中A是氢或羧酸基团，B是选自肽，蛋白质，脂质的生物分子，碳水化合物和多核苷酸。生物分子共轭聚合物可以设置在导电基底上，其中基底具有在基底表面上聚合的第一层PEDOT和在第一层PEDOT上聚合的式（III）的生物分子共轭PEDOT聚合物的第二层。第一和第二层形成与导电基底电连通的电荷传输材料。导电衬底还包括掺杂剂。

6. 发明授权

US5888618A Fire-resistant, retroreflective structure 失效
标题翻译：耐火，回射结构
公开(公告)号：US5888618A
公开(公告)日：1999-03-30
申请号：US756391
申请日：1996-11-26
申请人： David C. Martin
发明人： David C. Martin
IPC分类号： B32B3/10 , B32B3/18 , B32B3/26 , B32B27/08 , B32B27/18 , B32B27/30 , G02B5/124 , B32B5/30
CPC分类号： G02B5/124 , B32B3/10 , B32B3/18 , Y10S428/92 , Y10S428/921 , Y10T428/24479 , Y10T428/24521 , Y10T428/2457 , Y10T428/31507 , Y10T428/3158 , Y10T428/31797 , Y10T428/31917 , Y10T428/3192 , Y10T428/31928
摘要： A fire-resistant retroreflective structure having an array of rigid retroreflective elements and a method for making the structure are disclosed. The retroreflective structure is formed of an array of rigid retroreflective elements having a first side and a second side. A transparent polymeric film is attached to the first side of the array of rigid retroreflective elements. A transparent fire-resistant outerlayer is attached to the transparent polymeric film. A flame-retardant layer is placed proximate to the second side of the array of rigid retroreflective elements. A fire-resistant polymer underlayer is attached to the flame-retardant layer. The five resistant polymer underlayer can be bonded to the transparent polymeric film through the array of rigid retroreflective elements and the flame-retardant layer.
摘要翻译：公开了具有刚性回射元件阵列的耐火逆反射结构和制造该结构的方法。回射结构由具有第一侧和第二侧的刚性回射元件的阵列形成。透明聚合物膜连接到刚性回射元件阵列的第一侧。透明耐火外层附着在透明聚合物膜上。将阻燃层放置成靠近刚性回射元件阵列的第二侧。耐火聚合物底层附着在阻燃层上。五个耐电聚合物底层可以通过刚性回射元件阵列和阻燃层结合到透明聚合物膜上。

7. 发明授权

US5831766A Retroreflective structure 失效
公开(公告)号：US5831766A
公开(公告)日：1998-11-03
申请号：US596805
申请日：1996-02-05
申请人： David C. Martin , Edward D. Phillips , William P. Rowland
发明人： David C. Martin , Edward D. Phillips , William P. Rowland
IPC分类号： B32B3/00 , G02B5/122 , G02B5/124
CPC分类号： G02B5/124 , Y10S428/913 , Y10T428/164 , Y10T428/24372 , Y10T428/24612
摘要： A retroreflective structure is described in which an array of transparent prisms is formed on a release coating of a sheet. The facet side of the prisms is made reflective and the prisms are either released to form a plurality of individual retroreflective structures or the array is adhered to a supporting substrate and then released from the base sheet. In the latter case, the array can be applied to a pre-existing structure formed of compatible fabrics, such as tarpaulins.

8. 发明授权

US5512219A Method of casting a microstructure sheet having an array of prism elements using a reusable polycarbonate mold 失效
标题翻译：使用可重复使用的聚碳酸酯模具铸造具有棱镜元件阵列的微结构片材的方法
公开(公告)号：US5512219A
公开(公告)日：1996-04-30
申请号：US253676
申请日：1994-06-03
申请人： William P. Rowland , David C. Martin
发明人： William P. Rowland , David C. Martin
IPC分类号： B29C33/38 , B29C33/42 , B29C33/56 , B29C39/14 , B29D11/00 , G02B5/124 , B29C33/40
CPC分类号： B29C33/56 , B29C33/3857 , B29C33/424 , B29C39/148 , B29D11/00605 , G02B5/124 , B29K2995/003
摘要： A durable reusable polymeric mold for casting a microstructure sheet having an array of prism elements and a method for forming the microstructure sheet are disclosed. A polymeric mold has a facet side and a base side including an array of prism elements upon which an radiation cured sheet can be formed. A protective surface layer can be formed on the facet side of the polymeric mold. The protective surface layer is sufficiently opaque to radiation to protect the polymeric mold from damage when the curable sheet is formed and is sufficiently bonded to the polymeric mold to allow the cured sheet to be removed from the protective surface layer while not substantially removing the protective surface layer from the polymeric mold. The microstructure sheet can be used as a retroreflective structure.
摘要翻译：公开了一种用于铸造具有棱镜元件阵列的微结构片的耐用的可重复使用的聚合物模具和用于形成微结构片材的方法。聚合物模具具有小面侧和底侧，其包括可以形成辐射固化片的棱镜元件阵列。可以在聚合物模具的小面上形成保护性表面层。保护性表面层与辐射完全不透明以保护聚合物模具免受损伤，当可固化片材形成时，并且充分粘合到聚合物模具上以允许固化片材从保护表面层移除，而基本不除去保护表面层。微结构片可用作回射结构。

9. 发明授权

US4801193A Retroreflective sheet material and method of making same 失效
标题翻译：逆反射片材及其制造方法
公开(公告)号：US4801193A
公开(公告)日：1989-01-31
申请号：US164184
申请日：1988-03-04
申请人： David C. Martin
发明人： David C. Martin
IPC分类号： G02B5/124 , G02B5/136
CPC分类号： G02B5/124 , Y10S359/90
摘要： A retroreflective sheeting has microretroreflective formations on one surface which are partially metallized and partially exposed to the atmosphere about them. It is produced by forming a coating on microprism surface, and this coating includes a thin metallic deposit over substantially the entire surface and a second coating material over only a portion of the surface. The coated surface is then exposed to a solvent to remove the coating from its predominant area and leave the metal deposit on only a minor portion of the area. A backing sheet is then applied over the microprisms and bonded to the retroreflective sheeting so as to leave an air interface about the predominant area of the microprisms. As a result, some light rays are retroreflected by the metal deposit and some are retroreflected by the atmosphere interface. The sheeting exhibits daytime whiteness over the bulk of its surface area.
摘要翻译：定向反光片在一个表面上具有微反射层，其部分金属化并且部分地暴露于围绕它们的气氛。其通过在微棱镜表面上形成涂层而产生，并且该涂层在基本上整个表面上包括薄的金属沉积物，并且仅在表面的一部分上包括第二涂层材料。然后将涂覆的表面暴露于溶剂以从其主要区域去除涂层，并将金属沉积物留在该区域的少部分上。然后将背衬片施加在微棱镜上并结合到回射片材上，以便在微棱镜的主要区域上留下空气界面。结果，一些光线被金属沉积物回射，一些光线被大气界面回射。该片材在其表面积的大部分表现出白天的白度。

10. 发明申请

US20220289902A1 BIOFUNCTIONAL THIOPHENE MONOMERS AND POLYMERS THEREOF FOR ELECTRONIC BIOMEDICAL DEVICES 有权
公开(公告)号：US20220289902A1
公开(公告)日：2022-09-15
申请号：US17637108
申请日：2020-08-28
申请人： David C. Martin , Samadhan Suresh Nagane , Peter Sitarik
发明人： David C. Martin , Samadhan Suresh Nagane , Peter Sitarik
IPC分类号： C08G61/12 , C07D495/04 , C07D519/00 , C07J33/00 , H01B1/12
摘要： Disclosed herein are functionalized 3,4-alkylenedioxythiophene (ADOT+) monomers represented by a chemical formula (CR1R2)(CR3R4)(CR4R6)xO2H2S, wherein x=0 or 1; wherein each of R1, R2, R3, R4, R5, and R6 is independently selected from hydrogen, a hydrocarbyl moiety, and a heteroatom-containing functional group; and wherein at least one of R1, R2, R3, R4, R5, and R6 comprises the heteroatom-containing functional group selected from an aldehyde, a maleimide, and their derivatives thereof. Also, disclosed herein are aldehyde derivatives represented by (ADOT-CH2—NH)pY and a maleimide derivative represented by (ADOT-(CH2)q—N)pZ where p=1-2 and each of Y and Z is a hydrocarbyl moiety or a biofunctional hydrocarbyl moiety. In an embodiment of the ADOT+ monomers, one of R1, R2, R3, R4, R5, and R6 is replaced by a direct bond to an amide group, an azide group, or an ester group of a biofunctional hydrocarbyl moiety. Also, disclosed herein are polymers and copolymers made therefrom.

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