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1. 发明申请

US20220289902A1 BIOFUNCTIONAL THIOPHENE MONOMERS AND POLYMERS THEREOF FOR ELECTRONIC BIOMEDICAL DEVICES 有权
公开(公告)号：US20220289902A1
公开(公告)日：2022-09-15
申请号：US17637108
申请日：2020-08-28
申请人： David C. Martin , Samadhan Suresh Nagane , Peter Sitarik
发明人： David C. Martin , Samadhan Suresh Nagane , Peter Sitarik
IPC分类号： C08G61/12 , C07D495/04 , C07D519/00 , C07J33/00 , H01B1/12
摘要： Disclosed herein are functionalized 3,4-alkylenedioxythiophene (ADOT+) monomers represented by a chemical formula (CR1R2)(CR3R4)(CR4R6)xO2H2S, wherein x=0 or 1; wherein each of R1, R2, R3, R4, R5, and R6 is independently selected from hydrogen, a hydrocarbyl moiety, and a heteroatom-containing functional group; and wherein at least one of R1, R2, R3, R4, R5, and R6 comprises the heteroatom-containing functional group selected from an aldehyde, a maleimide, and their derivatives thereof. Also, disclosed herein are aldehyde derivatives represented by (ADOT-CH2—NH)pY and a maleimide derivative represented by (ADOT-(CH2)q—N)pZ where p=1-2 and each of Y and Z is a hydrocarbyl moiety or a biofunctional hydrocarbyl moiety. In an embodiment of the ADOT+ monomers, one of R1, R2, R3, R4, R5, and R6 is replaced by a direct bond to an amide group, an azide group, or an ester group of a biofunctional hydrocarbyl moiety. Also, disclosed herein are polymers and copolymers made therefrom.

2. 发明授权

US08586702B2 Substituted 3,4-propylenedioxythiophene monomers and 3,4-propylenedioxythiophene-based crosslinkers and polymers thereof 失效
标题翻译：取代的3,4-亚丙二氧基噻吩单体和3,4-亚丙二烯基噻吩基交联剂及其聚合物
公开(公告)号：US08586702B2
公开(公告)日：2013-11-19
申请号：US13215321
申请日：2011-08-23
申请人： David C. Martin , Kathleen E. Feldman
发明人： David C. Martin , Kathleen E. Feldman
IPC分类号： C08G75/00
CPC分类号： C07D495/04 , C08G61/126 , C08G2261/1424 , C08G2261/145 , C08G2261/44
摘要： Substituted 3,4-propylenedioxythiophene monomers may be prepared by reacting 3-allyl-3,4-dihydro-2H-thieno[3,4-b][1,4]dioxepine or 3,3-diallyl-3,4-dihydro-2H-thieno[3,4-b][1,4]dioxepine with a thiol having a hydrocarbyl moiety optionally containing one or more heteroatom-containing functional groups under radical addition conditions under radical addition conditions. Such monomers may be used in homo- or copolymerization processes to obtain thiophene-type polymers containing substituents (which may bear functional groups such as silane, thiol, hydroxyl, carboxylic acid, amine, sugar groups, polyoxyalkylene, and the like). Crosslinkers useful for introducing crosslinking into thiophene-type polymers may be prepared by reacting 3-allyl-3,4-dihydro-2H-thieno[3,4-b][1,4]dioxepine with a compound having two or more thiol groups under radical addition conditions.
摘要翻译：取代的3,4-亚丙二氧基噻吩单体可以通过使3-烯丙基-3,4-二氢-2H-噻吩并[3,4-b] [1,4]二氧杂环庚三烯或3,3-二烯丙基-3,4-二氢 -2H-噻吩并[3,4-b] [1,4]二氧杂环庚烯与在自由基加成条件下具有任选含有一个或多个含杂原子的官能团的烃基部分的硫醇。这样的单体可以用于均聚或共聚方法以获得含有取代基（可以具有官能团如硅烷，硫醇，羟基，羧酸，胺，糖基，聚氧化烯等）的噻吩型聚合物。用于将交联引入噻吩型聚合物中的交联剂可以通过使3-烯丙基-3,4-二氢-2H-噻吩并[3,4-b] [1,4]二氧杂环庚烯与具有两个或更多个硫醇基的化合物根本添加条件。

3. 发明申请

US20120148848A1 POLYMERIC SUBSTRATES HAVING A THIN METAL FILM AND FINGERPRINT RESISTANT CLEAR COATING DEPOSITED THEREON AND RELATED METHODS 审中-公开
标题翻译：具有薄金属薄膜和指纹电阻透明涂层的聚合物基板及其相关方法
公开(公告)号：US20120148848A1
公开(公告)日：2012-06-14
申请号：US13050118
申请日：2011-03-17
申请人： David C. Martin , Kurt A. Humbert , Brian K. Rearick
发明人： David C. Martin , Kurt A. Humbert , Brian K. Rearick
IPC分类号： B05D7/00 , B32B27/28 , B05D1/36 , B32B15/00
CPC分类号： B05D5/067 , B05D5/083 , B05D2350/65 , Y10T428/3154 , Y10T428/31678
摘要： Disclosed are methods of coating a polymeric substrate. The methods include (a) depositing a thin metal film onto the polymeric substrate, and (b) depositing a transparent radiation curable film-forming composition onto a thin metal film, wherein the transparent radiation curable film-forming composition comprises a fluorine-containing radiation curable compound.
摘要翻译：公开了涂覆聚合物基材的方法。所述方法包括：（a）在所述聚合物基材上沉积薄金属膜，和（b）将透明的可辐射固化成膜组合物沉积到薄金属膜上，其中所述透明可辐射固化膜形成组合物包含含氟辐射可固化化合物。

4. 发明授权

US08086662B1 Distributed hypermedia method and system for automatically invoking external application providing interaction and display of embedded objects within a hypermedia document 有权
标题翻译：分布式超媒体方法和系统，用于自动调用外部应用程序，提供超媒体文档中嵌入对象的交互和显示
公开(公告)号：US08086662B1
公开(公告)日：2011-12-27
申请号：US11586918
申请日：2006-10-26
申请人： Michael D. Doyle , David C. Martin , Cheong S. Ang
发明人： Michael D. Doyle , David C. Martin , Cheong S. Ang
IPC分类号： G06F9/46 , G06F17/30 , G06F9/50
CPC分类号： G06F9/5027 , G06F9/5055 , G06F9/547 , G06F17/30899 , G06F2209/509 , G06F2209/541 , G06F2209/549
摘要： A system allowing a user of a browser program on a computer connected to an open distributed hypermedia system to access and execute an embedded program object. The program object is embedded into a hypermedia document much like data objects. The user may select the program object from the screen. Once selected the program object executes on the user's (client) computer or may execute on a remote server or additional remote computers in a distributed processing arrangement. After launching the program object, the user is able to interact with the object as the invention provides for ongoing interprocess communication between the application object (program) and the browser program. One application of the embedded program object allows a user to view large and complex multi-dimensional objects from within the browser's window. The user can manipulate a control panel to change the viewpoint used to view the image. The invention allows a program to execute on a remote server or other computers to calculate the viewing transformations and send frame data to the client computer thus providing the user of the client computer with interactive features and allowing the user to have access to greater computing power than may be available at the user's client computer.
摘要翻译：允许连接到开放式分布式超媒体系统的计算机上的浏览器程序的用户访问和执行嵌入式程序对象的系统。程序对象嵌入到超媒体文档中，非常像数据对象。用户可以从屏幕中选择程序对象。一旦被选择，程序对象在用户（客户端）计算机上执行，或者可以在分布式处理装置中的远程服务器或其他远程计算机上执行。在启动程序对象之后，用户能够与对象进行交互，因为本发明提供了应用对象（程序）和浏览器程序之间正在进行的进程间通信。嵌入式程序对象的一个应用程序允许用户从浏览器窗口内查看大而复杂的多维对象。用户可以操纵控制面板来改变用于观看图像的视点。本发明允许程序在远程服务器或其他计算机上执行以计算观看转换并将帧数据发送到客户端计算机，从而向客户端计算机的用户提供交互式特征，并允许用户访问更大的计算能力可能在用户的客户端计算机上可用。

5. 发明申请

US20090292325A1 HYBRID BIOELECTRICAL INTERFACE DEVICE 审中-公开
标题翻译：混合生物界面装置
公开(公告)号：US20090292325A1
公开(公告)日：2009-11-26
申请号：US12432343
申请日：2009-04-29
申请人： Paul S. Cederna , Brent M. Egeland , Mohammad Reza Abidian , Antonio Peramo , Melanie G. Urbancheck , Daryl A. Kipke , Sarah Richardson-Burns , David C. Martin
发明人： Paul S. Cederna , Brent M. Egeland , Mohammad Reza Abidian , Antonio Peramo , Melanie G. Urbancheck , Daryl A. Kipke , Sarah Richardson-Burns , David C. Martin
IPC分类号： A61N1/00
CPC分类号： A61F2/72 , A61F2250/0001 , A61L27/34 , A61L27/3675 , A61N1/05 , A61N1/0543 , A61N1/0551 , A61N1/36125
摘要： A hybrid bioelectrical interface (HBI) device can be an implantable device comprising an abiotic component operable to transmit charge via electrons or ions; a biological component interfacing with the neural tissue, the biological component being sourced from biologic, biologically-derived, or bio-functionalized material; and a conjugated polymer component that together provide a means to chronically interface living neural tissue with electronic devices for extended durations (e.g. greater than 10 years). In some embodiments, conjugated polymers provide a functional electrical interface for charge transfer and signal transduction between the nervous system and an electronic device (e.g. robotic prosthetic limb, retinal implant, microchip).
摘要翻译：混合生物电接口（HBI）装置可以是可植入装置，其包括可操作以经由电子或离子传递电荷的非生物成分; 与神经组织接触的生物组分，生物组分来自生物学，生物衍生的或生物功能化的材料; 共轭聚合物组分共同提供长寿命地将活体神经组织与电子装置接合以延长持续时间（例如大于10年）的手段。在一些实施方案中，共轭聚合物为神经系统和电子设备（例如机器人假肢，视网膜植入物，微芯片）之间的电荷转移和信号转导提供功能性电接口。

6. 发明授权

US06451930B1 Topcoat with improved adhesive qualities 失效
标题翻译：面漆具有改善的粘合性质
公开(公告)号：US06451930B1
公开(公告)日：2002-09-17
申请号：US09524830
申请日：2000-03-14
申请人： John W. Burgman , David C. Martin , Soner Kilic , Jane N. Valenta
发明人： John W. Burgman , David C. Martin , Soner Kilic , Jane N. Valenta
IPC分类号： C08G7718
CPC分类号： C08G18/6295 , C09D175/04 , C09D201/025 , C09D201/10 , C08L2666/16
摘要： A film-forming composition, typically a topcoat, having improved adhesion to certain commercially available adhesives. The composition includes a curable film-forming polymer, typically an acrylic and/or a polyester polymer, with carbamate and/or urea groups. The composition further includes a material containing one or more hydrolyzable silyl groups. The hydrolyzable silyl group-containing material optionally can be a polymeric or oligomeric. Also disclosed are a method of applying the above-described film-forming composition to a substrate and the coated article prepared by such a method.
摘要翻译：一种成膜组合物，通常为顶涂层，具有改进的粘合性。该组合物包括具有氨基甲酸酯和/或脲基团的可固化成膜聚合物，通常为丙烯酸和/或聚酯聚合物。组合物还包含含有一个或多个可水解甲硅烷基的材料。可水解的含甲硅烷基的材料任选地可以是聚合的或低聚的。还公开了将上述成膜组合物施用于通过这种方法制备的基材和涂布制品的方法。

7. 发明授权

US06260038B1 Clustering mixed attribute patterns 失效
标题翻译：聚合混合属性模式
公开(公告)号：US06260038B1
公开(公告)日：2001-07-10
申请号：US09394883
申请日：1999-09-13
申请人： David C. Martin , Dharmendra Shantilal Modha , Shivakumar Vaithyanathan
发明人： David C. Martin , Dharmendra Shantilal Modha , Shivakumar Vaithyanathan
IPC分类号： G06F1730
CPC分类号： G06F17/30598 , G06K9/6218 , Y10S707/99932 , Y10S707/99935 , Y10S707/99936 , Y10S707/99937 , Y10S707/99942 , Y10S707/99943
摘要： A technique for clustering data points in a data set that is arranged as a matrix having n objects and m attributes. Each categorical attribute of the data set is converted to a 1-of-p representation of the categorical attribute. A converted data set A is formed based on the data set and the 1-of-p representation for each categorical attribute. The converted data set A is compressed using, for example, a Goal Directed Projection compression technique or a Singular Value Decomposition compression technique, to obtain q basis vectors, with q being defined to be at least m+1. The transformed data set is projected onto the q basis vectors to form a data matrix having at least one vector, with each vector having q dimensions. Lastly, a clustering technique is performed on the data matrix having vectors having q dimensions.
摘要翻译：一种用于聚类数据集中的数据点的技术，其被布置为具有n个对象和m个属性的矩阵。将数据集的每个分类属性转换为分类属性的1-p表示。基于数据集和每个分类属性的1-p表示形成转换数据集A. 转换的数据集合A使用目标定向投影压缩技术或奇异值分解压缩技术进行压缩，以获得q个基本向量，其中q被定义为至少m + 1。经变换的数据集被投影到q基向量上以形成具有至少一个向量的数据矩阵，其中每个向量具有q维度。最后，对具有q维的向量的数据矩阵执行聚类技术。

8. 发明授权

US5770763A Difunctional bitricyclodecatriene monomers 失效
公开(公告)号：US5770763A
公开(公告)日：1998-06-23
申请号：US705630
申请日：1996-08-30
申请人： David C. Martin , Jeffrey S. Moore , Larry J. Markoski , Kenneth A. Walker , Gary E. Spilman
发明人： David C. Martin , Jeffrey S. Moore , Larry J. Markoski , Kenneth A. Walker , Gary E. Spilman
IPC分类号： C07C37/055 , C07C39/17 , C07C63/38 , C07C63/49 , C07C63/72 , C07C211/61 , C07C233/65 , C07C265/14 , C08G65/40 , C08G69/26 , C08G69/32 , C07C205/12
CPC分类号： C08G69/32 , C07C211/61 , C07C233/65 , C07C265/14 , C07C29/147 , C07C37/00 , C07C63/38 , C07C63/49 , C07C63/72 , C08G65/4012 , C08G69/26 , C07C2102/06 , C07C2103/08
摘要： Novel difunctionalized cyclobutabenzene monomers of the general formula: ##STR1## wherein Z can be hydrogens or a cyclobutane ring; and X and Y are carboxyl, amino, alcohol, isocyanate, acid halide, or bis-acyl halide groups. Exemplary difunctional bitricyclodecatriene monomers are �2,2'-bidicyclo�2.4.0!octa-1,3,5-triene!-5,5'-dicarboxylic acid (BXTA) and �2,2'-bitricyclo�6.2.0.0!deca-1,3,(6),7-triene!-7,7'-dicarboxylic acid (QXTA). The difunctionalized bitricyclodecatriene monomers can form part of a polymer backbone chain in which the multiple butane ring functionalities can be easily opened to produce strong, three-dimensional covalent bond crosslinking between polymer chains. The crosslinking can be induced simply by heating the polymer to a temperature in excess of 250.degree. C.

9. 发明授权

US5648145A Fire-resistant, retroreflective structure 失效
标题翻译：耐火，回射结构
公开(公告)号：US5648145A
公开(公告)日：1997-07-15
申请号：US119459
申请日：1993-09-10
申请人： David C. Martin
发明人： David C. Martin
IPC分类号： B32B3/10 , B32B3/18 , B32B3/26 , B32B27/08 , B32B27/18 , B32B27/30 , G02B5/124 , B32B5/30
CPC分类号： G02B5/124 , B32B3/10 , B32B3/18 , Y10S428/92 , Y10S428/921 , Y10T428/24479 , Y10T428/24521 , Y10T428/2457 , Y10T428/31507 , Y10T428/3158 , Y10T428/31797 , Y10T428/31917 , Y10T428/3192 , Y10T428/31928
摘要： A fire-resistant retroreflective structure having an array of rigid retroreflective elements and a method for making the structure are disclosed. The retroreflective structure is formed of an array of rigid retroreflective elements having a first side and a second side. A transparent polymeric film is attached to the first side of the array of rigid retroreflective elements. A transparent fire-resistant outerlayer is attached to the transparent polymeric film. A flame-retardant layer is placed proximate to the second side of the array of rigid retroreflective elements. A fire-resistant polymer underlayer is attached to the flame-retardant layer. The fire resistant polymer underlayer can be bonded to the transparent polymeric film through the array of rigid retroreflective elements and the flame-retardant layer.
摘要翻译：公开了具有刚性回射元件阵列的耐火逆反射结构和制造该结构的方法。回射结构由具有第一侧和第二侧的刚性回射元件的阵列形成。透明聚合物膜连接到刚性回射元件阵列的第一侧。透明耐火外层附着在透明聚合物膜上。将阻燃层放置在刚性回射元件阵列的第二侧附近。耐火聚合物底层附着在阻燃层上。耐火聚合物底层可以通过刚性回射元件阵列和阻燃层结合到透明聚合物膜上。

10. 发明授权

US5552508A Difunctional bitricyclodecatriene monomers 失效
标题翻译：双功能双环癸烯单体
公开(公告)号：US5552508A
公开(公告)日：1996-09-03
申请号：US448637
申请日：1995-05-23
申请人： David C. Martin , Jeffrey S. Moore , Larry J. Mar koski , Kenneth A. Walker , Gary E. Spilman
发明人： David C. Martin , Jeffrey S. Moore , Larry J. Mar koski , Kenneth A. Walker , Gary E. Spilman
IPC分类号： C07C37/055 , C07C39/17 , C07C63/38 , C07C63/49 , C07C63/72 , C07C211/61 , C07C233/65 , C07C265/14 , C08G65/40 , C08G69/26 , C08G69/32 , C08G63/00
CPC分类号： C08G69/32 , C07C211/61 , C07C233/65 , C07C265/14 , C07C29/147 , C07C37/00 , C07C63/38 , C07C63/49 , C07C63/72 , C08G65/4012 , C08G69/26 , C07C2102/06 , C07C2103/08
摘要： Novel difunctionalized cyclobutabenzene monomers of the general formula: ##STR1## wherein Z can be hydrogens or a cyclobutane ring; and X and Y are carboxyl, amino, alcohol, isocyanate, acid halide, or bis-acyl halide groups. Exemplary difunctional bitricyclodecatriene monomers are [2,2'-bidicyclo[2.4.0]octa-1,3,5-triene]-5,5'-dicarboxylic acid (BXTA) and [2,2'-bitricyclo[6.2.0.0]deca-1,3,(6),7-triene]-7,7'-dicarboxylic acid (QXTA). The difunctionalized bitricyclodecatriene monomers can form part of a polymer backbone chain in which the multiple butane ring functionalities can be easily opened to produce strong, three-dimensional covalent bond crosslinking between polymer chains. The crosslinking can be induced simply by heating the polymer to a temperature in excess of 250.degree. C.
摘要翻译：新的具有以下通式的二官能化环丁苯类单体：其中Z可以是氢或环丁烷环; X和Y是羧基，氨基，醇，异氰酸酯，酰卤或双酰卤基。示例性双官能双环癸三烯单体是[2,2'-双环[2.4.0]八氢-1,3,5-三烯] -5,5'-二羧酸（BXTA）和[2,2'-二环[6.2.0.0 ]癸-1,3，（6），7-三烯] -7,7'-二羧酸（QXTA）。双官能化的双环癸三烯单体可以形成聚合物主链的一部分，其中多个丁烷环官能团可以容易地打开以在聚合物链之间产生强烈的三维共价键交联。可以简单地通过将聚合物加热到超过250℃的温度来诱导交联。

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