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1. 发明授权

US06451930B1 Topcoat with improved adhesive qualities 失效
标题翻译：面漆具有改善的粘合性质
公开(公告)号：US06451930B1
公开(公告)日：2002-09-17
申请号：US09524830
申请日：2000-03-14
申请人： John W. Burgman , David C. Martin , Soner Kilic , Jane N. Valenta
发明人： John W. Burgman , David C. Martin , Soner Kilic , Jane N. Valenta
IPC分类号： C08G7718
CPC分类号： C08G18/6295 , C09D175/04 , C09D201/025 , C09D201/10 , C08L2666/16
摘要： A film-forming composition, typically a topcoat, having improved adhesion to certain commercially available adhesives. The composition includes a curable film-forming polymer, typically an acrylic and/or a polyester polymer, with carbamate and/or urea groups. The composition further includes a material containing one or more hydrolyzable silyl groups. The hydrolyzable silyl group-containing material optionally can be a polymeric or oligomeric. Also disclosed are a method of applying the above-described film-forming composition to a substrate and the coated article prepared by such a method.
摘要翻译：一种成膜组合物，通常为顶涂层，具有改进的粘合性。该组合物包括具有氨基甲酸酯和/或脲基团的可固化成膜聚合物，通常为丙烯酸和/或聚酯聚合物。组合物还包含含有一个或多个可水解甲硅烷基的材料。可水解的含甲硅烷基的材料任选地可以是聚合的或低聚的。还公开了将上述成膜组合物施用于通过这种方法制备的基材和涂布制品的方法。

2. 发明授权

US07897261B2 Surface active additives for coatings 有权
标题翻译：涂料用表面活性剂
公开(公告)号：US07897261B2
公开(公告)日：2011-03-01
申请号：US11178548
申请日：2005-07-11
申请人： John W. Burgman , Simion Coca , Edward R. Coleridge , Heather L. Lim , Karen A. Morow , Jane N. Valenta
发明人： John W. Burgman , Simion Coca , Edward R. Coleridge , Heather L. Lim , Karen A. Morow , Jane N. Valenta
IPC分类号： B32B27/32 , C08F2/00
CPC分类号： C09D143/00 , C08L33/068 , C08L2312/00 , Y10T428/31504 , Y10T428/31855 , Y10T428/31938 , C08L2666/04
摘要： A coating composition is provided comprising (a) a polymer containing reactive functional groups; (b) a curing agent having reactive functional groups that are reactive with the functional groups in the polymer in (a); and (c) a polymeric material different from (a) and (b) having functional groups. The functional groups in components (a) and (b) are more reactive with each other than with the functional groups in component (c) such that upon curing, at least a portion of the functional groups on component (c) remain unreacted. A coating layer formed from the composition upon application to a substrate has surface regions and a bulk region, and the concentration of component (c) at one or more surface regions is greater than the concentration of component (c) in the bulk region of the coating layer. The composition can be used in multi-layer composites containing two or more coating layers.
摘要翻译：提供涂料组合物，其包含（a）含有反应性官能团的聚合物; （b）具有与（a）中的聚合物中的官能团反应的反应性官能团的固化剂; 和（c）不同于具有官能团的（a）和（b）的聚合物材料。组分（a）和（b）中的官能团与组分（c）中的官能团相比更具反应性，使得在固化后，组分（c）上至少一部分官能团保持未反应。由涂布到基材上的组合物形成的涂层具有表面区域和体积区域，并且在一个或多个表面区域的组分（c）的浓度大于组分（c）在本体区域中的浓度涂层。该组合物可用于含有两层或多层涂层的多层复合材料。

3. 发明申请

US20090023862A1 SOLVENTBORNE THERMOSETTING COMPOSITIONS CONTAINING COPOLYMERS OF ISOBUTYLENE TYPE MONOMERS 审中-公开
标题翻译：含有异丁烯类单体的共聚物的溶剂热稳定剂组合物
公开(公告)号：US20090023862A1
公开(公告)日：2009-01-22
申请号：US11778820
申请日：2007-07-17
申请人： Simion Coca , Jane N. Valenta , Steve Valasek , John W. Burgman
发明人： Simion Coca , Jane N. Valenta , Steve Valasek , John W. Burgman
IPC分类号： C08F8/00 , C08J3/20
CPC分类号： C08F220/28 , C08F212/08 , C09D133/06
摘要： The present invention is directed to a solventborne thermosetting composition comprising:(a) a polymeric binder comprising a copolymer, said copolymer being a polymerization product of: (i) 10 to 30 percent by weight, based on the total weight of monomers used to prepare the copolymer, of a monomer having the following structure (I): wherein R1 comprises linear or branched C1 to C4 alkyl, and R2 comprises methyl, linear, cyclic or branched C1 to C20 alkyl or alkenyl; (ii) 5 to 25 percent by weight, based on the total weight of monomers used to prepare the copolymer, of a monomer having aromatic functionality; (iii) 0 to 60 percent by weight, based on the total weight of monomers used to prepare the copolymer, of an ethylenically unsaturated monomer containing secondary hydroxyl groups; and (iv) 15 to 50 percent by weight, based on the total weight of monomers used to prepare the copolymer, of an ethylenically unsaturated monomer containing primary hydroxyl groups; (b) an aminoplast curing agent; and(c) a compound comprising a capped isocyanate-functional material.
摘要翻译：本发明涉及一种溶剂型热固性组合物，其包含：（a）包含共聚物的聚合物粘合剂，所述共聚物是聚合产物，其聚合产物为：（i）基于用于制备的单体总重量的10至30重量％该共聚物具有以下结构（I）的单体：其中R 1包含直链或支链C 1至C 4烷基，R 2包括甲基，直链，环状或支链C 1至C 20烷基或链烯基; （ii）基于用于制备共聚物的单体的总重量，5至25重量％的具有芳族官能团的单体; （iii）基于用于制备共聚物的单体的总重量，0至60重量％的含有仲羟基的烯属不饱和单体; 和（iv）基于用于制备共聚物的单体的总重量为15〜50重量％的含有伯羟基的烯属不饱和单体; （b）氨基塑料固化剂; 和（c）包含封端的异氰酸酯官能材料的化合物。

4. 发明授权

US07329468B2 Multi-layer composites formed from compositions having improved adhesion, coating compositions, and methods related thereto 有权
标题翻译：由具有改进的粘附性，涂层组合物和与其相关的方法的组合物形成的多层复合材料
公开(公告)号：US07329468B2
公开(公告)日：2008-02-12
申请号：US10935643
申请日：2004-09-07
申请人： Lawrence G. Anderson , John W. Burgman , Karen A. Morow , Richard J. Sadvary , Shiryn Tyebjee , Dennis A. Simpson , Thomas R. Hockswender
发明人： Lawrence G. Anderson , John W. Burgman , Karen A. Morow , Richard J. Sadvary , Shiryn Tyebjee , Dennis A. Simpson , Thomas R. Hockswender
IPC分类号： B32B9/04
CPC分类号： B05D7/57 , B05D7/574 , C08J5/12 , C08K3/38 , C08K5/55 , C09D7/60 , Y10T428/31511 , Y10T428/31663 , Y10T428/31725 , Y10T428/31786 , Y10T428/31935
摘要： The present invention provides an improved multi-layer composite of two or more polymeric layers at least one of which is formed from a thermosetting composition. The composite includes at least a first polymeric layer formed on a substrate and a second polymeric layer over the first polymeric layer, wherein in the absence of a boron-containing compound, the first and second polymeric layers have poor interlayer adhesion. The improvement resides in the inclusion of at least one boron-containing compound in one or both of the first and second polymeric layers in an amount sufficient to improve the interlayer adhesion between the first and second polymeric layers. Also provided is an improved curable coating composition used to form a multi-layer composite coating of two or more cured coating layers, at least one of which is formed from the thermosetting composition. Related methods and coated substrates are also provided.
摘要翻译：本发明提供了两种或更多种聚合物层的改进的多层复合材料，其中至少一种由热固性组合物形成。所述复合材料包括形成在基材上的至少第一聚合物层和在所述第一聚合物层上的第二聚合物层，其中在不存在含硼化合物的情况下，所述第一和第二聚合物层具有差的层间粘合性。改进在于在足以改善第一和第二聚合物层之间的层间粘合力的量中将至少一种含硼化合物包含在第一和第二聚合物层的一个或两个中。还提供了一种改进的可固化涂料组合物，其用于形成两层或多层固化涂层的多层复合涂层，其中至少一层由热固性组合物形成。还提供了相关方法和涂覆的基底。

5. 发明授权

US07172809B2 Coating compositions comprising silyl blocked components, coatings, coated substrates and methods related thereto 失效
标题翻译：包含甲硅烷基封端组分，涂层，涂覆基材和与其有关的方法的涂料组合物
公开(公告)号：US07172809B2
公开(公告)日：2007-02-06
申请号：US10642826
申请日：2003-08-19
申请人： Steven V. Barancyk , John W. Burgman , James B. O'Dywer , Laura A. Kiefer-Liptak , Michael Allen Mayo , Gregory J. McCollum , Shiryn Tyebjee
发明人： Steven V. Barancyk , John W. Burgman , James B. O'Dywer , Laura A. Kiefer-Liptak , Michael Allen Mayo , Gregory J. McCollum , Shiryn Tyebjee
IPC分类号： B32B5/16
CPC分类号： C09D201/06 , C08G18/4692 , C08G18/792 , C09D167/00 , C09D175/04 , Y10T428/25 , Y10T428/251 , Y10T428/254 , Y10T428/2991 , Y10T428/2993 , Y10T428/2998 , Y10T428/31511 , Y10T428/31551 , C08L2666/28 , C08L2666/16
摘要： Coating compositions formed from at least one hydroxyl functional non-vinyl material comprising at least one alcoholic hydroxyl group blocked with a hydrolyzable silyl group, and at least one curing agent are provided by the present invention. Another embodiment of the present invention is directed to a coating composition formed from components comprising at least one carbamate functional material comprising at least one carbamate group blocked with a hydrolyzable silyl group, and at least one curing agent. Another embodiment of the present invention is directed to a coating composition formed from components comprising at least one carboxyl functional material comprising at least one carboxyl group blocked with a hydrolyzable silyl group, and at least one curing agent. Another embodiment of the present invention is directed to a coating composition formed from components comprising at least one amide functional material comprising at least one amide blocked with a hydrolyzable silyl group, and at least one curing agent. Other embodiments of the present invention are directed to substrates coated with the aforementioned cured compositions. Also provided are multi-component composite coatings which include a cured basecoat deposited from a pigmented coating composition and a cured topcoat deposited from a topcoating composition. The multi-component composite coatings of the invention provide highly scratch resistant color-plus-clearcoatings. Further embodiments of the present invention are directed to methods for improving scratch resistance of a substrate.
摘要翻译：由至少一种包含至少一个用可水解甲硅烷基封端的醇羟基的羟基官能非乙烯基材料形成的涂料组合物和至少一种固化剂由本发明提供。本发明的另一个实施方案涉及由包含至少一种氨基甲酸酯官能材料的组分形成的涂料组合物，所述氨基甲酸酯官能材料包含至少一个被可水解甲硅烷基封端的氨基甲酸酯基团和至少一种固化剂。本发明的另一个实施方案涉及由包含至少一种包含至少一个被可水解甲硅烷基封端的羧基的羧基官能材料和至少一种固化剂的组分形成的涂料组合物。本发明的另一个实施方案涉及由包含至少一种酰胺官能材料的组分形成的涂料组合物，所述酰胺官能材料包含至少一个用可水解甲硅烷基封端的酰胺和至少一种固化剂。本发明的其它实施方案涉及用上述固化组合物涂覆的基材。还提供了多组分复合涂层，其包括由着色涂料组合物沉积的固化底涂层和从表面涂层组合物沉积的固化顶涂层。本发明的多组分复合涂层提供高耐刮擦的彩色 - 透明涂层。本发明的其它实施方案涉及用于改善基材的耐刮擦性的方法。

6. 发明授权

US06635341B1 Coating compositions comprising silyl blocked components, coating, coated substrates and methods related thereto 失效
标题翻译：包含甲硅烷基封端组分，涂层，涂覆基材和与之有关的方法的涂料组合物
公开(公告)号：US06635341B1
公开(公告)日：2003-10-21
申请号：US09629421
申请日：2000-07-31
申请人： Steven V. Barancyk , John W. Burgman , James B. O'Dywer , Laura A. Kiefer-Liptak , Michael Allen Mayo , Gregory J. McCollum , Shiryn Tyebjee
发明人： Steven V. Barancyk , John W. Burgman , James B. O'Dywer , Laura A. Kiefer-Liptak , Michael Allen Mayo , Gregory J. McCollum , Shiryn Tyebjee
IPC分类号： B32B516
CPC分类号： C09D201/06 , C08G18/4692 , C08G18/792 , C09D167/00 , C09D175/04 , Y10T428/25 , Y10T428/251 , Y10T428/254 , Y10T428/2991 , Y10T428/2993 , Y10T428/2998 , Y10T428/31511 , Y10T428/31551 , C08L2666/28 , C08L2666/16
摘要： Coating compositions formed from at least one hydroxyl functional non-vinyl material comprising at least one alcoholic hydroxyl group blocked with a hydrolyzable silyl group, and at least one curing agent are provided by the present invention. Another embodiment of the present invention is directed to a coating composition formed from components comprising at least one carbamate functional material comprising at least one carbamate group blocked with a hydrolyzable silyl group, and at least one curing agent. Another embodiment of the present invention is directed to a coating composition formed from components comprising at least one carboxyl functional material comprising at least one carboxyl group blocked with a hydrolyzable silyl group, and at least one curing agent. Another embodiment of the present invention is directed to a coating composition, formed from components comprising at least one amide functional material comprising at least one amide blocked with a hydrolyzable silyl group, and at least one curing agent. Other embodiments of the present invention are directed to substrates coated with the aforementioned cured compositions. Also provided are multi-component composite coatings which include a cured basecoat deposited from a pigmented coating composition and a cured topcoat deposited from a topcoating composition. The multi-component composite coatings of the invention provide highly scratch resistant color-plus-clearcoatings. Further embodiments of the present invention are directed to methods for improving scratch resistance of a substrate.
摘要翻译：由至少一种包含至少一个用可水解甲硅烷基封端的醇羟基的羟基官能非乙烯基材料形成的涂料组合物和至少一种固化剂由本发明提供。本发明的另一个实施方案涉及由包含至少一种氨基甲酸酯官能材料的组分形成的涂料组合物，所述氨基甲酸酯官能材料包含至少一个被可水解甲硅烷基封端的氨基甲酸酯基团和至少一种固化剂。本发明的另一个实施方案涉及由包含至少一种包含至少一个被可水解甲硅烷基封端的羧基的羧基官能材料和至少一种固化剂的组分形成的涂料组合物。本发明的另一个实施方案涉及由包含至少一种酰胺官能材料的组分形成的涂料组合物，所述酰胺官能材料包含至少一个用可水解甲硅烷基封端的酰胺和至少一种固化剂。本发明的其它实施方案涉及用上述固化组合物涂覆的基材。还提供了多组分复合涂层，其包括由着色涂料组合物沉积的固化底涂层和从表面涂层组合物沉积的固化顶涂层。本发明的多组分复合涂层提供高耐刮擦的彩色 - 透明涂层。本发明的其它实施方案涉及用于改善基材的耐刮擦性的方法。

7. 发明授权

US5709950A Color-plus-clear composite coatings that contain polymers having carbamate functionality 失效
标题翻译：含有透明复合涂层，含有具有氨基甲酸酯官能团的聚合物
公开(公告)号：US5709950A
公开(公告)日：1998-01-20
申请号：US770196
申请日：1996-12-19
申请人： John W. Burgman , Gina M. Terrago , Christopher A. Verardi
发明人： John W. Burgman , Gina M. Terrago , Christopher A. Verardi
IPC分类号： C08G18/46 , C08G18/50 , C08G65/333 , C08G71/00 , C08L61/20 , C08L71/02 , C09D171/02 , C09D201/06 , C08L61/32 , C08L71/08
CPC分类号： C09D171/02 , C08G18/4615 , C08G18/5045 , C08G65/33344 , C08G71/00 , C08L71/02 , C09D201/06 , C08L61/20 , Y10T428/31551 , Y10T428/31565 , Y10T428/31573 , Y10T428/31786 , Y10T428/31794 , Y10T428/31797 , Y10T428/31855 , Y10T428/31909 , Y10T428/31942
摘要： Flexible, aminoplast-curable film-forming compositions and multi-component composite coating compositions comprising at least one pigmented or colored base coat and at least one transparent clear coat are disclosed. A pigmented or colored base coat is first applied to a substrate followed by the application of a clear coat to the base coat. Both the colored base coat and the clear coat are flexible, curable film-forming compositions having an aminoplast crosslinking agent, and the base coat and optionally the clear coat has carbamate functional polymers. The flexible, multi-component composite coating compositions provide improved durability, water spotting resistance, and/or acid etch resistance, making the composite coatings particularly useful for plastic automotive parts.
摘要翻译：公开了柔性的氨基塑料固化成膜组合物和包含至少一种着色或着色底涂层和至少一个透明透明涂层的多组分复合涂料组合物。首先将着色或着色的底涂层施加到基底上，然后向基底涂层施加透明涂层。着色底涂层和透明涂层均为具有氨基塑料交联剂的柔性可固化成膜组合物，底涂层和任选的透明涂层具有氨基甲酸酯官能聚合物。柔性多组分复合涂料组合物提供改进的耐久性，耐水渍性和/或耐酸蚀性，使复合涂料对塑料汽车部件特别有用。

8. 发明授权

US06268055B1 Photochromic epoxy resin coating composition and articles having such a coating 有权
标题翻译：光致变色环氧树脂涂料组合物和具有这种涂层的制品
公开(公告)号：US06268055B1
公开(公告)日：2001-07-31
申请号：US09187698
申请日：1998-11-06
申请人： Robert W. Walters , Cletus N. Welch , John W. Burgman , Debra L. Singer , Shanti Swarup
发明人： Robert W. Walters , Cletus N. Welch , John W. Burgman , Debra L. Singer , Shanti Swarup
IPC分类号： C08G5942
CPC分类号： C09D163/00 , G02B5/23 , Y10T428/31511 , C08L2666/28
摘要： Described are photochromic epoxy resin coatings that meet commercially acceptable “cosmetic” standards for optical coatings. Also described are articles having such coatings. The coatings exhibit a Fischer microhardness of from 50 to 150 Newtons per mm2 and desirable photochromic properties, i.e., the formation of darker activated colors and faster rates of photochromic activation and fade when irradiated with ultraviolet light.
摘要翻译：描述了满足商业上可接受的用于光学涂层的“化妆品”标准的光致变色环氧树脂涂料。还描述了具有这种涂层的制品。涂层表现出每毫米50至150牛顿的菲舍尔显微硬度和所需的光致变色性质，即，当用紫外线照射时，形成更暗的活化颜色和更快的光致变色激活速率和褪色。

9. 发明授权

US5965670A Curable-film forming compositions having improved mar and acid etch resistance 失效
标题翻译：具有改善的抗酸蚀蚀性的可固化成膜组合物
公开(公告)号：US5965670A
公开(公告)日：1999-10-12
申请号：US72472
申请日：1998-05-04
申请人： George W. Mauer , William E. Michael , John W. Burgman , Leigh-Ann Humbert
发明人： George W. Mauer , William E. Michael , John W. Burgman , Leigh-Ann Humbert
IPC分类号： C08L33/14 , C08K5/3492 , C08L61/20 , C08L61/32 , C09D133/00 , C09D133/06 , C09D133/14 , C09D161/20 , C08G79/02
CPC分类号： C09D133/066 , C08L61/20 , C08L61/32
摘要： Curable film-forming compositions comprising acrylic polyols, aminoplast and carbamoyl triazines are disclosed. The compositions are useful as clear coats in composite color-plus-clear coatings.
摘要翻译：公开了包含丙烯酸多元醇，氨基塑料和氨基甲酰基三嗪的可固化成膜组合物。该组合物可用作复合颜色 - 透明涂层中的透明涂层。

10. 发明授权

US06592998B2 Multi-layer composites formed from compositions having improved adhesion, coating compositions, and methods related thereto 失效
公开(公告)号：US06592998B2
公开(公告)日：2003-07-15
申请号：US09919095
申请日：2001-07-31
申请人： Lawrence G. Anderson , John W. Burgman , Karen A. Morow , Richard J. Sadvary , Roger L. Scriven , Shiryn Tyebjee , Dennis A. Simpson , Thomas R. Hockswender
发明人： Lawrence G. Anderson , John W. Burgman , Karen A. Morow , Richard J. Sadvary , Roger L. Scriven , Shiryn Tyebjee , Dennis A. Simpson , Thomas R. Hockswender
IPC分类号： B32B904
CPC分类号： C09D183/06 , B05D7/57 , B05D7/576 , C08L33/08 , C08L83/00 , C08L83/04 , C08L2666/52 , C09D133/08 , C09J133/08 , Y10T428/31504 , Y10T428/31551 , Y10T428/31663 , Y10T428/31667
摘要： Improved multi-layer composites are provided. The multi-layer composites include at least a first polymeric layer and a second polymeric layer formed over the first polymeric layer thereby forming an interface region there between. At least one of the polymeric layers is formed from a thermosetting composition which contains an adhesion promoter composition. The adhesion promoter composition is formed from (1) at least one adhesion promoting component, and (2) at least one surface active component. The improvement is represented by the presence of the adhesion promoting component (1) at the interface region.

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