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    • 9. 发明申请
    • Silica Sol
    • 二氧化硅溶胶
    • US20160176719A1
    • 2016-06-23
    • US14910330
    • 2014-08-20
    • AKZO NOBEL CHENICALS INTERNATIONAL B.V.
    • Erik SanneFreddie Hansson
    • C01B33/143D21H21/10D21H17/37C01B33/14D21H17/68
    • C01B33/143C01B33/14C01B33/141C01B33/142C01B33/145D21H17/375D21H17/68D21H19/40D21H21/10
    • The present invention relates to a silica sol having a pH above about 10, molar ratio of Si02:M20, in which M is alkali metal, of from about 6:1 to about 16:1, concentration of soluble silica above about 3000 mg Si02/l, and S-value of from about 18 to about 40%. The invention further relates to a process for producing a silica sol which comprises acidifying an aqueous alkali metal silicate solution to a pH of from 1 to 4 to form an acid sol, alkalizing the acid sol by addition of aqueous alkali metal silicate solution to obtain an intermediate sol and interrupt the addition of aqueous alkali metal silicate solution when the intermediate sol has reached a pH of from about 5 to about 8, stirring the intermediate sol for a time period of from about 10 to about 6000 seconds without addition of aqueous alkali metal silicate solution, alkalizing the intermediate sol by addition of aqueous alkali metal silicate solution to obtain a silica sol having a pH above about 10 and molar ratio of Si02:M20, in which M is alkali metal, of from about 6:1 to about 16:1, and optionally adding an aluminum compound to the acid sol, intermediate sol or silica sol. The invention further relates to a silica sol obtainable by the process of the invention. The invention further relates to the use of the silica sol as a flocculating agent, in water purification and in producing paper and board. The invention further relates to a process for producing paper and board which comprises: (i) providing an aqueous suspension comprising cellulosic fibers; (ii) adding to the suspension one or more drainage and retention aids comprising the silica sol; and (iii) dewatering the obtained suspension to provide a sheet or web of paper or board.
    • 本发明涉及pH高于约10,SiO 2 :M 2 O摩尔比(其中M为碱金属)为约6:1至约16:1的二氧化硅溶胶,高于约3000mg SiO 2的可溶性二氧化硅浓度 / l,S值为约18至约40%。 本发明还涉及二氧化硅溶胶的制造方法,其包括将碱金属硅酸盐水溶液酸化至1〜4的pH以形成酸性溶胶,通过加入碱金属硅酸盐水溶液碱化酸性溶胶,得到 中间溶胶,并且当中间溶胶达到约5至约8的pH时中断加入碱金属硅酸盐水溶液,在不加入碱金属水溶液的情况下搅拌中间溶胶约10至约6000秒的时间 硅酸盐溶液,通过加入碱金属硅酸盐水溶液碱化中间体溶胶,得到pH高于约10的硅溶胶,其中M为碱金属的SiO 2 :M 2 O的摩尔比为约6:1至约16 :1,并且任选地向酸性溶胶,中间溶胶或二氧化硅溶胶中加入铝化合物。 本发明还涉及通过本发明的方法获得的二氧化硅溶胶。 本发明还涉及二氧化硅溶胶作为絮凝剂,在水净化和生产纸和纸板中的用途。 本发明还涉及生产纸和纸板的方法,其包括:(i)提供包含纤维素纤维的水性悬浮液; (ii)向悬浮液中加入一种或多种包含二氧化硅溶胶的排水和助留剂; 和(iii)对获得的悬浮液进行脱水以提供纸张或纸板或纸板。