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    • 7. 发明申请
    • REFERENCE SAMPLE FOR ANALYSIS
    • 参考样本分析
    • US20160103106A1
    • 2016-04-14
    • US14868840
    • 2015-09-29
    • SHIMADZU CORPORATION
    • Fumitaka MARUYAMAShigehiko FUJIMAKI
    • G01N30/72G01N30/04
    • G01N30/7206G01N30/04G01N30/12G01N2030/042G01N2030/125H01J49/0009
    • A reference sample for analysis that is optimal for calibration of a pyrolysis gas chromatograph-mass spectrometer and with which precise calibration is always possible by preventing a reference substance from evaporating is provided. A reference sample sheet 1 is provided by distributing a target component or target components with a uniform normality in a base made of a high polymer material, and the reference sample sheet 1 is rolled up so that the target component or target components can be prevented from evaporating from the reference sample sheet 1 even in the case where a component has volatility. A reference sample for calibration of a pyrolysis gas chromatograph-mass spectrometer can be easily, quickly, and efficiently collected by punching out the reference sample sheet 1 using a micro-puncher 2.
    • 提供了用于分析的参考样品,用于热解气相色谱 - 质谱仪的校准,并通过防止参考物质蒸发而始终可以进行精确校准。 参考样品片1通过在由高分子材料制成的基底中分散具有均匀正常性的目标组分或目标组分而提供,并且卷起参考样品片1,从而可以防止目标组分或目标组分 即使在组分具有挥发性的情况下也从参考样品片1蒸发。 用于校准热解气相色谱 - 质谱仪的参考样品可以通过使用微型打孔机2冲压参考样品片1而容易,快速并有效地收集。
    • 9. 发明授权
    • Sample introduction device including channel switching mechanism
    • 样品引入装置包括通道切换机构
    • US09274030B2
    • 2016-03-01
    • US14169733
    • 2014-01-31
    • SHIMADZU CORPORATION
    • Akira Aono
    • G01N1/22G01N30/12G01N30/02
    • G01N1/2202G01N30/12G01N2001/2282G01N2030/025G01N2030/128
    • A sample introduction device having a channel configuration which allows recapture of samples and in which thorough purging is performed so that no sample components remain inside the channel. In the trap capture process, a first six-way switching valve is placed in state where ports a-f, b-c and d-e are connected, a second six-way switching valve is placed in state where ports a-b, c-d and e-f are connected, and an electromagnetic valve is opened. Carrier gas is introduced through a carrier gas channel, and is discharged via the first six-way valve-sample channel-second six-way switching valve-trap channel-second six-way switching valve-channel-first six-way valve-discharge channel. Carrier gas is also introduced through the path going through the electronic control flow controller, so the operation of stabilization of the analysis channel continues to be performed.
    • 具有通道结构的样品引入装置,其允许重新捕获样品,并且进行彻底清洗,使得通道内不残留样品成分。 在陷阱捕获过程中,将第一六通切换阀置于端口af,bc和de连接的状态,将第二六通切换阀置于端口ab,cd和ef连接的状态, 电磁阀打开。 载气通过载气通道引入,并通过第一六通阀样通道 - 第二六通切换阀 - 捕集通道 - 第二六通切换阀 - 通道 - 第一六通阀 - 排出 渠道。 载气也通过电子控制流量控制器的路径引入,因此继续执行分析通道的稳定运行。