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    • 8. 发明申请
    • HOLOGRAPHIC MEDIA WITH IMPROVED LIGHT SENSITIVITY
    • 具有改善光敏性的全息图
    • US20160320695A1
    • 2016-11-03
    • US15105138
    • 2014-12-16
    • COVESTRO DEUTSCHLAND AG
    • Thomas RÖLLEHorst BERNETHFriedrich-karl BRUDERDennis HÖNELThomas FÄCKEGünther WALZERainer HAGENChristian DIEDRICH
    • G03F7/00G03F7/035G03H1/02G03F7/029
    • G03F7/001G02B1/04G03F7/0046G03F7/027G03F7/029G03F7/035G03H1/02G03H2001/0264G03H2260/12G11B7/24044C08L75/04
    • The present invention provides a novel photopolymer formulation comprising matrix polymers, writing monomer and a photoinitiator and further comprising a compound of formula (1) where A1, A2 and A3 are each independently hydrogen, fluorine, chlorine, bromine or iodine, R1, R2, R3, R4 and R5 are each independently hydrogen, halogen, cyano, nitro, amino, alkylimino, azide, isonitrile, enamino, formyl, acyl, carboxyl, carboxylate, carboxamide, orthoester, sulphonate, phosphate, organosulphonyl, organosulphoxidyl, optionally fluorinated alkoxy or an optionally substituted aromatic, heteroaromatic, aliphatic, araliphatic, olefinic or acetylenic radical while suitable radicals may be connected together via bridge of any desired substitution, or in that two or more compounds of formula (I) may be connected together via at least one of the radicals R1, R2, R3, R4 and R5, in which case these radicals therein constitute a 2- to 4-tuply functional bridge, with the proviso that at least one of the radicals R1, R2, R3, R4 and R5 is not hydrogen. Further subjects of the invention are a photopolymer comprising matrix polymers, a writing monomer and photoinitiator, a holographic medium comprising a photopolymer formulation of the present invention or being obtainable by use thereof, the use of a holographic medium of the present invention and also a process for producing a holographic medium by using a photopolymer formulation of the present invention.
    • 其中A1,A2和A3各自独立地为氢,氟,氯,溴或碘,R1,R2,R3,R4和R5各自独立地为氢,卤素,氰基,硝基,氨基,烷基亚氨基,叠氮化物,异腈,烯氨基,甲酰基 酰基,羧基,羧酸酯,羧酰胺,原酸酯,磺酸酯,磷酸酯,有机磺酰基,有机磺基,任选氟化的烷氧基或任选取代的芳族,杂芳族,脂族,芳脂族,烯属或炔基,而合适的基团可以通过任何所需的桥 或者其中两个或更多个式(I)化合物可以通过基团R 1,R 2,R 3,R 4和R 5中的至少一个连接在一起,在这种情况下,这些基团在其中构成2-至4-元组的官能团 桥,条件是基团R 1,R 2,R 3,R 4和R 5中的至少一个不是氢。 本发明的另外的主题是包含基质聚合物,书写单体和光引发剂的光聚合物,包含本发明的光聚合物制剂或可通过其使用获得的全息介质,使用本发明的全息介质以及方法 用于通过使用本发明的光聚合物制剂来生产全息介质。