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1. 发明授权

US4325888A Preparation of peracid by liquid-liquid extraction 失效
标题翻译：通过液 - 液萃取制备过酸
公开(公告)号：US4325888A
公开(公告)日：1982-04-20
申请号：US151817
申请日：1980-05-21
申请人： Anthony M. Hildon
发明人： Anthony M. Hildon
IPC分类号： B01D11/04 , C07C409/24 , C07C409/26 , C07C179/10
CPC分类号： B01D11/04 , C07C407/00 , C07C407/003
摘要： The invention provides a process and apparatus for liquid-liquid extraction in which a first liquid phase is passed continuously through a series of extraction stages (10) while a second liquid phase is passed continuously through the series in counter-current to the first phase. In each stage the second phase is dispersed as by a sieve plate (11) and then allowed to coalesce into a settled body (14) from which the second phase is withdrawn and passed to the next adjacent stage. The invention is characterized by the fact that the flows of the two phases in each stage are generally transverse to each other. Preferably the first phase flows through the series of stages under gravity while the second phase is pumped (16) from stage to stage to control its inter-stage transfer.The invention combines the features of separate control of residence time characteristics of an extraction column with the safety aspects inherent in a mixer/settler battery.
摘要翻译：本发明提供了一种用于液 - 液萃取的方法和装置，其中第一液相连续通过一系列萃取级（10），而第二液相通过与第一相逆流连续通过该级串联。在每个阶段中，第二阶段通过筛板（11）分散，然后使其聚结成沉降体（14），第二阶段从其中取出并传递到下一相邻阶段。本发明的特征在于，每个阶段中的两相的流动通常彼此横向。优选地，第一阶段在重力作用下流过一系列阶段，而第二阶段从阶段泵送到阶段（16）以控制其阶段间转移。本发明将提取塔的停留时间特性的单独控制的特征与混合器/沉降池电池中固有的安全方面相结合。

2. 发明授权

US4267124A Process for the manufacture of carboxylic peracids 失效
标题翻译：制造羧酸过酸的方法
公开(公告)号：US4267124A
公开(公告)日：1981-05-12
申请号：US24372
申请日：1979-03-27
申请人： Nicolas Hardy , Luc Lerot , Rene Walraevens
发明人： Nicolas Hardy , Luc Lerot , Rene Walraevens
IPC分类号： C07C67/00 , C07C407/00 , C07C409/24 , C07C409/26 , C07D301/14 , C07C179/10 , C07C179/12
CPC分类号： C07D301/14 , C07C407/00 , C07C407/003 , C07C409/24
摘要： A continuous process for the manufacture of carboxylic peracids by reacting the corresponding carboxylic acid with hydrogen peroxide in the presence of a catalyst and in the presence of an inert organic liquid which is a solvent for the peracid and is capable of forming a heterogeneous azeotrope with water, removing the water present in the reaction mixture by distillation of the water/organic liquid azeotrope, and keeping sufficient water in the reaction mixture to allow the formation of an aqueous phase which is separate from an organic phase containing the organic liquid.
摘要翻译：通过在催化剂存在下和在作为过酸的溶剂的惰性有机液体的存在下使相应的羧酸与过氧化氢反应并且能够与水形成非均相共沸物的方法来制备羧酸过酸的连续方法通过蒸馏水/有机液体共沸物除去存在于反应混合物中的水，并在反应混合物中保持足够的水以允许形成与含有机液体的有机相分开的水相。

3. 发明授权

US4152352A Process for the carbonylation of aralkylhalides 失效
标题翻译：亚油酸碱化过程
公开(公告)号：US4152352A
公开(公告)日：1979-05-01
申请号：US647809
申请日：1976-01-09
申请人： Robert Perron
发明人： Robert Perron
IPC分类号： C07C69/017 , B01J21/00 , B01J31/26 , C07B61/00 , C07C29/80 , C07C29/86 , C07C51/00 , C07C51/10 , C07C59/76 , C07C67/00 , C07C205/56 , C07C255/57 , C07C179/10
CPC分类号： B01J31/20 , B01J31/26 , C07C29/80 , C07C29/86 , C07C51/10 , B01J2231/34 , B01J2531/0208 , B01J2531/84 , B01J2531/845 , C07C2101/16
摘要： A process for the production of arylpyruvic acids which comprises reacting an arylmethylhalide in a liquid solvent medium with carbon monoxide at pressures of 5 to 200 bars in the presence of a catalytic amount of a metal carbonyl compound and an alkaline earth metal inorganic base.

4. 发明授权

US4088676A Process for the preparation of organic solutions of percarboxylic acids 失效
公开(公告)号：US4088676A
公开(公告)日：1978-05-09
申请号：US678825
申请日：1976-04-28
申请人： Willi Hofen , Gunter Prescher , Gerd Siekmann , Gunter Wolf
发明人： Willi Hofen , Gunter Prescher , Gerd Siekmann , Gunter Wolf
IPC分类号： B01D3/00 , C07C67/00 , C07C407/00 , C07C409/24 , C07C409/26 , C07C179/10
CPC分类号： C07C409/24 , C07C407/00 , C07C407/003 , Y10S203/06
摘要： A process for the continuous preparation of organic solutions of percarboxylic acids by reaction of an aqueous solution of hydrogen peroxide with the corresponding carboxylic acid in the presence of an acid, water-soluble catalyst which boils above 160.degree. C., extraction of the percarboxylic acid from the resulting reaction mixture using an organic solvent which is immiscible with water, reconcentration of the raffinate, which essentially contains hydrogen peroxide and the acid catalyst, by distilling off water in a distillation column and recycle of the raffinate, concentrated in this way, into the reaction with the carboxylic acid. The raffinate is divided into two partial streams in a ratio of 1 to 25:1. The raffinate is fed to a distillation column which is operated under reduced pressure and which has at least two take-off weirs as tray inserts, the first take-off weir being at least two theoretical plates above the sump phase, the second take-off weir being arranged at least two theoretical plates above the first take-off weir and the section of column between the second take-off weir and the top of the column having at least two theoretical plates. The larger partial stream of the raffinate is passed into the column below the first take-off weir and the smaller partial stream is passed into the column below the second take-off weir. Water is removed at the top of the distillation column. A first side stream, which essentially contains the hydrogen peroxide from the small partial stream of the raffinate from the extraction, is withdrawn from the second take-off weir and is a 2 to 40% strength by weight aqueous solution of hydrogen peroxide, which is optionally fed, together with the larger partial stream of the raffinate from the extraction, into the column below the first take-off weir. A second side stream is withdrawn from the first take-off weir and is an aqueous solution of the acid catalyst which optionally can be further worked up and re-used. The re-concentrated aqueous solution of hydrogen peroxide and acid catalyst, withdrawn as a sump product from the distillation, is recycled into the reaction with carboxylic acid. A third side stream can be taken from a third take-off weir which is arranged not more than 2 theoretical plates below the first take-off weir.The following applications are related to the process hereof for production of propylene oxide as being directed to aspects of the process, some of which are disclosed herein.______________________________________ German Serial U.S. Atty's Docket U.S. Serial No. No. No. ______________________________________ P 25 19 288.5 Bayer 2883 678,819 P 25 19 300.4 Bayer 2884 678,820 P 25 19 299.8 Bayer 2885 678,821 P 25 19 298.7-42 Bayer 2886 678,822 P 25 19 297.6 Bayer 2887 678,823 P 25 19 295.4 Bayer 2888 678,824 P 25 19 292.1-42 Bayer 2890 678,826 P 25 19 291.0-42 Bayer 2891 678,827 P 25 19 289.6 Bayer 2892 678,828 P 25 19 297.4 Bayer 2893 678,829 ______________________________________ All of the German applications were filed Apr. 30, 1975. Those applications are incorporated herein by reference.

5. 发明授权

US4487723A Substituted-butanediperoxoic acids and process for bleaching 失效
标题翻译：取代的丁二酸二辛酸和漂白方法
公开(公告)号：US4487723A
公开(公告)日：1984-12-11
申请号：US336542
申请日：1982-01-04
申请人： James M. Mayer
发明人： James M. Mayer
IPC分类号： C11D7/54 , A01N37/16 , C07C67/00 , C07C407/00 , C07C409/24 , C11D3/39 , C07C179/10
CPC分类号： C11D3/3945 , A01N37/16 , C07C409/24
摘要： Substituted-butanediperoxoic acids represented by the formula ##STR1## wherein R is alkyl of 6 to 18 carbon atoms or phenyl are useful oxidizing agents. These substituted-butanediperoxoic acids are useful as bleaching agents and disinfecting agents.

6. 发明授权

US4473507A Controlled release laundry bleach product 失效
标题翻译：受控制的洗衣漂白剂
公开(公告)号：US4473507A
公开(公告)日：1984-09-25
申请号：US508760
申请日：1983-06-28
申请人： Frank P. Bossu
发明人： Frank P. Bossu
IPC分类号： C11D3/39 , C11D17/04 , C07C179/10
CPC分类号： C11D17/046 , C11D3/3937 , C11D3/3945
摘要： A granular hydrophobic peroxyacid laundry product comprising a bleach with a surfactant bleach release agent, and an acid having a pKa of from about 2 to about 7, contained inside a pouch, bag or substrate, provides a controlled bleach release laundry product for better bleaching in a laundry wash liquor. The bleach can be an alkylmonoperoxy succinic acid.
摘要翻译：包含漂白剂与表面活性剂漂白剂脱模剂的颗粒状疏水性过氧酸洗涤产品以及包含在袋，袋或底物内的pKa为约2至约7的酸提供了受控漂白剂释放洗衣产品，以便更好地漂白洗衣液。漂白剂可以是烷基过氧化琥珀酸。

7. 发明授权

US4172086A Process for the manufacture of peroxycarboxylic acids 失效
标题翻译：过氧羧酸的制备方法
公开(公告)号：US4172086A
公开(公告)日：1979-10-23
申请号：US782204
申请日：1977-03-28
申请人： Sidney Berkowitz
发明人： Sidney Berkowitz
IPC分类号： C07B61/00 , B01J27/00 , B01J31/00 , C07C20060101 , C07C59/00 , C07C67/00 , C07C407/00 , C07C409/24 , C07C409/30 , C11D20060101 , C11C3/00 , C07C179/10
CPC分类号： C07C409/30 , C07C407/00 , C07C407/006 , C07C409/24
摘要： Peroxycarboxylic acids are prepared by the oxidation of a fatty acid with an excess of hydrogen peroxide in the presence of a strong acid catalyst. The yield is improved and the reaction time is reduced by intimately dispersing throughout the reaction mixture an inert water immiscible solvent for the peroxycarboxylic acid. The product may be recovered in crystalline form from the solvent phase.
摘要翻译：过氧羧酸通过在强酸催化剂存在下用过量的过氧化氢氧化脂肪酸来制备。通过在整个反应混合物中紧密分散过氧羧酸的惰性水不混溶溶剂，提高了产率并降低了反应时间。产物可以从溶剂相中以结晶形式回收。

8. 发明授权

US4160778A Epoxidation 失效
标题翻译：环氧化
公开(公告)号：US4160778A
公开(公告)日：1979-07-10
申请号：US873523
申请日：1978-01-30
申请人： Anthony M. Hildon , Thomas D. Manly , Alan J. Jaggers
发明人： Anthony M. Hildon , Thomas D. Manly , Alan J. Jaggers
IPC分类号： C07C409/24 , C07C409/26 , C07C179/10
CPC分类号： C07C407/00 , C07C407/003
摘要： The invention provides a continuous process for the preparation of a peracid which comprises reacting hydrogen peroxide with a carboxylic acid in an aqueous medium containing a mineral acid, and extracting the peracid thus formed into an organic phase comprising an organic solvent so as to produce an aqueous solution comprising sulphuric acid and water and an organic solution comprising peracid and organic solvent, wherein the hydrogen peroxide is added to the reaction mixture in a plurality of stages, thereby to limit the concentration of hydrogen peroxide at any location. Preferably the reaction and extraction are effected simultaneously.
摘要翻译：本发明提供了一种用于制备过酸的连续方法，其包括使过氧化氢与含有无机酸的水性介质中的羧酸反应，并将由此形成的过酸提取到包含有机溶剂的有机相中，以产生水溶液包含硫酸和水的溶液和包含过酸和有机溶剂的有机溶液，其中过氧化氢以多个阶段加入到反应混合物中，从而限制过氧化氢在任何位置的浓度。优选地，反应和萃取同时进行。

9. 发明授权

US4129586A Peroxide free radical initiators containing ultraviolet light stabilizing groups 失效
标题翻译：含有紫外光稳定基团的过氧化物自由基引发剂
公开(公告)号：US4129586A
公开(公告)日：1978-12-12
申请号：US803493
申请日：1977-06-06
申请人： Chester S. Sheppard , Ronald E. MacLeay
发明人： Chester S. Sheppard , Ronald E. MacLeay
IPC分类号： C07C409/16 , C07C409/34 , C07C409/38 , C07C409/40 , C07C409/42 , C07C409/44 , C08F4/32 , C08K5/14 , C08K5/23 , C07C179/06 , C07C179/10 , C07C179/18
CPC分类号： C08K5/14 , C07C409/16 , C07C409/34 , C07C409/38 , C07C409/40 , C08F4/32 , C08K5/23
摘要： Compounds which contain azo or peroxide linkages as well as the radical of an ultraviolet light stabilizing group are described. These compounds function as polymerization initiators which cause an ultraviolet light stabilization group to be chemically bound to the polymer.
摘要翻译：描述了含有偶氮或过氧化物键的化合物以及紫外光稳定基团的基团。这些化合物起着聚合引发剂的作用，其使紫外光稳定基团与聚合物化学键合。

10. 发明授权

US4424394A Manufacture of arylacetic acids and their esters 失效
标题翻译：芳基乙酸及其酯的制造
公开(公告)号：US4424394A
公开(公告)日：1984-01-03
申请号：US092444
申请日：1979-11-08
申请人： Kurt Schneider , Rudolf Kummer , Kurt Schwirten , Hans-Dieter Schindler, deceased , Maria E. Schindler, heir-at-law , Ute Lang, heir-at-law , Rainer Schindler, heir-at-law
发明人： Kurt Schneider , Rudolf Kummer , Kurt Schwirten , Hans-Dieter Schindler, deceased , Maria E. Schindler, heir-at-law , Ute Lang, heir-at-law , Rainer Schindler, heir-at-law
IPC分类号： B43K24/10 , B43K27/00 , C07C67/36 , C07C51/00 , C07C69/76 , C07C179/10
CPC分类号： B43K24/10 , B43K27/00 , B43K7/005
摘要： Arylacetic acids and their esters, of the formula Ar(CH.sub.2 -COOR).sub.n (where Ar=aryl, R is H or a hydrocarbon radical, and n is 1 or 2) are manufactured by carbonylation of halomethylaryl compounds Ar(CH.sub.2 C).sub.n (where X is Cl, Br or I) with carbon monoxide and a catalyst m.sup.+ �Fe(O).sub.3 NO!.sup.- (where M is an alkali metal, ammonium or one equivalent of an alkaline earth metal) in the presence of stoichiometric amounts of an inorganic base or of an alcoholate of an alcohol ROH.
摘要翻译：通过羰基化卤代甲基芳基化合物Ar（CH 2 C）n（其中Ar = CH 2 -COR n）n（其中Ar =芳基，R为H或烃基，n为1或2）的芳基乙酸及其酯，其中X是Cl，Br或I）与一氧化碳和催化剂m + [Fe（O）3 NO] - （其中M是碱金属，铵或一当量的碱土金属）在化学计量的无机碱或醇ROH的醇化物。

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