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序号 专利名 申请号 申请日 公开(公告)号 公开(公告)日 发明人
161 Process for the production of aminoanthraquinone compounds US472141 1974-05-22 US4016182A 1977-04-05 Paul Buecheler
The present invention concerns a novel process for the reduction of a nitro-anthraquinone compound of formula I: ##STR1## wherein M IS AN INTEGER 1, 2 OR 3, ANDn is an integer 1, 2 or 3,The sum of m + n being 3, 4 or 5, and the rings A and B are either further substituted or unsubstituted,To the corresponding amino-anthraquinone compound which comprises reacting the compound of formula I with hydrazine in aqueous medium. The resulting amino-anthraquinone compounds are in general known and are useful intermediates in the production of anthraquinone dyestuffs.
162 Process for preparing 1-aminoanthraquinone US557058 1975-03-10 US3975411A 1976-08-17 Muneyasu Sameshima; Tagui Osawa; Utaka Hirai
5-Nitro-1,4,4a,9a-tetrahydroanthraquinone is suspended in water in the form of a powder and then catalytically hydrogenated in the presence both of a hydrogenation catalyst containing a metal such as palladium, platinum or the like as its effective component and of a base such as sodium hydroxide, pyridine or the like thereby to form a hydroquinone type compound of 1-aminoanthraquinone. By contacting the resultant reaction solution with air or by adding an oxidizing agent such as hydrogen peroxide to the reaction solution, the hydroquinone type compound is readily oxidized into 1-aminoanthraquinone in the suspended state.
163 Process for the manufacture of amino-anthraquinones US400759 1973-09-26 US3933866A 1976-01-20 Zdenek Seha
A process for the manufacture of aminoanthraquinones from nitroanthraquinone, wherein the nitroanthraquinones are treated with ammonia in dipolar aprotic solvents that are inert towards ammonia and nitroanthraquinones.
164 Process for isolating aminoanthraquinones US33801173 1973-03-05 US3873582A 1975-03-25 SZEKELY ISTVAN
The present invention relates to a process for the separation of mixture of aminoanthraquinones, wherein the amines are partitioned in a system of two liquid phases consisting of an acid, aqueous phase and an organic phase which is immiscible with water, the two phases are separated, and the amines are isolated therefrom.
165 Process for the manufacture of anthraquinone derivatives US15416971 1971-06-17 US3836548A 1974-09-17 GRELAT M; ARCHAMBAULT J
1-AMINO-2-HYDROXYMETHYL-ANTHRAQUINONE IS OXIDISED TO GIVE 1-AMINO-ANTHRAQUINONE-2-CARBOXYLIC ACID.
166 Dispersible anthraquinone dyestuffs US21985172 1972-01-21 US3806524A 1974-04-23 HINDERMANN P; KOLLIKER H; STAUB A

1-V1,2-(R"-O-CO-O-Y''-X2-),4-V2''-ANTHRAQUINONE

DIFFICULTLY WATER-SOLUBLE ANTHRAQUINONE DYESTUFFS FREE FROM WATER-SOLUBILIZATING GROUPS WHICH DISSOCIATE ACID IN WATER OF THE FORMULA
WHEREIN V1 REPRESENTS HYDROXYL OR --NH2, V2'' REPRESENTS HYDROGEN, HYDROXYL, PHENYLAMINO OR PHENYLAMINO RING-SUBSTITUTED BY ONE SUBSTITUTED SELECTED FROM CHLORINE AND C1-C4 ALKOXY OR BY ONE TO THREE C1-C4ALKYL, X2 REPRESENTS OXYGEN,SULPHUR, --CO--O--, --CONH--, --SO2--O--, --SO2NH-- OR --O--ALKYLENE--O--, WHEREIN THE ALKYLENE MOIETY HAS AT MOST 4 CARBON ATOMS, Y'' IS AN ALIPHATIC, AROMATICOR HETEROCYCLIC BRIDGE, AND R" IS ALKYL, CYCLOHEXYL OR ARYL; THESE DYESTUFFS BEING SUITED PARTICULARLY FOR THE DYEING OF SYNTHERIC ORGANIC FIBERS, ESPECIALLYPOLYETHYLENE GLYCOL TEREPTHALATE FIBERS, AFFORDING DYEINGS ON THESE FIBERS WHICH HAVE GOOD FASTENESS PROPERTIES AND ESPECIALLY FOOD FASTENESS TO LIGHT AND SUBLIMATION.
167 Dispersible anthraquinone dyestuffs US3767681D 1972-01-21 US3767681A 1973-10-23 KOELLIKER H; STAUB A; HINDERMANN P
DIFFICULTLY WATER-SOLUBLE ANTHRAQUINONE DYESTUFFS, FREE FROM WATER-SOLUBILIZING GROUPS WHICH DISSOCIATE ACID IN WATER OF THE FORMULA WHERIN V1 REPRESENTS HYDROXYL OR -NH2, V2 REPRESENTS HYDROGEN, HYDROXYL, -NH2, LOWER AKYLAMINO, CYCLOHEXYLAMINO, PHENYLAMINO, PHENOXYPHENYLAMINO, PHENYLAZOPHENYLAMINO OR PHENYLAMINO RING-SUBSTITUTED BY CHLORINE LOWER ALKYL OR LOWER ALKOXY, X IS OXYGEN OR SULFUR, Y IS C1-C4-ALKYLENE OR

1-V1,2-(R-O-CO-O-Y-NH-SO2-C6H4-X-),3-W,4-V2-ANTHRAQUINONE

W IS HYDROGEN, CHLORINE OR X-PHENYLENE

-SO2-NH-Y-O-CO-O-R

AND R REPRESENTS AN OPTIONALLY SUBSTITUTED ALIPHATIC CYCLOALIPHATIC OR AROMATIC RADICAL; THESE DYESTUFFS BEING SUITED PARTICULARLY FOR THE DYEING OF SYNTHETIC ORGANIC FIBERS, ESPECIALLY POLYETHYLENE GLYCOL TEREPHTHALATE FIBERS, AFFORDING DYEINGS ON THESE FIBERS WHICH HAVE GOOD FASTNESS PROPERTIES AND ESPECIALLY GOOD FASTNESS TO LIGHT AND SUBLIMATION.
168 Anthraquinone compounds US3642837D 1969-03-06 US3642837A 1972-02-15 GREENHALGH COLIN WILLIAM; NEWTON DAVID FRANCIS
ANTHRAQUINONE COMPOUNDS WHICH CONTAIN ONE OR TWO CHLOROMETHYL OR BROMOMETHYL GROUPS EACH OF WHICH IS IN ORTHO POSITION TO AN AMINO GROUP WHICH IS ATTACHED TO AN X-POSITION OF THE ANTHRAQUINONE NUCLEUS WHICH MAY CONTAIN ADDITIONAL SUBSTITUENTS, THE PREPARATION OF THE SAID COMPOUNDS FROM THE CORRESPONDING HYDROXYMETHYL DERIVATIVES, AND THE USE OF THE SAID COMPOUNDS AS INTERMEDIATES IN THE MANUFACTURE OF DYESTUFFS.
169 Process for dyeing or printing fibers from aromatic polyesters US3503697D 1967-11-15 US3503697A 1970-03-31 RAMANATHAN VISVANATHAN
170 Anthraquinone dyestuffs and processes for their production US3468879D 1966-04-11 US3468879A 1969-09-23 HARMS WOLFGANG; OERTZEN KLAUS VON; BEIN HANS-SAMUEL; SIEGEL EDGAR
171 1-amino-2-alkoxy-4-anthraquinonylaralkyl urethanes US3455970D 1966-11-15 US3455970A 1969-07-15 RICKENBACHER HANS RUDOLF
The invention comprises compounds of the formula where A is aryl, X is alkyl or alkoxyalkyl and Y is alkylene. The compounds are prepared by reacting a compound of the formula with a halogenoformic acid aralkyl ester.
172 2-cyanovinyl esters of organic carboxylic acids US21851062 1962-08-22 US3288779A 1966-11-29 JUSTIN RANDALL JOHN
173 Process for the preparation of 2, 3, 4-trichloroanthraquinone-1-carboxylic esters US25446463 1963-01-28 US3284472A 1966-11-08 PAUL KNIEL
174 New anthraquinone dyestuffs US25936263 1963-02-18 US3185698A 1965-05-25 JACOB KOCH; MAX JOST
175 1-amino-2-anthraquinoylamino-dinaphthofurandiones US74526158 1958-06-30 US2995579A 1961-08-08 FRANCESCO SARTORI MARIO
176 Dyestuffs of the anthraquinone series US70328257 1957-12-17 US2911417A 1959-11-03 ERNST ANTON; JULIUS EISELE; WILHELM FEDERKIEL
177 Halogenated amino-anthraquinonyl-oxdiazoles US19718150 1950-11-22 US2650926A 1953-09-01 STILMAR FREDERIC B
178 Preparation of alpha-amino anthraquinone US7846649 1949-02-25 US2610971A 1952-09-16 MCSHEEHY JUSTIN A; RAIMOND WILLIAM A
179 Vat dyes of the anthraquinone-oxdiazole series US15180450 1950-03-24 US2601179A 1952-06-17 STILMAR FREDERIC B
180 Vat dyes of the anthraquinone 1, 3, 4-oxdiazole series US8161949 1949-03-15 US2511018A 1950-06-13 STILMAR FREDERIC B