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21. 发明申请

US20050101749A1 Process for the polymerization of olefins 失效
标题翻译：烯烃聚合方法
公开(公告)号：US20050101749A1
公开(公告)日：2005-05-12
申请号：US10467389
申请日：2002-01-30
申请人： Akhlaq Moman , Khalid Al-Bahily , Atieh Abu-Raqabah , John Ledford , Orass Hamed , Raju Raghavan , Sameh Rizkallah
发明人： Akhlaq Moman , Khalid Al-Bahily , Atieh Abu-Raqabah , John Ledford , Orass Hamed , Raju Raghavan , Sameh Rizkallah
IPC分类号： C08F4/02 , C08F4/68 , C08F4/685 , C08F10/00 , C08F110/02 , C08F210/16
CPC分类号： C08F10/00 , C08F110/02 , C08F210/16 , Y10S526/904 , C08F4/68 , C08F4/027 , C08F4/685 , C08F2500/18 , C08F2500/03 , C08F210/08 , C08F210/14
摘要： The present invention relates to a process for homopolymerization of ethylene or copolymerization of ethylene with alpha-olefins by contacting ethylene or ethylene and alpha-olefin with a catalyst composition comprising: (a) a solid catalyst precursor comprising at least one vanadium compound, at least one magnesium compound and a polymeric material or a solid catalyst precursor comprising at least one vanadium compound, at least one further transition metal compound and/or at least one alcohol, at least one magnesium compound and a polymeric material; and (b) a cocatalyst comprising an aluminum compound.
摘要翻译：本发明涉及乙烯均聚或乙烯与α-烯烃的共聚合方法，该方法是将乙烯或乙烯与α-烯烃与催化剂组合物接触，该催化剂组合物包含：（a）至少含有一种钒化合物的固体催化剂前体，至少一种镁化合物和包含至少一种钒化合物，至少一种其它过渡金属化合物和/或至少一种醇，至少一种镁化合物和聚合物材料的聚合材料或固体催化剂前体; 和（b）包含铝化合物的助催化剂。

22. 发明授权

US6084042A Mixed titanium-vanadium catalysts for solution ethylene polymerization 失效
标题翻译：用于溶液乙烯聚合的混合钛钒催化剂
公开(公告)号：US6084042A
公开(公告)日：2000-07-04
申请号：US106164
申请日：1998-06-29
申请人： Isam Jaber , Stephen John Brown
发明人： Isam Jaber , Stephen John Brown
IPC分类号： B01J23/16 , C08F4/685 , C08F10/00 , C08F10/02 , C08F110/06 , C08F210/16 , C08F4/654 , C08F4/68
CPC分类号： C08F10/00 , C08F10/02 , C08F110/06 , C08F210/16
摘要： The present invention provides a Ziegler-Natta catalyst based on titanium and vanadium useful in solution processes for the polymerization of olefins having a low amount of aluminum and magnesium. The catalysts of the present invention have a molar ratio of magnesium to the first aluminum component from 4.0:1 to 8.0:1 and molar ratio of magnesium to titanium and vanadium from 4.0:1 to 8.0:1. The invention provides a novel catalyst preparation method to substantially increase the polymer molecular weight in the high temperature ethylene polymerization process.
摘要翻译：本发明提供一种基于钛和钒的齐格勒 - 纳塔催化剂，其用于具有低量铝和镁的烯烃聚合的溶液方法中。本发明的催化剂的镁与第一铝组分的摩尔比为4.0:1至8.0:1，镁与钛和钒的摩尔比为4.0:1至8.0:1。本发明提供了一种在高温乙烯聚合方法中大幅度提高聚合物分子量的新型催化剂制备方法。

23. 发明授权

US5804614A Process for the production of ethylene-propylene elastomeric copolymers 失效
标题翻译：制备乙烯 - 丙烯弹性体共聚物的方法
公开(公告)号：US5804614A
公开(公告)日：1998-09-08
申请号：US714398
申请日：1996-09-16
申请人： Tiziano Tanaglia
发明人： Tiziano Tanaglia
IPC分类号： C08F4/654 , C08F2/14 , C08F2/18 , C08F2/44 , C08F4/60 , C08F4/659 , C08F4/68 , C08F4/685 , C08F210/00 , C08F210/06 , C08F210/16 , C08F210/18 , C08K9/02
CPC分类号： C08F210/16 , Y10S526/904
摘要： Process for the preparation in liquid phase of copolymers of ethylene with propylene and optionally another diene, in the presence of a catalyst selected from (a) Titanium salt supported on magnesium salt and (b) compound of Vanadium soluble in hydrocarbon solvents either supported on an inert material or prepolymerized, and a co-catalyst essentially consisting of an organic compound of Aluminium, and a possible chlorinated activator, characterized in that: 1) when the polymerization is almost complete, a solid material insoluble in the reaction environment and having an average diameter of between 0.001 and 200 microns is added to the reaction mixture; 2) the suspension of polymer and solid material are kept in contact for a sufficient time to obtain perfectly free-flowing polymeric particles; 3) the perfectly free-flowing polymeric particles of step (2) are recovered.
摘要翻译：在乙烯与丙烯和任选的另一种二烯的共聚物的液相中在催化剂存在下制备方法，所述催化剂选自（a）负载在镁盐上的钛盐和（b）可溶于烃溶剂的钒化合物，惰性材料或预聚合物，以及基本上由铝的有机化合物组成的助催化剂和可能的氯化活化剂，其特征在于：1）当聚合几乎完成时，不溶于反应环境并具有平均值的固体材料将直径为0.001至200微米的直径加入到反应混合物中; 2）聚合物和固体材料的悬浮液保持接触足够的时间以获得完全自由流动的聚合物颗粒; 3）回收步骤（2）的完全自由流动的聚合物颗粒。

24. 发明授权

US5492974A Process for preparing polymer bound metallocenes 失效
标题翻译：制备聚合物结合金属茂的方法
公开(公告)号：US5492974A
公开(公告)日：1996-02-20
申请号：US455380
申请日：1995-05-31
申请人： Bernd Peifer , Helmut G. Alt , M. Bruce Welch , Syriac J. Palackal
发明人： Bernd Peifer , Helmut G. Alt , M. Bruce Welch , Syriac J. Palackal
IPC分类号： C08F4/642 , C07F17/00 , C08F4/58 , C08F4/60 , C08F4/619 , C08F4/6192 , C08F4/646 , C08F4/656 , C08F4/657 , C08F4/685 , C08F8/00 , C08F8/42 , C08F10/00
CPC分类号： C08F8/42 , C08F10/00 , C08F4/61912 , C08F4/61916 , C08F4/61922
摘要： A polymer bound ligand represented by the formula QM(R).sub.m and process for preparing same are provided, wherein Q is a polystyrene, M is Si, C, Ge, Sn, P, or N, each R is a that at least one R is a cyclopentadienyl-type compound, and m is 2 or 3, said process comprising reacting a metallated polystyrene and an organohalide compound, wherein the polystyrene is metallated with an alkali metal, and wherein said organohalide compound is represented by the formula XM(R).sub.m wherein X is a halide. Other aspects of the present invention include a polymer bound metallocene represented by the formula QM(R).sub.m ZY.sub.n and a process for preparing same, wherein Z is a transition metal, Y is a halide, methyl, hydrogen, or a cyclopentadienyl-type group, and n is 2 or 3. Other aspects of the present invention include a catalyst system comprising the polymer bound metallocene and an organoaluminoxane, a method for preparing same, and a polymerization process employing the catalyst system.
摘要翻译：提供由式QM（R）m表示的聚合物结合配体及其制备方法，其中Q是聚苯乙烯，M是Si，C，Ge，Sn，P或N，每个R是至少一个 R是环戊二烯基型化合物，m为2或3，所述方法包括使金属化聚苯乙烯和有机卤化物化合物反应，其中聚苯乙烯用碱金属进行金属化，其中所述有机卤化物由式XM（R ）m，其中X是卤化物。本发明的其它方面包括由式QM（R）mZYn表示的聚合物结合金属茂及其制备方法，其中Z为过渡金属，Y为卤化物，甲基，氢或环戊二烯基型基团，并且n为2或3.本发明的其它方面包括包含聚合物结合的茂金属和有机铝氧烷的催化剂体系，其制备方法和使用该催化剂体系的聚合方法。

25. 发明授权

US5473020A Polymer bound ligands, polymer bound metallocenes, catalyst systems, preparation, and use 失效
标题翻译：聚合物结合的配体，聚合物结合的金属茂，催化剂体系，制备和用途
公开(公告)号：US5473020A
公开(公告)日：1995-12-05
申请号：US268425
申请日：1994-06-30
申请人： Bernd Peifer , Helmut G. Alt , M. Bruce Welch , Syriac J. Palackal
发明人： Bernd Peifer , Helmut G. Alt , M. Bruce Welch , Syriac J. Palackal
IPC分类号： C08F4/642 , C07F17/00 , C08F4/58 , C08F4/60 , C08F4/619 , C08F4/6192 , C08F4/646 , C08F4/656 , C08F4/657 , C08F4/685 , C08F8/00 , C08F8/42 , C08F10/00 , C08F8/40
CPC分类号： C08F8/42 , C08F10/00 , C08F4/61912 , C08F4/61916 , C08F4/61922
摘要： A polymer bound ligand represented by the formula QM(R).sub.m and process for preparing same are provided, wherein Q is a polystyrene, M is Si, C, Ge, Sn, P, or N, each R is a that at least one R is a cyclopentadienyl-type compound, and m is 2 or 3, said process comprising reacting a metallated polystyrene and an organohalide compound, wherein the polystyrene is metallated with an alkali metal, and wherein said organohalide compound is represented by the formula XM(R).sub.m wherein X is a halide. Other aspects of the present invention include a polymer bound metallocene represented by the formula QM(R).sub.m ZY.sub.n and a process for preparing same, wherein Z is a transition metal, Y is a halide, methyl, hydrogen, or a cyclopentadienyl-type group, and n is 2 or 3. Other aspects of the present invention include a catalyst system comprising the polymer bound metallocene and an organoaluminoxane, a method for preparing same, and a polymerization process employing the catalyst system.
摘要翻译：提供由式QM（R）m表示的聚合物结合配体及其制备方法，其中Q是聚苯乙烯，M是Si，C，Ge，Sn，P或N，每个R是至少一个 R是环戊二烯基型化合物，m为2或3，所述方法包括使金属化聚苯乙烯和有机卤化物化合物反应，其中聚苯乙烯用碱金属进行金属化，其中所述有机卤化物由式XM（R ）m，其中X是卤化物。本发明的其它方面包括由式QM（R）mZYn表示的聚合物结合金属茂及其制备方法，其中Z为过渡金属，Y为卤化物，甲基，氢或环戊二烯基型基团，并且n为2或3.本发明的其它方面包括包含聚合物结合的茂金属和有机铝氧烷的催化剂体系，其制备方法和使用该催化剂体系的聚合方法。

26. 发明授权

US5266544A Olefin polymerization catalyst and process for the polymerization of olefins 失效
标题翻译：烯烃聚合催化剂和烯烃聚合方法
公开(公告)号：US5266544A
公开(公告)日：1993-11-30
申请号：US888641
申请日：1992-05-27
申请人： Toshiyuki Tsutsui , Takashi Ueda
发明人： Toshiyuki Tsutsui , Takashi Ueda
IPC分类号： C08F4/639 , C08F4/6392 , C08F4/685 , C08F10/00 , C08F4/642 , C08F4/653 , C08F4/69
CPC分类号： C08F10/00 , C08F4/63904 , C08F4/63916 , C08F4/63922 , Y10S526/943
摘要： In accordance with the present invention, there are provided olefin polymerization solid catalysts comprising[A] a solid titanium catalyst component containing titanium, magnesium and halogen as its essential ingredients, said catalyst component having supported thereon[B] a transition metal compound containing a ligand having a cycloalkadienyl skeleton and, if necessary,[C] an organoaluminum oxy-compound.In accordance with the invention, there are also provided olefin polymerization solid catalysts comprising[i] a solid containing a transition metal compound containing a ligand having a cycloalkadienyl skeleton, said solid having supported thereon[ii] a titanium catalyst component containing titanium, magnesium and halogen as its essential ingredients and, if necessary,[iii] an organoaluminum oxy-compound.
摘要翻译：根据本发明，提供了包含[A]含有钛，镁和卤素作为其主要成分的固体钛催化剂组分的烯烃聚合固体催化剂，所述催化剂组分负载在其上[B]含有配体的过渡金属化合物具有环二烯基骨架，并且如果需要，[C]有机铝氧基化合物。根据本发明，还提供了包含[i]包含含有具有环二烯基骨架的配体的过渡金属化合物的固体的烯烃聚合固体催化剂，所述固体在其上负载[ii]含有钛，镁的钛催化剂组分和卤素作为其必需成分，如果需要，[iii]有机铝氧化合物。

27. 发明授权

US5155079A Multiple site olefin polymerization catalysts 失效
标题翻译：多位烯烃聚合催化剂
公开(公告)号：US5155079A
公开(公告)日：1992-10-13
申请号：US712206
申请日：1991-06-07
申请人： Leonard V. Cribbs , Michael W. Lynch
发明人： Leonard V. Cribbs , Michael W. Lynch
IPC分类号： C08F2/06 , C08F4/60 , C08F4/633 , C08F4/64 , C08F4/659 , C08F4/685 , C08F10/00 , C08F10/02
CPC分类号： C08F10/02
摘要： A multiple site solid catalyst component capable of producing polyolefins having a broad or multimodal molecular weight distribution, such as a bi-modal molecular weight distribution, is prepared by contacting a particulate solid support with a zirconium compound or complex to bind the zirconium compound or complex to the support, optionally followed by contacting the supported zirconium compound or complex with a Lewis acid to produce an intermediate product, optionally isolating and washing the supported zirconium compound or complex or resulting intermediate product to remove soluble by-products therefrom, and reacting the washed or unwashed supported zirconium compound or complex or intermediate product with a titanium or vanadium compound to produce a solid catalyst component.

28. 发明授权

US5026511A Process for the production of polyethylene materials 失效
标题翻译：聚乙烯材料生产工艺
公开(公告)号：US5026511A
公开(公告)日：1991-06-25
申请号：US485248
申请日：1990-02-26
申请人： Akira Sano , Hirofumi Kamiishi , Seizo Kobayashi , Kazuo Matsuura , Shigeki Yokoyama
发明人： Akira Sano , Hirofumi Kamiishi , Seizo Kobayashi , Kazuo Matsuura , Shigeki Yokoyama
IPC分类号： C08F4/64 , B29C55/00 , B29C55/18 , C08F4/60 , C08F4/685 , C08F110/00 , C08F110/02 , C08J5/18 , C08L23/06 , D01F6/04
CPC分类号： C08J5/18 , B29C55/005 , B29C55/18 , C08L23/06 , D01F6/04 , B29K2023/06 , C08J2323/06
摘要： A process for producing a polyethylene material for use in products requiring high mechanical strength and high elastic modulus is disclosed. The process involves the use of a specific class of particulate polyethylenes having an intrinsic viscosity of 5-50 dl/g in decalin at 135.degree. C. and the steps of compression molding, solvent immersing, solid-phase extruding or rolling and finally drawing the material in that order.

29. 发明申请

US20050222350A1 Catalyst composition and olefin polymerization using same 失效
标题翻译：催化剂组合物和使用其的烯烃聚合
公开(公告)号：US20050222350A1
公开(公告)日：2005-10-06
申请号：US11138089
申请日：2005-05-26
申请人： Brooke Small , Angel Marcucci
发明人： Brooke Small , Angel Marcucci
IPC分类号： C07F11/00 , C08F4/60 , C08F4/62 , C08F4/6392 , C08F4/659 , C08F4/68 , C08F4/685 , C08F4/69 , C08F10/02 , C08F110/02 , C08F210/16 , C08F4/44
CPC分类号： B01J31/18 , B01J31/1815 , B01J31/2204 , B01J31/24 , B01J2231/122 , B01J2231/20 , B01J2531/56 , B01J2531/62 , B01J2531/72 , C07F11/005 , C08F4/63912 , C08F4/6392 , C08F10/02 , C08F110/02 , C08F210/16 , C08F2420/02 , C08F4/63904 , C08F2500/02 , C08F2500/23 , C08F210/14 , C08F4/69224 , C08F10/00 , C08F4/69232
摘要： Novel metal complexes, particularly chromium complexes, which contain at least one tridentate ligand are disclosed and prepared. Olefins, particularly ethylene, can be reacted to form butene and/or other homo- or co-oligomers and/or polymers with high α-olefin concentrations by contacting a metal catalyst which contains a transition metal, particularly chromium, complexes having per metal atom at least one tridentate ligand with N, O, or N and O coordinating sites.
摘要翻译：公开并制备了含有至少一个三齿配体的新型金属络合物，特别是铬络合物。烯烃，特别是乙烯可以通过使包含过渡金属的金属催化剂，特别是铬，具有每个金属原子的络合物接触，使烯烃和/或其它具有高α-烯烃浓度的均聚物或共低聚物和/或聚合物反应至少一个具有N，O或N和O配位点的三齿配位体。

30. 发明授权

US5487938B1 Silica supported transition metal catalyst 失效
标题翻译：二氧化硅负载过渡金属催化剂
公开(公告)号：US5487938B1
公开(公告)日：1997-11-18
申请号：US33694794
申请日：1994-11-10
申请人： DOW CHEMICAL CO
发明人： SPENCER LEE , KOLTHAMMER BRIAN W S , RIPPLINGER MIRIAM P , WOOSTER JEFFREY J , CHUM PAK-WING S , GROOT DE JACQUELYN A
IPC分类号： C08J5/18 , B29C55/02 , B29K23/00 , B29L7/00 , C08F4/646 , C08F4/658 , C08F4/685 , C08F10/00 , C08F210/00 , C08F210/02 , C08F210/16 , B32B27/00
CPC分类号： C08F10/00 , Y10S428/91 , Y10T428/26 , Y10T428/31855 , C08F4/6555 , C08F4/6357

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