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    • 7. 发明授权
    • Wet etching of silicon containing antireflective coatings
    • 含硅抗反射涂层的湿蚀刻
    • US09418865B2
    • 2016-08-16
    • US14140737
    • 2013-12-26
    • Intermolecular Inc.International Business Machines Corporation
    • Gregory NowlingJohn Fitzsimmons
    • H01L21/311
    • H01L21/31111H01L21/31133H01L21/67086
    • Provided are methods for processing semiconductor substrates or, more specifically, etching silicon containing antireflective coatings (SiARCs) from the substrates while preserving silicon oxides layers disposed on the same substrates. An etching solution including sulfuric acid and hydrofluoric acid may be used for these purposes. In some embodiments, the weight ratio of sulfuric acid to hydrofluoric acid in the etching solution is between about 15:1 and 100:1 (e.g., about 60:1). The temperature of the etching solution may be between about 30° C. and 50° C. (e.g., about 40° C., during etching). It has been found that such processing conditions provide a SiARC etching rate of at least about 50 nanometers per minute and selectivity of SiARC over silicon oxide of greater than about 10:1 or even greater than about 50:1. The same etching solution may be also used to remove photoresist, organic dielectric, and titanium nitride.
    • 提供了用于处理半导体衬底的方法,或者更具体地,从衬底中蚀刻含硅抗反射涂层(SiARCs),同时保留设置在相同衬底上的氧化硅层。 包括硫酸和氢氟酸的蚀刻溶液可以用于这些目的。 在一些实施方案中,蚀刻溶液中硫酸与氢氟酸的重量比为约15:1至100:1(例如约60:1)。 蚀刻溶液的温度可以在约30℃至50℃之间(例如在蚀刻期间约为40℃)。 已经发现,这样的处理条件提供至少约50纳米每分钟的SiARC蚀刻速率,SiARC相对于氧化硅的选择性大于约10:1或甚至大于约50:1。 也可以使用相同的蚀刻溶液去除光致抗蚀剂,有机电介质和氮化钛。
    • 10. 发明授权
    • Variable composition transparent conductive oxide layer and methods of forming thereof
    • 可变组合物透明导电氧化物层及其形成方法
    • US09391232B1
    • 2016-07-12
    • US14577967
    • 2014-12-19
    • Intermolecular, Inc.
    • Minh Huu LeJianhua Hu
    • H01L33/42H01L33/00H01L33/38
    • H01L33/005H01L33/38H01L33/42H01L2933/0016H01L2933/0033H01L2933/0058H01L2933/0066H01L2933/0091
    • Provided are light emitting diodes (LEDs) and methods of fabricating such LEDs. An LED may include a transparent conductive oxide (TCO) layer having a varying refractive index. For example, the refractive index may be higher at the interface of the TCO layer with an epitaxial stack than on the side of the TCO layer. The refractive index variability allows reducing light intensity losses in the LED. The refractive index variability may be achieved by feeding a substrate through a deposition chamber having a variable concentration of at least one process gas, such as oxygen. Specifically, the concentration of the process gas may be higher at one slit opening than at another slit opening. As the substrate moves through the deposition chamber, the TCO layer is continuously deposited. Due to the concentration variability, the resulting TCO layer may have a variable composition throughout the thickness of the TCO layer.
    • 提供了发光二极管(LED)和制造这种LED的方法。 LED可以包括具有变化的折射率的透明导电氧化物(TCO)层。 例如,在具有外延堆叠的TCO层的界面处的折射率可以高于在TCO层的侧面上的折射率。 折射率变化允许减少LED中的光强度损失。 折射率可变性可以通过将衬底通过具有可变浓度的至少一种工艺气体(例如氧气)的沉积室进行。 具体地,处理气体的浓度在一个狭缝开口处可以比在另一个狭缝开口处更高。 当衬底移动通过沉积室时,TCO层被连续沉积。 由于浓度变化,所得的TCO层可以在TCO层的整个厚度上具有可变的组成。