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1. 发明授权

US5210244A Procedure for the production of vanadium bis-arenes from vanadium oxychloride 失效
标题翻译：从氧化亚氮烷中生产钒酸铋的方法
公开(公告)号：US5210244A
公开(公告)日：1993-05-11
申请号：US911286
申请日：1992-07-09
申请人： Fausto Calderazzo , Guido Pampaloni , Francesco Masi , Angelo Moalli , Maria C. Cassani , Renzo Invernizzi
发明人： Fausto Calderazzo , Guido Pampaloni , Francesco Masi , Angelo Moalli , Maria C. Cassani , Renzo Invernizzi
IPC分类号： C07F9/00 , C08F4/06 , C08F4/60 , C08F4/68 , C08F4/76 , C08F10/00
CPC分类号： C07F9/00
摘要： A procedure is described for the preparation of a vanadium bis-arene, [V(arene).sub.2 ], starting from vanadium oxychloride, aluminium metal, aluminium trichloride and an arene, wherein:(a) vanadium oxychloride (VOCl.sub.3), active aluminium metal, and aluminium trichloride are put in contact with each other, in a liquid arene, to transform the vanadium oxychloride into the complex compound [V(arene).sub.2 ].sup.+ [AlCl.sub.4 ].sup.- ;(b) a liquid cyclic or acyclic or acyclic ether is added to the reaction product of step (a) to reduce [V(arene).sub.2 ].sup.+ to [V(arene).sub.2 ]; and(c) the vanadium bis-arene [V(arene).sub.2 ] is recovered from the reacton product of step (b).The vanadium bis-arenes thus obtained are use in the preparation of catalysts for the polymerization of olefins.

2. 发明授权

US5093508A Process for producing vanadium-arenes 失效
标题翻译：生产钒酸盐的方法
公开(公告)号：US5093508A
公开(公告)日：1992-03-03
申请号：US641877
申请日：1991-01-04
申请人： Fausto Calderazzo , Guido Pampaloni , Lucia Rocchi , Angelo Moalli , Francesco Masi , Renzo Invernizzi
发明人： Fausto Calderazzo , Guido Pampaloni , Lucia Rocchi , Angelo Moalli , Francesco Masi , Renzo Invernizzi
IPC分类号： C07F9/00 , C08F4/20
CPC分类号： C07F9/00
摘要： Vanadium-arenes[V(arene).sub.2 ]wherein "arene" means benzene or mono-, di- or poly-(C.sub.1 -C.sub.5)-alkyl-substituted benzene, are prepared by means of a process which comprises:(a) forming a complex:[V(arene).sub.2 ](+).AlCl.sub.4 (-) by reacting vanadium trichloride, aluminum metal and aluminum trichloride with one another, by operating in the presence of the selected arene;(b) treating the so obtained complex with an either cyclic or acyclic, liquid aliphatic ether to obtain the reduction of [V(arene).sub.2 ](+) to [V(arene).sub.2 ]; and(c) recovering the so separated vanadium-arene.The vanadium-arenes are useful in the preparation of catalysts for olefin polymerization.

3. 发明授权

US4987111A Catalyst component and catalyst for the polymerization of ethylene and the copolymerization of ethylene with alpha-olefins 失效
标题翻译：用于乙烯聚合的催化剂组分和催化剂以及乙烯与α-烯烃的共聚合
公开(公告)号：US4987111A
公开(公告)日：1991-01-22
申请号：US403681
申请日：1989-09-06
申请人： Fausto Calderazzo , Guido Pampaloni , Francesco Masi , Angelo Moalli , Renzo Invernizzi
发明人： Fausto Calderazzo , Guido Pampaloni , Francesco Masi , Angelo Moalli , Renzo Invernizzi
IPC分类号： C08F4/60 , C08F4/639 , C08F4/646 , C08F4/685 , C08F10/00 , C08F10/02
CPC分类号： C08F10/02
摘要： A solid catalyst component for the polymerization of ethylene and the copolymerization of ethylene with C.sub.3 -C.sub.10 alpha-olefins, contains titanium, vanadium and chlorine, is substantially definable by the formula (in atomic proportions):V (1), Ti (n), Cl (4n)where n varies from 1 to 3, and is prepared by reacting titanium tetrachloride with a vanadium arene [V.degree.(arene).sub.2 ] (arene=benzene or mono-, di- or tri-alkyl substituted benzene) in accordance with the equation:V.degree.(arene).sub.2 +nTiCl.sub.4 .fwdarw.VTi.sub.n Cl.sub.4n +2 arenepossibly followed by treatment with an alkyl aluminum chloride. This catalyst component, when associated with a trialkyl aluminium, is highly active in the production of ethylene polymers and copolymers by low temperature, low pressure methods in suspension, or by high temperature, high pressure methods conducted in a tubular reactor or pressure vessel, or by high temperature methods conducted in solution.

4. 发明授权

US4980491A Process for producing vanadium-arenes 失效
标题翻译：生产钒 - 芳烃的方法
公开(公告)号：US4980491A
公开(公告)日：1990-12-25
申请号：US516267
申请日：1990-04-30
申请人： Fausto Calderazzo , Guido Pampaloni , Francesco Masi , Angelo Moalli , Renzo Invernizzi
发明人： Fausto Calderazzo , Guido Pampaloni , Francesco Masi , Angelo Moalli , Renzo Invernizzi
IPC分类号： C07F9/00 , C07F17/00 , C08F4/60 , C08F4/68 , C08F10/00 , C08F10/02
CPC分类号： C07F9/00
摘要： Vanadium-arenes [V(arene).sub.2 ] (arene=benzene or mono-, di-, or poly-alkyl-substituted benzene) are obtained, with a high yield, by means of the reduction of a vanadium-arene iodide with zinc, manganese or iron in metal form, or with cobalt di-(cyclopentadienyl).Vanadium-arenes are useful in the preparation of catalyst components active in ethylene polymerization, or in the copolymerization of ethylene in an alpha-olefin.

5. 发明授权

US07081505B2 Activating organometallic composition for the (co) polymerization of alpha-olefins comprising fluorinated cyclopentadienyl compounds 有权
标题翻译：活化用于包含氟化环戊二烯基化合物的α-烯烃的（共）聚合的有机金属组合物
公开(公告)号：US07081505B2
公开(公告)日：2006-07-25
申请号：US10483415
申请日：2002-07-10
申请人： Anna Sommazzi , Francesco Masi , Giampietro Borsotti , Roberto Santi , Fausto Calderazzo , Guido Pampaloni , Vincenzo Passarelli
发明人： Anna Sommazzi , Francesco Masi , Giampietro Borsotti , Roberto Santi , Fausto Calderazzo , Guido Pampaloni , Vincenzo Passarelli
IPC分类号： C08F4/44 , C08F4/6192 , B01J31/14
CPC分类号： C08F10/00 , C08F4/65927 , Y10S526/943 , C08F4/65912
摘要： An organometallic composition which can be used as activating component in a metallocene catalyst for the (co)polymerization of α-olefins, comprises: (A) a fluorinated di-unsaturated cyclic compound, having a relatively acid hydrogen atom, (B) an organometallic compound sufficiently basic to react with the acid hydrogen of the above compound (A), and (C) a polar aprotic organic compound, not containing metallic atoms, having a dielectric constant, in the pure state, equal to or greater than 2, and a weak coordinating capacity. Said composition allows a metallocene catalytic system of the ionic type to be obtained, with a high activity in the (co)polymerization of olefins and a reduced content of metallic residue in the polymeric product thus obtained.
摘要翻译：可用作α-烯烃（共）聚合的茂金属催化剂中的活化组分的有机金属组合物包括：（A）具有相对酸性氢原子的氟化二不饱和环状化合物，（B）有机金属具有足够碱性的化合物与上述化合物（A）的酸性氢反应，和（C）在纯状态下不具有介电常数的金属原子的极性非质子有机化合物等于或大于2，以及协调能力弱。所述组合物允许获得离子型茂金属催化体系，在烯烃的（共）聚合中具有高活性，并且由此获得的聚合物中的金属残余物含量降低。

6. 发明授权

US5189000A Supported catalyst for the polymerization and copolymerization of olefinically unsaturated compounds, and a (co)polymerization process which uses it 失效
标题翻译：用于烯烃不饱和化合物的聚合和共聚的支持催化剂和使用它的（CO）聚合方法
公开(公告)号：US5189000A
公开(公告)日：1993-02-23
申请号：US673272
申请日：1991-03-21
申请人： Francesco Masi , Renzo Invernizzi , Antonio Carbonaro , Lorenzo Costa , Angelo Moalli
发明人： Francesco Masi , Renzo Invernizzi , Antonio Carbonaro , Lorenzo Costa , Angelo Moalli
IPC分类号： C08F4/658 , B01J20060101 , C07F20060101 , C08F20060101 , C08F2/00 , C08F4/00 , C08F4/02 , C08F4/60 , C08F4/61 , C08F4/617 , C08F4/62 , C08F4/622 , C08F4/64 , C08F4/659 , C08F4/6592 , C08F10/00 , C08F10/02 , C08F210/16
CPC分类号： C08F10/00
摘要： A supported catalyst for the polymerization and copolymerization of olefinically unsaturated compounds is described, comprising an organometallic compound of aluminium and a second component obtained by bringing a titanium, vanadium or chromium compound, at least one compound of a second metal chosen from V, Al, Zr, Hf, Mo and Nd and optionally a magnesium compound into contact with a porous support consisting of microbeads of aerogels of one or more inorganic oxides distinguished by low density, high porosity and the fact that at least 90% of the pores have a diameter lying within a very narrow range of values. The process for the polymerization or copolymerization of olefinically unsaturated compounds based on the use of said catalyst is also described.

7. 发明授权

US5071928A Process for polymerizing ethylene and copolymerizing ethylene with alpha-olefins and relevant catalyst 失效
标题翻译：聚乙烯乙烯与乙烯共聚合乙烯和相关催化剂的方法
公开(公告)号：US5071928A
公开(公告)日：1991-12-10
申请号：US407611
申请日：1989-09-15
申请人： Francesco Ciardelli , Francesco Masi , Stefano Malquori , Cesare Ferrero , Lia Barazzoni , Francesco Menconi , Angelo Moalli , Renzo Invernizzi
发明人： Francesco Ciardelli , Francesco Masi , Stefano Malquori , Cesare Ferrero , Lia Barazzoni , Francesco Menconi , Angelo Moalli , Renzo Invernizzi
IPC分类号： C08F4/658 , C08F4/60 , C08F4/656 , C08F4/6592 , C08F10/00 , C08F10/02
CPC分类号： C08F10/02
摘要： Ethylene homopolymers and ethylene copolymers with alpha-(C.sub.3 -C.sub.10)-olefins are obtained by polymerizing the monomers with a polymerization catalyst formed by:a) an alkyl-aluminum; andb) a modified solid catalyst component obtained by treating with a Lewis' base a non-modified solid component to be defined by means of the following formula, expressed as atomic proportions:Ti(1), hf(0.5-3), Si (1-6), Mg (0.5-15) Al (0.5-15),X (20-60, ROH (1-10) wherein:X represents either chlorine and bromine, andR represents either a linear or branched alkyl radical of from 1 to 6 carbon atoms.The catalyst is particularly useful for controlling the molecular weight and the molecular weight distribution of ethylene hompolymers and copolymers.

8. 发明授权

US5070051A Catalyst component and catalyst for the production of very high molecular weight polyolefins 失效
标题翻译：用于生产非常高分子量聚烯烃的催化剂组分和催化剂
公开(公告)号：US5070051A
公开(公告)日：1991-12-03
申请号：US659533
申请日：1991-02-22
申请人： Francesco Masi , Angelo Moalli , Renzo Invernizzi , Francesco Menconi , Cesare Ferrero , Stefano Malquori , Lia Barazzoni , Mario Polesello
发明人： Francesco Masi , Angelo Moalli , Renzo Invernizzi , Francesco Menconi , Cesare Ferrero , Stefano Malquori , Lia Barazzoni , Mario Polesello
IPC分类号： C08F4/658 , C08F4/60 , C08F4/654 , C08F4/655 , C08F4/6592 , C08F10/00 , C08F10/02
CPC分类号： C08F10/02
摘要： A solid catalyst component for the low-pressure polymerization of ethylene and C.sub.3 -C.sub.10 alpha-olefins into very high molecular weight polyolefins is in the form of a spherical granular solid having a surface area of between 20 and 40 m.sup.2 /g, a mean pore radius of between 5,000 and 40,000 .ANG. and a porosity of between 40 and 90 vol %, and is definable by the following formula (in atomic proportions:X (1), Mg (1-8), Al (0.2-0.8), Cl (5-20), (Et+OEt+OR) (1-3);where: X=Hf or Zr; Et=ethyl group; OEt=ethoxy group; and OR=alkoxy group containing from 2 to 8 carbon atoms in the linear or branched alkyl portion.Such a catalyst component is obtained by preparing a solid spherical granular support by spray-drying an ethanolic solution of magnesium chloride, reacting said support with a hafnium or zirconium alkoxide or halogenalkoxide, and finally reacting the thus treated support with an alkyl aluminum chloride.

9. 发明授权

US5821189A Catalyst for the homopolymerization or copolymerization of ethylene and process for its preparation 失效
标题翻译：用于乙烯均聚或共聚的催化剂及其制备方法
公开(公告)号：US5821189A
公开(公告)日：1998-10-13
申请号：US444870
申请日：1995-05-19
申请人： Fausto Calderazzo , Guido Pampaloni , Francesco Masi , Andrea Vallieri
发明人： Fausto Calderazzo , Guido Pampaloni , Francesco Masi , Andrea Vallieri
IPC分类号： C08F4/60 , C08F4/619 , C08F4/642 , C08F4/659 , C08F4/6592 , C08F10/00 , B01J31/00 , B01J37/00 , C08F4/02
CPC分类号： C08F10/00 , C08F4/61904 , C08F4/61912 , C08F4/659
摘要： A catalyst for the (co)polymerization of ethylene is obtained by a process comprising the contact of the following components (A), (B), (C) and (D) in the respective molar ratios (1):(0.5-2):(0-25):(0-15): (A): a bivalent arene of titanium having the formula Ti (.eta..sup.6 -arene)(AlR.sub.x X.sub.4-x).sub.2 ; wherein: "arene" indicates benzene, or benzene substituted with from 1 to 6 C.sub.1 -C.sub.10 alkyl groups; each X independently represents a chlorine, bromine or fluorine atom; R is a C.sub.1 C.sub.10 alkyl group, linear or branched; "x" is a number varying from 0.5 to 2.5; (B): a compound or a mixture of compounds selected from the group consisting of the chlorides or bromides of the metals titanium, zirconium, vanadium, hafnium, tin, germanium, cerium or osmium, in the oxidation state (+4), and antimony or vanadium in the oxidation state (+5), and the derivatives of these metals in said oxidation state with oxygenated binders wherein at least one oxygen atom is bound or co-ordinated to the metal; (C): an aluminum alkyl or halide of aluminum alkyl (D): an organic chloroderivative selected from: (a) di- or poly-chloroalkanes; (b) alkyl esters of aliphatic carboxylic acids di- or tri-chlorosubstituted on the carbon in the alpha position with respect to the carboxyl; and (c) derivatives of chlorotriphenylemethane or dichlorodiphenylmethane having a carboxyalkyl group in the para position of at least one of the phenyl rings.
摘要翻译：通过包括以下组分（A），（B），（C）和（D）以相应的摩尔比（1）：（0.5-2）的接触的方法获得乙烯（共）聚合的催化剂）（0-25）：（0-15）：（A）：具有式Ti（eta 6-芳烃）（AlRxX4-x）2的钛的二价芳烃;其中：“芳烃”表示苯，具有1至6个C 1 -C 10烷基; 每个X独立地表示氯，溴或氟原子; R是直链或支链的C1C10烷基; “x”是从0.5到2.5的数字; （B）：处于氧化态（+4）的金属钛，锆，钒，铪，锡，锗，铈或锇的氯化物或溴化物的化合物或化合物的混合物，以及处于氧化态（+5）的锑或钒，以及所述氧化态的这些金属与氧化粘合剂的衍生物，其中至少一个氧原子与金属结合或配位; （C）：烷基铝的烷基铝或卤化物（D）：有机氯化物选自：（a）二 - 或多氯代烷烃; （b）在相对于羧基的α位上的碳上二或三氯取代的脂族羧酸的烷基酯; 和（c）在至少一个苯环的对位具有羧基烷基的氯三苯甲烷或二氯二苯基甲烷的衍生物。

10. 发明授权

US5382557A Procedure for the preparation of a solid component of catalyst for the (co)polymerization of ethylene 失效
标题翻译：制备乙烯（共）聚合催化剂固体成分的方法
公开(公告)号：US5382557A
公开(公告)日：1995-01-17
申请号：US911465
申请日：1992-07-10
申请人： Francesco Masi , Renzo Invernizzi , Angelo Moalli , Cesare Ferrero , Francesco Menconi , Lia Barazzoni
发明人： Francesco Masi , Renzo Invernizzi , Angelo Moalli , Cesare Ferrero , Francesco Menconi , Lia Barazzoni
IPC分类号： C08F4/658 , C08F4/60 , C08F4/652 , C08F4/654 , C08F10/00 , C08F10/02 , B01J31/00 , A01J25/08
CPC分类号： C08F10/02
摘要： A solid component of catalyst highly active in the (co)polymerization of ethylene containing titanium, magnesium, aluminum, chlorine and alkoxy groups, and obtained by means of a procedure wherein:(i) a solid, granular support of magnesium chloride, obtained by spray-drying an alcohol solution of magnesium chloride, is suspended in a liquid hydrocarbon solvent and an aliphatic alcohol and a titanium tetraalkoxide are added to the suspension thus obtained,(ii) the suspension of step (i) is heated until a homogeneous solution is obtained and the solution is cooled to precipitate a granular solid in a relative suspension,(iii) the granular solid obtained in step (ii), in the relative suspension, is put in contact and reacted with an aluminum alkyl halide, and(iv) the solid component catalyst is recovered from the reaction products of step (iii).
摘要翻译：在含有钛，镁，铝，氯和烷氧基的乙烯的（共）聚合中具有高活性的催化剂的固体组分，并且通过以下程序获得：其中：（i）由氯化镁的固体颗粒载体将氯化镁的醇溶液喷雾干燥，悬浮在液体烃溶剂中，并将脂肪醇和四烷氧基钛加入到由此获得的悬浮液中，（ii）将步骤（i）的悬浮液加热至均匀溶液并将溶液冷却以在相对悬浮液中沉淀出颗粒状固体，（iii）在相对悬浮液中获得的步骤（ii）中获得的颗粒状固体与烷基卤化铝反应，和（iv）从步骤（iii）的反应产物中回收固体组分催化剂。

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