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1. 发明授权

US09373735B2 Polyimide-metal laminate and solar cell 有权
标题翻译：聚酰亚胺金属层压板和太阳能电池
公开(公告)号：US09373735B2
公开(公告)日：2016-06-21
申请号：US12993951
申请日：2009-05-20
申请人： Hiroto Shimokawa , Takeshi Uekido , Naoyuki Matsumoto , Ken Kawagishi , Hiroaki Yamaguchi
发明人： Hiroto Shimokawa , Takeshi Uekido , Naoyuki Matsumoto , Ken Kawagishi , Hiroaki Yamaguchi
IPC分类号： H01L31/032 , H01L31/0392 , B29C41/24 , B29K79/00
CPC分类号： H01L31/0322 , B29C41/24 , B29K2079/08 , H01L31/03928 , Y02E10/541 , Y02P70/521
摘要： A polyimide-metal laminate comprising a polyimide film and a metal layer for use as an electrode, which is formed on the side (Side B) of the polyimide film which was in contact with a support when producing a self-supporting film in the production of the polyimide film, is used to produce a CIS solar cell.
摘要翻译：一种聚酰亚胺 - 金属层压体，其包含聚酰亚胺膜和用作电极的金属层，所述聚酰亚胺金属层叠体形成在所述聚酰亚胺膜的侧面（B侧），所述聚酰亚胺膜在制造时制造自支撑膜时与载体接触的聚酰亚胺膜用于制造CIS太阳能电池。

2. 发明申请

US20110079277A1 POLYIMIDE-METAL LAMINATE AND SOLAR CELL 有权
标题翻译：聚酰亚胺金属层压板和太阳能电池
公开(公告)号：US20110079277A1
公开(公告)日：2011-04-07
申请号：US12993951
申请日：2009-05-20
申请人： Hiroto Shimokawa , Takeshi Uekido , Naoyuki Matsumoto , Ken Kawagishi , Hiroaki Yamaguchi
发明人： Hiroto Shimokawa , Takeshi Uekido , Naoyuki Matsumoto , Ken Kawagishi , Hiroaki Yamaguchi
IPC分类号： H01L31/0272 , H01L31/0216 , H01L31/0224 , H01L31/04 , H01L31/18
CPC分类号： H01L31/0322 , B29C41/24 , B29K2079/08 , H01L31/03928 , Y02E10/541 , Y02P70/521
摘要： A polyimide-metal laminate comprising a polyimide film and a metal layer for use as an electrode, which is formed on the side (Side B) of the polyimide film which was in contact with a support when producing a self-supporting film in the production of the polyimide film, is used to produce a CIS solar cell.
摘要翻译：一种聚酰亚胺 - 金属层压体，其包含聚酰亚胺膜和用作电极的金属层，所述聚酰亚胺金属层叠体形成在所述聚酰亚胺膜的侧面（B侧），所述聚酰亚胺膜在制造时制造自支撑膜时与载体接触的聚酰亚胺膜用于制造CIS太阳能电池。

3. 发明授权

US09209333B2 Aromatic polyimide film, laminate and solar cell 有权
标题翻译：芳香聚酰亚胺薄膜，层压板和太阳能电池
公开(公告)号：US09209333B2
公开(公告)日：2015-12-08
申请号：US12993970
申请日：2009-05-20
申请人： Hiroto Shimokawa , Takeshi Uekido , Ken Kawagishi , Hiroaki Yamaguchi
发明人： Hiroto Shimokawa , Takeshi Uekido , Ken Kawagishi , Hiroaki Yamaguchi
IPC分类号： H01L31/0392 , C08J5/18
CPC分类号： H01L31/0392 , C08J5/18 , C08J2379/08 , H01L31/03928 , Y02E10/541 , Y02P70/521 , Y10T428/31681
摘要： Disclosed is a polyimide film prepared from an aromatic tetracarboxylic acid component and an aromatic diamine component, which has a dimensional change from 25° C. to 500° C. within a range of from −0.3% to +0.6% based on the initial dimension at 25° C. The polyimide film may be used as a substrate for a CIS solar cell.
摘要翻译：公开了由芳香族四羧酸成分和芳香族二胺成分制成的聚酰亚胺膜，其在基于初始尺寸的范围内，在从25℃至500℃的范围内变化范围为-0.3％至+ 0.6％聚酰亚胺膜可以用作CIS太阳能电池的基板。

4. 发明申请

US20110067760A1 AROMATIC POLYIMIDE FILM, LAMINATE AND SOLAR CELL 有权
标题翻译：芳香聚酰亚胺膜，层压板和太阳能电池
公开(公告)号：US20110067760A1
公开(公告)日：2011-03-24
申请号：US12993970
申请日：2009-05-20
申请人： Hiroto Shimokawa , Takeshi Uekido , Ken Kawagishi , Hiroaki Yamaguchi
发明人： Hiroto Shimokawa , Takeshi Uekido , Ken Kawagishi , Hiroaki Yamaguchi
IPC分类号： C08G73/10 , B32B15/08 , H01L31/0216
CPC分类号： H01L31/0392 , C08J5/18 , C08J2379/08 , H01L31/03928 , Y02E10/541 , Y02P70/521 , Y10T428/31681
摘要： Disclosed is a polyimide film prepared from an aromatic tetracarboxylic acid component and an aromatic diamine component, which has a dimensional change from 25° C. to 500° C. within a range of from −0.3% to +0.6% based on the initial dimension at 25° C. The polyimide film may be used as a substrate for a CIS solar cell.
摘要翻译：公开了由芳香族四羧酸成分和芳香族二胺成分制成的聚酰亚胺膜，其在基于初始尺寸的范围内，在从25℃至500℃的范围内变化范围为-0.3％至+ 0.6％聚酰亚胺膜可以用作CIS太阳能电池的基板。

5. 发明申请

US20120034455A1 POLYIMIDE FILM, METHOD FOR PRODUCING THE SAME, AND METAL-LAMINATED POLYIMIDE FILM 审中-公开
标题翻译：聚酰亚胺膜，其制造方法和金属层压聚酰亚胺膜
公开(公告)号：US20120034455A1
公开(公告)日：2012-02-09
申请号：US13264492
申请日：2010-04-14
申请人： Naoyuki Matsumoto , Hidenori Mii , Takeshi Uekido , Nobu Iizumi , Keiichi Yanagida , Eiji Masui , Toshiyuki Nishino , Takao Miyamoto
发明人： Naoyuki Matsumoto , Hidenori Mii , Takeshi Uekido , Nobu Iizumi , Keiichi Yanagida , Eiji Masui , Toshiyuki Nishino , Takao Miyamoto
IPC分类号： B32B15/08 , B29C55/02 , B32B27/08
CPC分类号： B29C55/04 , B29C41/24 , B29C41/28 , B29C55/08 , B29K2079/08 , B32B7/12 , B32B15/08 , B32B15/085 , B32B15/20 , B32B27/08 , B32B27/281 , B32B27/38 , B32B2255/10 , B32B2255/205 , B32B2307/514 , B32B2307/546 , B32B2307/732 , B32B2457/08 , C08G73/1042 , C08G73/1046 , C08G73/105 , C08G73/1067 , C08G73/1071 , C09D179/08 , C23C18/1641 , C23C18/165 , C23C18/31 , H05K1/0346 , H05K2201/0154 , Y10T428/265 , Y10T428/31681 , Y10T428/31721
摘要： The present invention provides a polyimide film having an anisotropic thermal expansion coefficient, and comprising a polyimide layer (b) and a polyimide layer (a) on one side or both sides of the polyimide layer (b), wherein the polyimide layer (a) is a layer of a polyimide prepared from a monomer component comprising a diamine having the structure of the following formula (1): wherein R represents a monovalent group selected from the groups listed as the following formula (2): wherein R1 represents a hydrogen atom or a methyl group, and two R1 groups may be the same as, or different from each other.
摘要翻译：本发明提供一种具有各向异性热膨胀系数的聚酰亚胺膜，在聚酰亚胺层（b）的一侧或两面上包含聚酰亚胺层（b）和聚酰亚胺层（a），其中聚酰亚胺层（a）是由包含具有下式（1）的结构的二胺的单体组分制备的聚酰亚胺层：其中R表示选自下列通式（2）所示的一价基团：其中R 1表示氢原子或甲基，并且两个R 1基团可以彼此相同或不同。

6. 发明申请

US20120028061A1 POLYIMIDE FILM FOR METALLIZING, METHOD FOR PRODUCING SAME, AND METAL-LAMINATED POLYIMIDE FILM 审中-公开
标题翻译：用于金属化的聚酰亚胺膜，其制造方法和金属层压聚酰亚胺膜
公开(公告)号：US20120028061A1
公开(公告)日：2012-02-02
申请号：US13264520
申请日：2010-04-14
申请人： Naoyuki Matsumoto , Hidenori Mii , Takeshi Uekido , Nobu Iizumi , Keiichi Yanagida , Eiji Masui , Toshiyuki nishino , Takao Miyamoto
发明人： Naoyuki Matsumoto , Hidenori Mii , Takeshi Uekido , Nobu Iizumi , Keiichi Yanagida , Eiji Masui , Toshiyuki nishino , Takao Miyamoto
IPC分类号： B32B27/06 , B05D3/02
CPC分类号： H05K1/0346 , B29C41/24 , B29C55/04 , B29K2079/08 , B32B7/12 , B32B15/08 , B32B15/20 , B32B27/281 , B32B2255/10 , B32B2255/205 , B32B2307/306 , B32B2307/3065 , B32B2307/308 , B32B2307/516 , B32B2307/546 , B32B2307/714 , B32B2307/732 , B32B2457/08 , C08G73/1042 , C08G73/1046 , C08G73/105 , C08G73/1067 , C08G73/1071 , C09D179/08 , H05K3/388 , H05K3/389 , H05K2201/0154 , Y10T428/31721
摘要： The present invention provides a polyimide film for metallizing, which has an anisotropic thermal expansion coefficient, and comprises a polyimide layer (b) and a polyimide layer (a) on one side or both sides of the polyimide layer (b); wherein the polyimide layer (b) is a layer of a polyimide prepared from an acid component comprising 3,3′,4,4′-biphenyltetracarboxylic dianhydride and a diamine component comprising p-phenylenediamine; and the polyimide layer (a) is a layer of a polyimide prepared from a monomer component comprising at least one selected from the group consisting of phenylenediamines and diaminodiphenyl ethers as a diamine component, and contains a surface treatment agent.
摘要翻译：本发明提供一种具有各向异性热膨胀系数的金属化用聚酰亚胺膜，在聚酰亚胺层（b）的一侧或两面包含聚酰亚胺层（b）和聚酰亚胺层（a）。其中所述聚酰亚胺层（b）是由包含3,3'，4,4'-联苯四羧酸二酐的酸组分和包含对苯二胺的二胺组分制备的聚酰亚胺层; 并且聚酰亚胺层（a）是由包含选自由苯二胺和作为二胺成分的二氨基二苯基醚组成的组中的至少一种的单体组分制备的聚酰亚胺层，并且含有表面处理剂。

7. 发明申请

US20140058060A1 POLYIMIDE FILM PRODUCTION METHOD, POLYIMIDE FILM PRODUCTION APPARATUS, AND POLYIMIDE FILM 有权
标题翻译：聚酰亚胺薄膜生产方法，聚酰亚胺薄膜生产设备和聚酰亚胺薄膜
公开(公告)号：US20140058060A1
公开(公告)日：2014-02-27
申请号：US14007079
申请日：2012-03-19
申请人： Takeshi Uekido
发明人： Takeshi Uekido
IPC分类号： H01L31/02
CPC分类号： H01L31/02 , B29C41/28 , B29C2035/0822 , B29K2079/08 , C08J5/18 , C08J2379/08 , H01L31/0392 , H01L31/03926 , Y02E10/50
摘要： A polyimide film which rarely undergoes the formation of bubbles, blisters or the like, even when heated to a high temperature; and a production method and a production apparatus for the polyimide film. The polyimide film production apparatus includes a support body, a cast furnace and a cure furnace, wherein the cure furnace is partitioned into multiple zones so that the temperature of a self-supporting film can be increased in a stepwise manner, and an infrared electric heater, which is disposed at a predetermined distance from the film, is arranged in a zone for heating the atmosphere of the self-supporting film to a temperature of 450° C. or higher on the upper surface side and/or the lower surface side of the self-supporting film. The polyimide production apparatus enables the production of a polyimide film which has a volatile content of 0.1 mass % or less after being heated at 450° C. for 20 minutes.
摘要翻译：即使加热到高温也很少会形成气泡，起泡等的聚酰亚胺膜; 以及聚酰亚胺膜的制造方法和制造装置。聚酰亚胺膜制造装置包括支撑体，铸造炉和固化炉，其中固化炉被分割成多个区域，使得自支撑膜的温度可以逐步地增加，并且红外电加热器被设置在距膜的预定距离处，被设置在用于将自支撑膜的气氛加热到450℃以上的温度的区域中，在该区域的上表面侧和/或下表面侧自拍电影。该聚酰亚胺生产装置能够在450℃下加热20分钟后生产挥发量为0.1质量％以下的聚酰亚胺膜。

8. 发明授权

US09276139B2 Polyimide film production method, polyimide film production apparatus, and polyimide film 有权
标题翻译：聚酰亚胺膜制造方法，聚酰亚胺膜制造装置和聚酰亚胺膜
公开(公告)号：US09276139B2
公开(公告)日：2016-03-01
申请号：US14007079
申请日：2012-03-19
申请人： Takeshi Uekido
发明人： Takeshi Uekido
IPC分类号： B29D7/00 , H01L31/02 , B29C41/28 , C08J5/18 , H01L31/0392 , B29K79/00 , B29C35/08
CPC分类号： H01L31/02 , B29C41/28 , B29C2035/0822 , B29K2079/08 , C08J5/18 , C08J2379/08 , H01L31/0392 , H01L31/03926 , Y02E10/50
摘要： A polyimide film which rarely undergoes the formation of bubbles, blisters or the like, even when heated to a high temperature; and a production method and a production apparatus for the polyimide film. The polyimide film production apparatus includes a support body, a cast furnace and a cure furnace, wherein the cure furnace is partitioned into multiple zones so that the temperature of a self-supporting film can be increased in a stepwise manner, and an infrared electric heater, which is disposed at a predetermined distance from the film, is arranged in a zone for heating the atmosphere of the self-supporting film to a temperature of 450° C. or higher on the upper surface side and/or the lower surface side of the self-supporting film. The polyimide production apparatus enables the production of a polyimide film which has a volatile content of 0.1 mass % or less after being heated at 450° C. for 20 minutes.
摘要翻译：即使加热到高温也很少会形成气泡，起泡等的聚酰亚胺膜; 以及聚酰亚胺膜的制造方法和制造装置。聚酰亚胺膜制造装置包括支撑体，铸造炉和固化炉，其中固化炉被分割成多个区域，使得自支撑膜的温度可以逐步地增加，并且红外电加热器被设置在距膜的预定距离处，被设置在用于将自支撑膜的气氛加热到450℃以上的温度的区域中，在该区域的上表面侧和/或下表面侧自拍电影。该聚酰亚胺生产装置能够在450℃下加热20分钟后生产挥发量为0.1质量％以下的聚酰亚胺膜。

9. 发明申请

US20120292800A1 PROCESS AND EQUIPMENT FOR PRODUCTION OF POLYIMIDE FILM 审中-公开
标题翻译：生产聚酰亚胺膜的工艺和设备
公开(公告)号：US20120292800A1
公开(公告)日：2012-11-22
申请号：US13575138
申请日：2011-01-24
申请人： Yohei Higuchi , Yasuhiro Nagoshi , Takeshi Uekido , Toshiyuki Nishino , Eiji Masui
发明人： Yohei Higuchi , Yasuhiro Nagoshi , Takeshi Uekido , Toshiyuki Nishino , Eiji Masui
IPC分类号： B29C39/44
CPC分类号： B29C41/28 , B29K2079/08 , C08J5/18 , C08J2379/08 , G01B11/0691 , G01N21/86 , G01N2021/869
摘要： Provided are a method and apparatus for the production of a polyimide film, which allow a polyimide film having physical properties with in-plane uniformity to be produced with high productivity. In the method for the production of a polyimide film, a solvent content of a self-supporting film is measured by infrared spectroscopy, and based on the measurement result, one or more kinds selected from a drying condition of a cast of a polyimide precursor solution, a post-heating condition of the self-supporting film, and an amount of extrusion of a polyimide precursor solution from a die are controlled.
摘要翻译：提供一种用于制造聚酰亚胺膜的方法和装置，其允许以高生产率制造具有面内均匀性的物理性质的聚酰亚胺膜。在制造聚酰亚胺膜的方法中，通过红外光谱法测定自支撑膜的溶剂含量，根据测定结果，选自聚酰亚胺前体溶液的铸件的干燥条件中的一种以上，自支撑膜的后加热条件以及来自模具的聚酰亚胺前体溶液的挤出量被控制。

10. 发明授权

US08053082B2 Adhesion-enhanced polyimide film, process for its production, and laminated body 有权
标题翻译：粘合增强聚酰亚胺膜，其生产方法和层压体
公开(公告)号：US08053082B2
公开(公告)日：2011-11-08
申请号：US10591749
申请日：2005-03-02
申请人： Masafumi Hashimoto , Takeshi Uekido , Toshiyuki Nishino , Toshihiko Anno
发明人： Masafumi Hashimoto , Takeshi Uekido , Toshiyuki Nishino , Toshihiko Anno
IPC分类号： B32B15/08 , B32B27/00 , B05D3/02
CPC分类号： B32B27/281 , B32B15/08 , B32B27/08 , B32B2307/306 , B32B2379/08 , Y10T428/31681 , Y10T428/31721
摘要： An adhesion-enhanced polyimide film which includes a core layer composed of a polyimide (a) having high rigidity and a low linear expansion coefficient, at least one side of which has a thin-layer formed by heating a coated layer including a heat-resistant surface treatment agent and a polyimide precursor which yields a highly heat-resistant amorphous polyimide (B).
摘要翻译：一种粘合增强聚酰亚胺膜，其包括由具有高刚性和低线膨胀系数的聚酰亚胺（a）构成的芯层，其至少一侧具有通过加热包括耐热性的涂层而形成的薄层表面处理剂和产生高耐热性无定形聚酰亚胺（B）的聚酰亚胺前体。

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