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1. 发明授权

US5585526A Preparation of P-fuchsones and synthesis of P-Dihydroxylated aromatic compounds therefrom 失效
标题翻译： P-呋喃酮的制备和由其衍生的对二羟基化芳族化合物
公开(公告)号：US5585526A
公开(公告)日：1996-12-17
申请号：US463733
申请日：1995-06-05
申请人： Michel Costantini , Daniel Manaut , Daniel Michelet
发明人： Michel Costantini , Daniel Manaut , Daniel Michelet
IPC分类号： B01J27/02 , B01J27/08 , B01J31/02 , C07B61/00 , C07C37/07 , C07C37/20 , C07C37/60 , C07C37/88 , C07C39/08 , C07C39/11 , C07C39/12 , C07C45/29 , C07C45/45 , C07C45/51 , C07C49/603 , C07C49/657 , C07C49/683 , C07C49/747 , C07C49/753
CPC分类号： C07C37/07 , C07C37/60 , C07C45/512 , C07C45/513 , C07C49/683 , C07C49/747 , C07C49/753
摘要： p-Dihydroxylated aromatic compounds are prepared via the oxidation of p-fuchsones, the latter advantageously being synthesized by reacting a phenolic compound having at least one hydrogen atom in the para-position to the hydroxyl function with a non-enolizable ketonic compound, in the presence of a catalytically effective amount of an acid catalyst and, optionally, a cocatalytically effective amount of an ionizable sulfur-containing compound.
摘要翻译：对 - 二羟基化的芳族化合物是通过p-胡蜂酮的氧化制备的，后者有利地通过使对位中具有至少一个氢原子的酚化合物与羟基官能团与非烯醇化酮化合物反应来合成，存在催化有效量的酸催化剂和任选的助催化有效量的可电离的含硫化合物。

2. 发明授权

US5466839A Preparation of p-fuchsones and synthesis of p-dihydroxylated aromatic compounds therefrom 失效
标题翻译： β-胡椒碱的制备及其由对二羟基化芳族化合物的合成
公开(公告)号：US5466839A
公开(公告)日：1995-11-14
申请号：US179234
申请日：1994-01-10
申请人： Michel Costantini , Daniel Manaut , Daniel Michelet
发明人： Michel Costantini , Daniel Manaut , Daniel Michelet
IPC分类号： B01J27/02 , B01J27/08 , B01J31/02 , C07B61/00 , C07C37/07 , C07C37/20 , C07C37/60 , C07C37/88 , C07C39/08 , C07C39/11 , C07C39/12 , C07C45/29 , C07C45/45 , C07C45/51 , C07C49/603 , C07C49/657 , C07C49/683 , C07C49/747 , C07C49/753
CPC分类号： C07C37/07 , C07C37/60 , C07C45/512 , C07C45/513 , C07C49/683 , C07C49/747 , C07C49/753
摘要： p-Dihydroxylated aromatic compounds are prepared via the oxidation of p-fuchsones, the latter advantageously being synthesized by reacting a phenolic compound having at least one hydrogen atom in the para-position to the hydroxyl function with a non-enolizable ketonic compound, in the presence of a catalytically effective amount of an acid catalyst and, optionally, a cocatalytically effective amount of an ionizable sulfur-containing compound.
摘要翻译：对 - 二羟基化的芳族化合物是通过p-胡蜂酮的氧化制备的，后者有利地通过使对位中具有至少一个氢原子的酚化合物与羟基官能团与非烯醇化酮化合物反应来合成，存在催化有效量的酸催化剂和任选的助催化有效量的可电离的含硫化合物。

3. 发明授权

US5670465A Preparation of p-fuchsones and synthesis of p-dihydroxylated aromatic compounds therefrom 失效
标题翻译： β-胡椒碱的制备及其由对二羟基化芳族化合物的合成
公开(公告)号：US5670465A
公开(公告)日：1997-09-23
申请号：US464311
申请日：1995-06-05
申请人： Michel Costantini , Daniel Manaut , Daniel Michelet
发明人： Michel Costantini , Daniel Manaut , Daniel Michelet
IPC分类号： B01J27/02 , B01J27/08 , B01J31/02 , C07B61/00 , C07C37/07 , C07C37/20 , C07C37/60 , C07C37/88 , C07C39/08 , C07C39/11 , C07C39/12 , C07C45/29 , C07C45/45 , C07C45/51 , C07C49/603 , C07C49/657 , C07C49/683 , C07C49/747 , C07C49/753
CPC分类号： C07C37/07 , C07C37/60 , C07C45/512 , C07C45/513 , C07C49/683 , C07C49/747 , C07C49/753
摘要： p-Dihydroxylated aromatic compounds are prepared via the oxidation of p-fuchsones, the latter advantageously being synthesized by reacting a phenolic compound having at least one hydrogen atom in the para-position to the hydroxyl function with a non-enolizable ketonic compound, in the presence of a catalytically effective amount of an acid catalyst and, optionally, a cocatalytically effective amount of an ionizable sulfur-containing compound.
摘要翻译：对 - 二羟基化的芳族化合物是通过p-胡蜂酮的氧化制备的，后者有利地通过使对位中具有至少一个氢原子的酚化合物与羟基官能团与非烯醇化酮化合物反应来合成，存在催化有效量的酸催化剂和任选的助催化有效量的可电离的含硫化合物。

4. 发明授权

US5414155A Preparation of o-dihydroxylated aromatic compounds via oxidation of o-fuchsones 失效
标题翻译：通过o-五味子的氧化制备邻二羟基化芳族化合物
公开(公告)号：US5414155A
公开(公告)日：1995-05-09
申请号：US179130
申请日：1994-01-10
申请人： Michel Costantini , Daniel Manaut , Daniel Michelet
发明人： Michel Costantini , Daniel Manaut , Daniel Michelet
IPC分类号： C07C37/07 , C07C37/50 , C07C37/60 , C07C39/08
CPC分类号： C07C37/60
摘要： o-Dihydroxylated aromatic compounds, for example pyrocatechol, are selectively prepared by reacting an o-fuchsone with an oxidizing agent, for example hydrogen peroxide, optionally in the presence of a catalytically effective amount of an acid catalyst.
摘要翻译： O-二羟基化芳族化合物，例如邻苯二酚，可以通过使o-氟沙星与氧化剂（例如过氧化氢）反应，任选地在催化有效量的酸催化剂存在下进行选择性制备。

5. 发明授权

US5399336A Stannozeosilite/zirconozeosilite zeolites and catalytic hydroxylation of phenolics therewith 失效
标题翻译：硅酸锌/氧化锆硅沸石沸石和酚醛树脂的催化羟基化
公开(公告)号：US5399336A
公开(公告)日：1995-03-21
申请号：US724215
申请日：1991-07-01
申请人： Jean-Louis Guth , Michel Costantini , Annie Lopez , Jean-Michel Popa
发明人： Jean-Louis Guth , Michel Costantini , Annie Lopez , Jean-Michel Popa
IPC分类号： B01J29/89 , B01J29/04 , B01J29/40 , C01B39/04 , C01B39/08 , C01B39/10 , C01B39/36 , C07C37/60 , C07C41/26 , C10G11/05 , C10G35/095 , C01B33/20
CPC分类号： C07C41/26 , B01J29/04 , C07C37/60 , Y10S423/22
摘要： Calcined silica/oxide zeolites, characteristically MFI stannozeosilites or zirconozeosilites, well adopted for catalyzing the H.sub.2 O.sub.2 hydroxylation of phenols or phenol ethers, have the formula (I):(Si.sub.96-x T'.sub.x)0.sub.192 (I)in which x is a number ranging from 0.1 to 5.0 and T' is tetravalent tin or tetravalent zirconium.
摘要翻译：煅烧二氧化硅/氧化物沸石，特别是用于催化苯酚或酚醚的H 2 O 2羟基化的MFI锡酮化合物或氧化锆沸石具有式（I）：（Si96-xT'x）0192（I），其中x是数字范围 0.1〜5.0，T'为四价锡或四价锆。

6. 发明授权

US5254746A Hydroxylation of phenols/phenol ethers 失效
标题翻译：苯酚/酚醚的羟基化
公开(公告)号：US5254746A
公开(公告)日：1993-10-19
申请号：US930457
申请日：1992-08-19
申请人： Michel Costantini , Jean-Michel Popa , Michel Gubelmann
发明人： Michel Costantini , Jean-Michel Popa , Michel Gubelmann
IPC分类号： B01J29/89 , C07C37/60 , C07C41/26 , C07C43/11
CPC分类号： C07C41/26 , B01J29/89 , C07C37/60
摘要： The phenols and phenol ethers are hydroxylated by reaction with hydrogen peroxide in the presence of a catalytically effective amount of a titanozeosilite, advantageously a silicon oxide/titanium oxide MFI zeolite having the general formula:SI.sub.(96-x), Ti.sub.x O.sub.192.
摘要翻译：苯酚和酚醚通过在催化有效量的钛硅硅酸盐存在下与过氧化氢反应而羟化，有利地是具有通式SI（96-x），TixO192的氧化硅/氧化钛MFI沸石。

7. 发明授权

US5159120A Preparation of dialkoxybutenes 失效
标题翻译： DIALKOXYBUTENES的制备
公开(公告)号：US5159120A
公开(公告)日：1992-10-27
申请号：US714584
申请日：1991-06-13
申请人： Michel Costantini , Dominique Laucher
发明人： Michel Costantini , Dominique Laucher
IPC分类号： B01J27/057 , C07B61/00 , C07C41/06 , C07C43/15
CPC分类号： C07C41/06
摘要： Dialkoxybutenes are selectively prepared in high yields by reacting 1,3-butadiene with an alcohol in the presence of oxygen and a catalytically effective amount of solid particulates which comprise a catalytically active phase deposited onto particles of a support therefor, such catalytically active phase comprising at least one Group VIII noble metal first component, at least one tellurium, selenium and/or sulfur second component, and, optionally, at least one bismuth, antimony, copper and/or tin third component.
摘要翻译：通过在氧的存在下使1,3-丁二烯与醇反应并且催化有效量的固体颗粒包含沉积在其载体的颗粒上的催化活性相来选择性地制备二烷氧基丁烯，所述催化活性相包含在至少一种VIII族贵金属第一组分，至少一种碲，硒和/或硫第二组分，以及任选的至少一种铋，锑，铜和/或锡第三组分。

8. 发明授权

US4093636A Epoxidation of olefinic compounds 失效
标题翻译：烯烃化合物的环氧化
公开(公告)号：US4093636A
公开(公告)日：1978-06-06
申请号：US768630
申请日：1977-02-14
申请人： Pierre-Etienne Bost , Michel Costantini
发明人： Pierre-Etienne Bost , Michel Costantini
IPC分类号： B01J31/12 , B01J37/24 , C07D301/20
CPC分类号： B01J37/24 , B01J31/122 , B01J2231/72
摘要： Tin catalysts are provided for epoxidizing olefinic compounds in the presence of organic hydroperoxides, in the liquid phase. These catalysts give good yields of the epoxide and of the alcohol derived from the organic hydroperoxide. They have the formula: RR 'SnCl.sub.2 (I) in which:R represents a wholly aliphatic or cycloaliphatic or aromatic or mixed aliphatic/aromatic, aliphatic/cycloaliphatic or cycloaliphatic/aromatic, inter alia alkylaryl or aralkyl, linear or branched, saturated or unsaturated monovalent hydrocarbon radical, which can optionally carry substituents, such as chlorine atoms, the number of carbon atoms being at most 20,R' represents either a chlorine atom or a monovalent organic radical of the formula: R"--Y (II) in which:Y represents an oxygen atom, or a (--O--O--) group, or a carbonyloxy group (--CO--O--), the radical R" being attached to the carbon atom of the (--CO--O--),R" may be identical or different to R and is as defined under R.
摘要翻译：在有机氢过氧化物存在下，在液相中提供锡催化剂用于环氧化烯属化合物。这些催化剂产生环氧化物和衍生自有机氢过氧化物的醇的良好产率。他们有公式：

9. 发明授权

US4092361A Process for the preparation of 3,5,5-trimethyl-cyclohex-2-ene-1,4-dione 失效
标题翻译：制备3,5,5-三甲基 - 环己-2-烯-1,4-二酮的方法
公开(公告)号：US4092361A
公开(公告)日：1978-05-30
申请号：US751159
申请日：1976-12-16
申请人： Michel Costantini , Adrien Dromard , Michel Jouffret
发明人： Michel Costantini , Adrien Dromard , Michel Jouffret
IPC分类号： C07C49/403 , C07C45/00 , C07C45/34 , C07C45/35 , C07C49/603 , C07C67/00
CPC分类号： C07C45/34
摘要： 3,5,5-Trimethyl-cyclohex-2-ene-1,4-dione is prepared by a liquid phase oxidation of .beta.-isophorone using carbon black as catalyst in the presence of a base.
摘要翻译：通过在碱存在下使用炭黑作为催化剂，通过β-异佛尔酮的液相氧化制备3,5,5-三甲基 - 环己-2-烯-1,4-二酮。

10. 发明授权

US06762319B1 Hydrocarbon, alcohol and/or ketone oxidation method 失效
标题翻译：烃，醇和/或酮氧化方法
公开(公告)号：US06762319B1
公开(公告)日：2004-07-13
申请号：US09937764
申请日：2002-04-16
申请人： Eric Fache , Michel Costantini
发明人： Eric Fache , Michel Costantini
IPC分类号： C07C5116
CPC分类号： C07C29/50 , C07C51/313 , C07C2601/14 , C07C55/14 , C07C35/08
摘要： The present invention relates to the oxidation, by means of oxygen or a gas containing it, of hydrocarbons to the corresponding carboxylic acids, alcohols and/or ketones or of alcohols and/or ketones to the corresponding carboxylic acids. It consists more precisely in a process for oxidizing hydrocarbon, alcohol and/or ketone, using oxygen or a gas containing it, in liquid phase and in the presence of a catalyst dissolved in the reaction medium, characterized in that the catalyst comprises a soluble manganese compound and at least one soluble chromium compound.
摘要翻译：本发明涉及通过氧气或含有它的气体将烃与相应的羧酸，醇和/或酮或醇和/或酮与相应的羧酸氧化。它更精确地包括在液相中和在溶解在反应介质中的催化剂存在下，使用氧气或含有它的气体氧化烃，醇和/或酮的方法，其特征在于催化剂包含可溶性锰化合物和至少一种可溶性铬化合物。

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