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1. 发明授权

US07659359B1 Stabilization of isosorbide-based polycarbonate 有权
标题翻译：异山梨醇基聚碳酸酯的稳定化
公开(公告)号：US07659359B1
公开(公告)日：2010-02-09
申请号：US12273132
申请日：2008-11-18
申请人： Roland Assink , Hans de Brouwer , Bernd Jansen , Jan Henk Kamps , Wilhelmus Johannes Daniel Steendam , Jan-Willem Goedmakers
发明人： Roland Assink , Hans de Brouwer , Bernd Jansen , Jan Henk Kamps , Wilhelmus Johannes Daniel Steendam , Jan-Willem Goedmakers
IPC分类号： C08G64/00 , C08G63/00
CPC分类号： C08J3/02 , C08G64/0208 , C08J2369/00
摘要： An isosorbide-containing polycarbonate composition is provided. The composition contains a polycarbonate having repeat units derived from isosorbide, a polycarbonate-property-modifying additive, and a pH stabilizer. When a solution containing 10 wt. % of the composition dissolved in dichloromethane is prepared the solution has a non-aqueous pH in a range of equal to or between 0.8 below and 0.5 above the pH of the dichloromethane.
摘要翻译：提供含有异山梨醇的聚碳酸酯组合物。组合物含有具有衍生自异山梨醇，聚碳酸酯性质改性添加剂和pH稳定剂的重复单元的聚碳酸酯。当含有10wt。制备溶解在二氯甲烷中的组合物的％，该溶液具有在二氯甲烷的pH以下等于或低于0.8或低于0.5的范围内的非水性pH。

2. 发明申请

US20060014919A9 Translucent thermoplastic composition, method for making the composition and articles molded there from 有权
标题翻译：半透明热塑性组合物，制备组合物的方法和在其上成型的制品
公开(公告)号：US20060014919A9
公开(公告)日：2006-01-19
申请号：US10783140
申请日：2004-02-20
申请人： Robert Venderbosch , Jan-Willem Goedmakers , Jeremy Hurst
发明人： Robert Venderbosch , Jan-Willem Goedmakers , Jeremy Hurst
IPC分类号： C08G64/00
CPC分类号： C08L83/10 , C08L25/12 , C08L55/02 , C08L67/02 , C08L69/00 , C08L2666/02
摘要： A thermoplastic composition comprising a matrix of a polycarbonate polymer in which are embedded polysiloxane domains with an average domain size between 20 and 45 nanometers. Said compositions can be obtained by combining a first polycarbonate/poly(diorganosiloxane) copolymer; with a second polycarbonate/poly(diorganosiloxane) copolymer. A range of translucencies are obtainable by varying the relative amounts of the two copolymers without substantial loss in impact properties.
摘要翻译：一种热塑性组合物，其包含聚碳酸酯聚合物的基质，其中嵌入的聚硅氧烷域的平均域尺寸为20至45纳米。所述组合物可以通过组合第一聚碳酸酯/聚（二有机硅氧烷）共聚物; 与第二聚碳酸酯/聚（二有机硅氧烷）共聚物。可以通过改变两种共聚物的相对量而不会在冲击性能方面实质上损失来获得一系列透明性。

3. 发明授权

US07632913B2 Method of producing polycarbonate in a flash devolatilization system 有权
标题翻译：在闪蒸脱挥发分系统中生产聚碳酸酯的方法
公开(公告)号：US07632913B2
公开(公告)日：2009-12-15
申请号：US11863723
申请日：2007-09-28
申请人： Maarten Antoon Jan Campman , Jan-Willem Goedmakers , Jürg Keller , Peter Willi Kreis
发明人： Maarten Antoon Jan Campman , Jan-Willem Goedmakers , Jürg Keller , Peter Willi Kreis
IPC分类号： C08G6/00 , C08G63/02
CPC分类号： B01J19/2415 , B01J19/245 , B01J2219/00159 , B01J2219/00162 , C08G64/205 , C08G64/305
摘要： The present invention provides a reactor system for producing polycarbonate. The reactor system has one or more reactant vessels, an oligomerization reactor, a first pressure control device, a preheater, a second pressure control device, a distributor, and a flash tank. The one or more reactant vessels contain reactants contain a melt transesterification catalyst, a dihydroxy compound, and an activated diaryl carbonate. The reactor system is connected in the following configuration: (i) the one or more reactant vessels connected to the oligomerization reactor, (ii) the first pressure control device disposed between and connecting the outlet of the oligomerization reactor and the inlet of the preheater; (iii) the second pressure control device disposed between and connecting the outlet of the preheater and the distributor; and (iv) the distributor disposed at the inlet to the flash tank. The pressure in the preheater is controllable at a pressure intermediate between the pressure in the oligomerization reactor and the flash tank.
摘要翻译：本发明提供了一种用于生产聚碳酸酯的反应器系统。反应器系统具有一个或多个反应物容器，低聚反应器，第一压力控制装置，预热器，第二压力控制装置，分配器和闪蒸罐。一个或多个反应物容器包含含有熔体酯交换催化剂，二羟基化合物和活化的碳酸二芳基酯的反应物。反应器系统以如下结构连接：（i）连接到低聚反应器的一个或多个反应容器，（ii）设置在低聚反应器的出口和预热器入口之间并连接低聚反应器的出口的第一压力控制装置; （iii）所述第二压力控制装置设置在所述预热器和所述分配器之间并连接所述预热器的出口; 和（iv）布置在闪蒸罐的入口处的分配器。预热器中的压力可以在低聚反应器和闪蒸罐中的压力之间的压力下控制。

4. 发明申请

US20080149164A1 LUMINESCENT THERMOPLASTIC COMPOSITIONS AND ARTICLES WITH ENHANCED EDGE EMISSION 审中-公开
标题翻译：亮度热塑性组合物和具有增强边缘排放的文章
公开(公告)号：US20080149164A1
公开(公告)日：2008-06-26
申请号：US11615376
申请日：2006-12-22
申请人： Jan-Willem Goedmakers , Theodorus Lambertus Hoeks , Jeremy D. Hurst , Marcus Zettl
发明人： Jan-Willem Goedmakers , Theodorus Lambertus Hoeks , Jeremy D. Hurst , Marcus Zettl
IPC分类号： H01L31/042
CPC分类号： H01L31/055 , C08K5/0041 , C08K5/01 , C08L69/005 , Y02E10/52 , C08L2666/02
摘要： A thermoplastic composition is provided comprising a thermoplastic polymer, a fluorescent dye or quantum dot, and a diffuser. When molded into an article, the composition has a haze level less than 55 at an article thickness, according to ASTM D1003-00. The composition has increased energy efficiency and enhances the emission of light at the edges of the article. The composition is particularly suited for use as a component of a luminescent solar collector.
摘要翻译：提供了包含热塑性聚合物，荧光染料或量子点和漫射器的热塑性组合物。当模制成制品时，根据ASTM D1003-00，组合物在制品厚度下的雾度水平低于55。该组合物提高了能量效率并且增强了在制品边缘处的光的发射。该组合物特别适合用作发光太阳能收集器的组分。

5. 发明授权

US5876609A Process for treating methylchlorosilanes by-products 失效
标题翻译：甲基氯硅烷副产物的处理方法
公开(公告)号：US5876609A
公开(公告)日：1999-03-02
申请号：US827554
申请日：1997-03-28
申请人： Michael Lee White , Sunita Singh Baghel , Luisito Alvarez Tolentino , Mark Kromer Barr , David Cheney DeMoulpied , William Lee Gately , Jan-Willem Goedmakers , Jeffrey David Hallen , Edward Francis Kennedy , Bang Mo Kim , Ray Walton Shade , Matthew David Butts
发明人： Michael Lee White , Sunita Singh Baghel , Luisito Alvarez Tolentino , Mark Kromer Barr , David Cheney DeMoulpied , William Lee Gately , Jan-Willem Goedmakers , Jeffrey David Hallen , Edward Francis Kennedy , Bang Mo Kim , Ray Walton Shade , Matthew David Butts
IPC分类号： C07F7/12 , C07F7/16 , C07F7/20 , C02F1/54 , C02F1/62
CPC分类号： C07F7/16 , Y10S210/912
摘要： The instant invention relates to a novel process for the hydrolysis of the by-products produced during the manufacture of methyldichlorosilanes comprising combining the by-products with an aqueous medium, optionally comprising a surfactant, at a pH range of at least about 7 and at a temperature of above about 0.degree. C. to produce a solid material in which copper and other metals are retained in a solid phase thereby resulting in a product with a high copper content.
摘要翻译：本发明涉及在制备甲基二氯硅烷期间产生的副产物的水解的新方法，包括将副产物与任选包含表面活性剂的水性介质在至少约7的pH范围和温度高于约0℃以产生固体材料，其中铜和其它金属保留在固相中，从而导致具有高铜含量的产物。

6. 发明申请

US20090088538A1 Method of Producing Polycarbonate in a Flash Devolatilization System 有权
标题翻译：在闪蒸脱挥发系统中生产聚碳酸酯的方法
公开(公告)号：US20090088538A1
公开(公告)日：2009-04-02
申请号：US11863723
申请日：2007-09-28
申请人： Maarten Antoon Jan Campman , Jan-Willem Goedmakers
发明人： Maarten Antoon Jan Campman , Jan-Willem Goedmakers
IPC分类号： C08F2/01 , B01J19/00 , C08G64/00
CPC分类号： B01J19/2415 , B01J19/245 , B01J2219/00159 , B01J2219/00162 , C08G64/205 , C08G64/305
摘要： The present invention provides a reactor system for producing polycarbonate. The reactor system has one or more reactant vessels, an oligomerization reactor, a first pressure control device, a preheater, a second pressure control device, a distributor, and a flash tank. The one or more reactant vessels contain reactants contain a melt transesterification catalyst, a dihydroxy compound, and an activated diaryl carbonate. The reactor system is connected in the following configuration: (i) the one or more reactant vessels connected to the oligomerization reactor, (ii) the first pressure control device disposed between and connecting the outlet of the oligomerization reactor and the inlet of the preheater; (iii) the second pressure control device disposed between and connecting the outlet of the preheater and the distributor; and (iv) the distributor disposed at the inlet to the flash tank. The pressure in the preheater is controllable at a pressure intermediate between the pressure in the oligomerization reactor and the flash tank.
摘要翻译：本发明提供了一种用于生产聚碳酸酯的反应器系统。反应器系统具有一个或多个反应物容器，低聚反应器，第一压力控制装置，预热器，第二压力控制装置，分配器和闪蒸罐。一个或多个反应物容器包含含有熔体酯交换催化剂，二羟基化合物和活化的碳酸二芳基酯的反应物。反应器系统以如下配置连接：（i）连接到低聚反应器的一个或多个反应容器，（ii）设置在低聚反应器的出口和预热器入口之间并连接低聚反应器的出口的第一压力控制装置; （iii）所述第二压力控制装置设置在所述预热器和所述分配器之间并连接所述预热器的出口; 和（iv）布置在闪蒸罐的入口处的分配器。预热器中的压力可以在低聚反应器和闪蒸罐中的压力之间的压力下控制。

7. 发明授权

US07166687B2 Translucent thermoplastic composition, method for making the composition and articles molded there from 有权
标题翻译：半透明热塑性组合物，制备组合物的方法和在其上成型的制品
公开(公告)号：US07166687B2
公开(公告)日：2007-01-23
申请号：US10783140
申请日：2004-02-20
申请人： Robert W. Venderbosch , Jan-Willem Goedmakers , Jeremy D. Hurst
发明人： Robert W. Venderbosch , Jan-Willem Goedmakers , Jeremy D. Hurst
IPC分类号： C08G64/00
CPC分类号： C08L83/10 , C08L25/12 , C08L55/02 , C08L67/02 , C08L69/00 , C08L2666/02
摘要： A thermoplastic composition comprising a matrix of a polycarbonate polymer in which are embedded polysiloxane domains with an average domain size between 20 and 45 nanometers. Said compositions can be obtained by combining a first polycarbonate/poly(diorganosiloxane) copolymer; with a second polycarbonate/poly(diorganosiloxane) copolymer. A range of translucencies are obtainable by varying the relative amounts of the two copolymers without substantial loss in impact properties.
摘要翻译：一种热塑性组合物，其包含聚碳酸酯聚合物的基质，其中嵌入的聚硅氧烷域的平均域尺寸为20至45纳米。所述组合物可以通过组合第一聚碳酸酯/聚（二有机硅氧烷）共聚物; 与第二聚碳酸酯/聚（二有机硅氧烷）共聚物。可以通过改变两种共聚物的相对量而不会在冲击性能方面实质上损失来获得一系列透明性。

8. 发明申请

US20070015081A1 Polycarbonate compositions having infrared absorbance, method of manufacture, and articles prepared therefrom 有权
标题翻译：具有红外吸光度，制造方法和由其制备的制品的聚碳酸酯组合物
公开(公告)号：US20070015081A1
公开(公告)日：2007-01-18
申请号：US11180746
申请日：2005-07-13
申请人： Jos van den Bogerd , Josephus Hubertus Dekkers , Rein Faber , Jan-Willem Goedmakers , Christianus Johannes Maas
发明人： Jos van den Bogerd , Josephus Hubertus Dekkers , Rein Faber , Jan-Willem Goedmakers , Christianus Johannes Maas
IPC分类号： G03C1/00
CPC分类号： C08K3/04 , A61F9/045 , C08K3/22 , C08K3/38 , Y10T428/25 , Y10T428/256 , Y10T428/269 , C08L69/00
摘要： A composition is disclosed, comprising a polycarbonate resin, an inorganic infrared shielding additive, and carbon black, wherein an article prepared from the composition has the inorganic infrared shielding additive present at about 0.01 to about 1.0 grams per square meter, and carbon black present at about 0.001 to about 2.0 grams per square meter. The article prepared from the composition meets at least one scale requirement for European Norm EN 169 and/or EN 171, and is useful for preparing infrared shielding protective eyewear with low haze.
摘要翻译：公开了一种组合物，其包含聚碳酸酯树脂，无机红外屏蔽添加剂和炭黑，其中由该组合物制备的制品具有约0.01至约1.0克/平方米的无机红外屏蔽添加剂，约0.001至约2.0克/平方米。由该组合物制备的制品满足欧洲标准EN 169和/或EN 171的至少一个规格要求，并且可用于制备低雾度的红外屏蔽防护眼镜。

9. 发明授权

US08900693B2 Polycarbonate compositions having infrared absorbance, method of manufacture, and articles prepared therefrom 有权
标题翻译：具有红外吸光度，制造方法和由其制备的制品的聚碳酸酯组合物
公开(公告)号：US08900693B2
公开(公告)日：2014-12-02
申请号：US11180746
申请日：2005-07-13
申请人： Jos A van den Bogerd , Josephus Hubertus Cornelius Maria Dekkers , Rein Mollerus Faber , Jan-Willem Goedmakers , Christianus Johannes Jacobus Maas
发明人： Jos A van den Bogerd , Josephus Hubertus Cornelius Maria Dekkers , Rein Mollerus Faber , Jan-Willem Goedmakers , Christianus Johannes Jacobus Maas
IPC分类号： B32B27/32 , B32B5/16 , B32B17/10
CPC分类号： C08K3/04 , A61F9/045 , C08K3/22 , C08K3/38 , Y10T428/25 , Y10T428/256 , Y10T428/269 , C08L69/00
摘要： A composition is disclosed, comprising a polycarbonate resin, an inorganic infrared shielding additive, and carbon black, wherein an article prepared from the composition has the inorganic infrared shielding additive present at about 0.01 to about 1.0 grams per square meter, and carbon black present at about 0.001 to about 2.0 grams per square meter. The article prepared from the composition meets at least one scale requirement for European Norm EN 169 and/or EN 171, and is useful for preparing infrared shielding protective eyewear with low haze.
摘要翻译：公开了一种组合物，其包含聚碳酸酯树脂，无机红外屏蔽添加剂和炭黑，其中由该组合物制备的制品具有约0.01至约1.0克/平方米的无机红外屏蔽添加剂，约0.001至约2.0克/平方米。由该组合物制备的制品满足欧洲标准EN 169和/或EN 171的至少一个规格要求，并且可用于制备低雾度的红外屏蔽防护眼镜。

10. 发明授权

US07141640B2 Process for producing dihydroxy compounds using upflow reactor system 有权
标题翻译：使用上流式反应器系统生产二羟基化合物的方法
公开(公告)号：US07141640B2
公开(公告)日：2006-11-28
申请号：US10065357
申请日：2002-10-08
申请人： Hatem Belfadhel , Corinne Duchanoy , Jan-Willem Goedmakers , Eduard Hendricus Schlarmann , Monique I. R. de Winne
发明人： Hatem Belfadhel , Corinne Duchanoy , Jan-Willem Goedmakers , Eduard Hendricus Schlarmann , Monique I. R. de Winne
IPC分类号： C08G64/00
CPC分类号： C07C39/16 , B01J8/0085 , B01J8/025 , B01J8/0278 , B01J8/0292 , B01J2208/00212 , B01J2208/00407 , B01J2208/00415 , B01J2208/00831 , B01J2208/00884 , B01J2219/0004 , B01J2219/1923 , B01J2219/1942 , B01J2219/1943 , C07C37/20 , Y02P20/582
摘要： An upflow reactor for the production of bisphenol A from acetone and phenol includes a vessel, a catalyst bed disposed within the vessel, and a reactant distribution/product collection system disposed within the vessel. The reactant distribution/product collection system includes a perforated distributor disposed at a lower end of the reactor. The reactant distribution/product collection system further includes a perforated collector disposed at an upper end of the reactor. A method for producing bisphenol A from acetone and phenol Includes Introducing the reacting mixture containing acetone and phenol to the distributor, directing it upward through the catalyst bed, and recovering the reacted acetone and phenol as bisphenol A together with other isomers and non reacted species. A method for avoiding catalyst bead carryover from the bed in an upflow reactor Includes receiving a product of the upflow reactor into the collector disposed at an upper end of the reactor through a screen with proper slit size.
摘要翻译：用于从丙酮和苯酚生产双酚A的向上流反应器包括容器，设置在容器内的催化剂床和设置在容器内的反应物分配/产物收集系统。反应物分配/产物收集系统包括布置在反应器下端的穿孔分布器。反应物分配/产物收集系统还包括设置在反应器上端的多孔收集器。从丙酮和苯酚生产双酚A的方法包括将含有丙酮和苯酚的反应混合物引入分配器，将其向上引导通过催化剂床，并且将其作为双酚A与其它异构体和未反应的物质一起回收反应的丙酮和苯酚。用于避免在上流式反应器中从床中催化剂珠粒携带的方法包括通过具有适当狭缝尺寸的筛网将上流反应器的产物接收到设置在反应器上端的收集器中。

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