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1. 发明授权

US09340486B2 Process for nitroalkane recovery by aqueous phase recycle to nitration reactor 有权
公开(公告)号：US09340486B2
公开(公告)日：2016-05-17
申请号：US13854491
申请日：2013-04-01
申请人： ANGUS Chemical Company
发明人： Mahesh Sawant , Daniel M. Trauth , John G. Pendergast, Jr.
IPC分类号： B01J19/00 , C07C201/08 , C07C201/16 , C07C201/06 , B01J10/00
CPC分类号： C07C201/06 , B01J10/00 , B01J19/00 , C07C201/08 , C07C201/16 , C07C205/02
摘要： Disclosed are a process and an apparatus for synthesizing nitroalkanes by reaction of a hydrocarbon feedstock with aqueous nitric acid. Energy and capital costs may be reduced by recycling a majority of the aqueous phase back to the reactor.

2. 发明授权

US09120721B2 Method of preparing chiral ketones from aldehydes 有权
标题翻译：从醛制备手性酮的方法
公开(公告)号：US09120721B2
公开(公告)日：2015-09-01
申请号：US14359847
申请日：2012-12-13
申请人： Nanyang Technological University
发明人： Yonggui Chi , Bhoopendra Tiwari
IPC分类号： C07C211/00 , C07C205/00 , C07C207/00 , C07C221/00 , C07C201/12 , C07C205/02 , C07C205/44 , C07B41/06 , C07C225/14 , C07C225/16
CPC分类号： C07C221/00 , C07B41/06 , C07C201/12 , C07C205/02 , C07C205/44 , C07C225/14 , C07C225/16
摘要： Present invention relates to a method of preparing a chiral α- or β-substituted ketone from the corresponding β- or γ-substituted aldehyde, wherein the ketone has formula (I), (III) or (V), and the corresponding aldehyde has formula (II), (IV) or (VI), respectively, the method comprising reacting the aldehyde of formula (II), (IV) or (VI) in the presence of an amine, oxygen and an organic solvent, wherein the reaction is carried out in the absence of a metal-based catalyst or a metal-based oxidant, wherein: R is H, a substituted or unsubstituted C1-C10 alkyl, substituted or unsubstituted C2-C15 alkenyl, substituted or unsubstituted C2-C15 alkynyl, substituted or unsubstituted C3-C15 cycloalkyl, substituted or unsubstituted C3-C15 cycloalkenyl, substituted or unsubstituted C3-C15 heterocycloalkyl, substituted or unsubstituted C3-C15 heterocycloalkenyl, substituted or unsubstituted C6-C15 aryl, or substituted or unsubstituted C6-C15 heteroaryl; and R′ is H, a substituted or unsubstituted C1-C10 alkyl, substituted or unsubstituted C2-C15 alkenyl, substituted or unsubstituted C2-C15 alkynyl, substituted or unsubstituted C3-C15 cycloalkyl, substituted or unsubstituted C3-C15 cycloalkenyl, substituted or unsubstituted C3-C15 heterocycloalkyl, substituted or unsubstituted C3-C15 heterocycloalkenyl, substituted or unsubstituted C6-C15 aryl, or substituted or unsubstituted C6-C15 heteroaryl.
摘要翻译：本发明涉及从相应的β-取代醛或γ-取代醛制备手性α-或β-取代的酮的方法，其中酮具有式（I），（III）或（V），和相应的醛分别具有式（II），（IV）或（VI），所述方法包括在胺，氧和有机溶剂的存在下使式（II），（IV）或（VI）的醛反应，其中该反应在不存在金属类催化剂或金属类氧化剂的情况下进行，其中：R为H，取代或未取代的C 1 -C 10烷基，取代或未取代的C 2 -C 15烯基，取代或未取代的C 2 -C 15 取代或未取代的C 3 -C 15环烯基，取代或未取代的C 3 -C 15环烯基，取代或未取代的C 3 -C 15杂环烷基，取代或未取代的C 3 -C 15杂环烯基，取代或未取代的C 6 -C 15芳基或取代或未取代的C 6 -C 15杂芳基 ; 取代或未取代的C 1 -C 15烷基，取代或未取代的C 2 -C 15烯基，取代或未取代的C 2 -C 15炔基，取代或未取代的C 3 -C 15环烷基，取代或未取代的C 3 -C 15环烯基，取代或未取代的 C 3 -C 15杂环烷基，取代或未取代的C 3 -C 15杂环烯基，取代或未取代的C 6 -C 15芳基或取代或未取代的C 6 -C 15杂芳基。

3. 发明授权

US08692036B2 Method for preparing 2,3-dimethyl-2,3-dinitrobutane 有权
标题翻译：制备2,3-二甲基-2,3-二硝基丁烷的方法
公开(公告)号：US08692036B2
公开(公告)日：2014-04-08
申请号：US13823831
申请日：2011-09-05
申请人： Shengjian Zhang , Yingxian Zhao , Hong Zhang
发明人： Shengjian Zhang , Yingxian Zhao , Hong Zhang
IPC分类号： C07C205/00
CPC分类号： C07C201/14 , C07C201/06 , C07C205/02
摘要： The present invention relates to a method for preparing 2,3-dimethyl-2,3-dinitrobutane (DMNB), which includes the following steps: (1) making titanium-silicate molecular sieve catalyst, acetone, hydrogen peroxide and ammonia contact and react at 65-80° C. to obtain a modified titanium-silicate molecular sieve catalyst; and (2-1) making acetone oxime and hydrogen peroxide contact and react in the presence of the modified titanium-silicate molecular sieve catalyst and water under the conditions of temperature of 60-90° C. and pH of 8-10, and separating DMNB from the reaction products thereof; or (2-2) making acetone, ammonia and hydrogen peroxide contact and react in the presence of the modified titanium-silicate molecular sieve catalyst and water under the conditions of temperature of 60-90° C. and pH of 8-10, and separating DMNB from the reaction products thereof. By the method provided by the present invention, DMNB can be prepared without having to use dangerous chemicals, such as 2-nitropropane, NaH and the like.
摘要翻译：本发明涉及一种制备2,3-二甲基-2,3-二硝基丁烷（DMNB）的方法，其包括以下步骤：（1）使钛硅酸盐分子筛催化剂，丙酮，过氧化氢和氨接触并反应在65-80℃下，得到改性钛酸酯分子筛催化剂; 和（2-1）使丙酮肟和过氧化氢接触并在改性的钛酸硅酸盐分子筛催化剂和水的存在下在60-90℃的温度和pH为8-10的条件下反应，并分离 DMNB反应产物; 或（2-2）使丙酮，氨和过氧化氢接触并在改性钛硅酸盐分子筛催化剂和水的存在下在60-90℃的温度和pH为8-10的条件下反应，和从其反应产物中分离DMNB。通过本发明提供的方法，可以制备DMNB，而不必使用危险化学品，例如2-硝基丙烷，NaH等。

4. 发明申请

US20140031594A1 Apparatus and Process for Nitration Selectivity Flexibility Enabled by Azeotropic Distillation 有权
标题翻译：通过共沸蒸馏使氮化反应灵敏度的设备和方法
公开(公告)号：US20140031594A1
公开(公告)日：2014-01-30
申请号：US14007531
申请日：2012-04-05
申请人： Mahesh Sawant , Daniel M. Trauth , John G. Pendergast
发明人： Mahesh Sawant , Daniel M. Trauth , John G. Pendergast
IPC分类号： C07C205/02
CPC分类号： C07C205/02 , C07C201/08 , C07C201/16
摘要： Disclosed are processes and apparatuses for concentrating at least one organic acid using an alkyl acetate as an entrainer. The processes and apparatuses may use the same alkyl acetate as an entrainer to concentrate a mixture of organic acids.
摘要翻译：公开了使用乙酸烷基酯作为夹带剂浓缩至少一种有机酸的方法和装置。方法和装置可以使用相同的乙酸烷基酯作为夹带剂来浓缩有机酸的混合物。

5. 发明申请

US20130343960A1 HYDROCARBON FEED FLEXIBLE HIGH PRESSURE NITRATION PLANT DESIGN 有权
标题翻译：石油进口灵活高压硝酸盐设计
公开(公告)号：US20130343960A1
公开(公告)日：2013-12-26
申请号：US13973142
申请日：2013-08-22
申请人： Mahesh Sawant , Daniel M. Trauth , John G. Pendergast , Ravindra S. Dixit
发明人： Mahesh Sawant , Daniel M. Trauth , John G. Pendergast , Ravindra S. Dixit
IPC分类号： B01D3/00
CPC分类号： B01D3/009 , B01J2219/00006 , C07C201/08 , C07C205/02 , C07C205/05
摘要： Disclosed is an apparatus for synthesizing nitroalkanes by reaction of a hydrocarbon feedstock with aqueous nitric acid. The apparatus may be designed such that it can synthesize more than one nitroalkane using the same equipment.
摘要翻译：公开了一种通过烃原料与硝酸水溶液反应合成硝基烷烃的装置。该设备可以被设计成使得可以使用相同的设备合成多于一个的硝基烷烃。

6. 发明授权

US08431754B2 Process for nitroalkane recovery by aqueous phase recycle to nitration reactor 有权
标题翻译：通过水相回收硝化烷烃回收到硝化反应器的方法
公开(公告)号：US08431754B2
公开(公告)日：2013-04-30
申请号：US12879824
申请日：2010-09-10
申请人： Mahesh Sawant , Daniel M. Trauth , John G. Pendergast, Jr.
发明人： Mahesh Sawant , Daniel M. Trauth , John G. Pendergast, Jr.
IPC分类号： C07C205/00
CPC分类号： C07C201/06 , B01J10/00 , B01J19/00 , C07C201/08 , C07C201/16 , C07C205/02
摘要： Disclosed are a process and an apparatus for synthesizing nitroalkanes by reaction of a hydrocarbon feedstock with aqueous nitric acid. Energy and capital costs may be reduced by recycling a majority of the aqueous phase back to the reactor.
摘要翻译：公开了通过烃原料与硝酸水溶液反应来合成硝基烷烃的方法和装置。通过将大部分水相回收到反应器中，可以减少能源和资本成本。

7. 发明授权

US06924309B2 Anti-inflammatory nitro and thia-fatty acids 失效
标题翻译：抗炎性硝基和硫脂肪酸
公开(公告)号：US06924309B2
公开(公告)日：2005-08-02
申请号：US10100490
申请日：2002-03-18
申请人： Antonio Ferrante , Christopher J. Easton , Ling Xia
发明人： Antonio Ferrante , Christopher J. Easton , Ling Xia
IPC分类号： A61K8/30 , A61K8/36 , A61K8/40 , A61K8/46 , A61K31/04 , A61K31/10 , A61K31/19 , A61K31/20 , A61K31/202 , A61K31/21 , A61K31/335 , A61P1/04 , A61P1/18 , A61P3/10 , A61P9/00 , A61P9/10 , A61P11/00 , A61P11/02 , A61P11/06 , A61P17/00 , A61P17/06 , A61P25/00 , A61P29/00 , A61P31/00 , A61P33/06 , A61P35/00 , A61P37/02 , A61P37/06 , A61P37/08 , A61P39/06 , A61P43/00 , C07C17/16 , C07C45/30 , C07C205/02 , C07C205/03 , C07C205/14 , C07C205/15 , C07C205/50 , C07C205/51 , C07C317/44 , C07C321/14 , C07C321/18 , C07C323/52 , C07C409/40 , A01N37/00 , C07C229/00 , C07C207/00 , C07C205/00
CPC分类号： C07C409/40 , A61K31/19 , A61K31/20 , A61K31/202 , A61K31/21 , A61K31/335 , A61K45/06 , C07C17/16 , C07C45/30 , C07C205/02 , C07C205/03 , C07C205/14 , C07C205/15 , C07C205/50 , C07C205/51 , C07C317/44 , C07C323/52 , Y02A50/411 , C07C19/075 , C07C21/14 , C07C47/02 , C07C47/21 , A61K2300/00
摘要： The present invention relates to compounds of the general formula: NO2-A-B wherein A is a saturated or unsaturated hydrocarbon chain of 14-26 carbon atoms and B is (CH2)n(COOH)m in which n is an integer from 0 to 2 and m is an integer from 0 to 2; or of general formula (I), wherein A′ is a saturated or unsaturated hydrocarbon chain of 9-26 carbon atoms, X is oxygen or is absent and B′ is (CH2)j(COOH)k in which j is an integer from 1 to 3 and k is 0 or 1; and the derivatives thereof in which the hydrocarbon chain includes one or more than one substitution selected from the group consisting of hydroxy, hydroperoxy, epoxy and peroxy. These compounds have biological activity, e.g. as anti-infective or anti-inflammatory agents.
摘要翻译：本发明涉及以下通式的化合物：其中A是14-26个碳原子的饱和或不饱和烃链，B是（CH 2 CH 2））其中n为0〜2的整数，m为0〜2的整数，n为0〜2的整数。或通式（I），其中A'是9-26个碳原子的饱和或不饱和烃链，X是氧或不存在，B'是（CH 2 CH 2）其中，j为1〜3的整数，k为0或1的化合物（COOH）k < 及其衍生物，其中烃链包括一个或多于一个选自羟基，氢过氧基，环氧基和过氧基的取代基。这些化合物具有生物活性，例如作为抗感染或抗炎剂。

8. 发明申请

US20040256743A1 Method for producing organic compound by substituting halogen atoms 审中-公开
标题翻译：用卤素原子取代有机化合物的方法
公开(公告)号：US20040256743A1
公开(公告)日：2004-12-23
申请号：US10864533
申请日：2004-06-10
申请人： Mitsui Chemicals, Inc.
发明人： Setsuko Funaki , Yoshiteru Taniguchi , Tadahito Nobori , Yoshihiro Yamamoto , Isao Hara , Takaomi Hayashi , Kazumi Mizutani , Shinji Kiyono
IPC分类号： C07F005/00 , C07F001/02
CPC分类号： C07D307/33 , C07B37/04 , C07B41/00 , C07B43/00 , C07C17/208 , C07C29/124 , C07C67/10 , C07C67/11 , C07C67/287 , C07C201/10 , C07C209/08 , C07C253/14 , C07C253/30 , C07C319/14 , C07C331/14 , C07C2601/08 , C07C2601/14 , C07C2603/18 , C07D307/14 , C07D307/24 , C07C23/08 , C07C69/003 , C07C323/22 , C07C205/02 , C07C323/56 , C07C255/46 , C07C255/41 , C07C255/20 , C07C255/19 , C07C255/16 , C07C255/03 , C07C211/42 , C07C69/145 , C07C69/24 , C07C69/63 , C07C33/24
摘要： A method for producing an organic compound having Q, the method including a step of reacting a compound represented by general formula (2) with an organic starting material having at least one halogen atom bonded to a carbon atom having four null bonds so as to replace the halogen atom in the organic starting material with Q: MQanullnull(2) wherein M, Q and a are defined in the presence of a compound represented by general formula (1) 1 wherein Znull and Rs are also defined.
摘要翻译：一种制备具有Q的有机化合物的方法，该方法包括使通式（2）表示的化合物与具有至少一个卤素原子键合的有机原料与具有四个σ键的碳原子反应的步骤，以便代替在通式（1）表示的化合物的存在下，定义其中M，Q和a的Q：MQa（2）中的卤素原子，其中Z'和R 5也被定义。

9. 发明申请

US20030092762A1 Anti-inflammatory nitro and thia-fatty acids 失效
标题翻译：抗炎性硝基和硫脂肪酸
公开(公告)号：US20030092762A1
公开(公告)日：2003-05-15
申请号：US10100490
申请日：2002-03-18
发明人： Antonio Ferrante , Christopher J. Easton , Ling Xia
IPC分类号： A61K031/337 , C07D33/38 , C07C25/39 , A61K031/195
CPC分类号： C07C409/40 , A61K31/19 , A61K31/20 , A61K31/202 , A61K31/21 , A61K31/335 , A61K45/06 , C07C17/16 , C07C45/30 , C07C205/02 , C07C205/03 , C07C205/14 , C07C205/15 , C07C205/50 , C07C205/51 , C07C317/44 , C07C323/52 , Y02A50/411 , C07C19/075 , C07C21/14 , C07C47/02 , C07C47/21 , A61K2300/00
摘要： The present invention relates to compounds of the general formula: NO2-A-B wherein A is a saturated or unsaturated hydrocarbon chain of 14-26 carbon atoms and B is (CH2)n(COOH)m in which n is an integer from 0 to 2 and m is an integer from 0 to 2; or of general formula (I), wherein Anull is a saturated or unsaturated hydrocarbon chain of 9-26 carbon atoms, X is oxygen or is absent and Bnull is (CH2)j(COOH)k in which j is an integer from 1 to 3 and k is 0 or 1; and the derivatives thereof in which the hydrocarbon chain includes one or more than one substitution selected from the group consisting of hydroxy, hydroperoxy, epoxy and peroxy. These compounds have biological activity, e.g. as anti-infective or anti-inflammatory agents.
摘要翻译：本发明涉及通式为：NO2-AB的化合物，其中A是14-26个碳原子的饱和或不饱和烃链，B是（CH2）n（COOH）m，其中n是0-2的整数 m为0〜2的整数。或通式（I），其中A'是9-26个碳原子的饱和或不饱和烃链，X是氧或不存在，B'是（CH 2）j（COOH）k，其中j是 1〜3，k为0或1; 及其衍生物，其中烃链包括一个或多于一个选自羟基，氢过氧基，环氧基和过氧基的取代基。这些化合物具有生物活性，例如作为抗感染或抗炎剂。

10. 发明授权

US3869253A Apparatus for producing nitroparaffins 失效
标题翻译：硝基石油生产装置
公开(公告)号：US3869253A
公开(公告)日：1975-03-04
申请号：US38450873
申请日：1973-08-01
申请人： AZOTE & PROD CHIM
发明人： LHONORE PIERRE , COHEN GUY , JACQUINOT BERNARD
IPC分类号： B01J12/00 , C07C201/14 , C07C205/02 , C07C79/02 , B01J1/00
CPC分类号： C07C201/06 , B01J12/00 , Y02P20/582 , C07C205/02
摘要： The invention relates to an process for the production of nitroparaffins from hydrocarbons higher than methane, by nitration with nitrogen peroxide in the presence of oxygen, introduced in the form of air, wherein the nitration is carried out at a pressure which is between 8 and approximately 14 bars, the reactant gases being preheated under the reaction pressure and introduced into the reaction zone between 150* and 330*C, the gaseous effluents originating from the nitration zone being subjected to a rapid cooling or quenching.
摘要翻译：本发明涉及一种从高于甲烷的烃生产硝基烷烃的方法，通过在氧气存在下用氮气进行硝化，以空气的形式引入，其中硝化在8至大约的压力下进行 14巴，反应物气体在反应压力下预热，并引入150至330℃的反应区，来自硝化区的气态流出物经受快速冷却或骤冷。

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