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    • 10. 发明授权
    • High speed electroplating metallic conductors
    • 高速电镀金属导体
    • US09530653B2
    • 2016-12-27
    • US15002342
    • 2016-01-20
    • Uri Cohen
    • Uri Cohen
    • C25D5/08H01L21/77H01L21/288C25D5/02H01L21/768H05K3/42C25D7/12C25D21/10H01L23/522H05K3/06H05K3/10H01L23/48H01L21/321H01L23/532
    • C25D5/026C25D5/022C25D5/028C25D5/08C25D7/123C25D21/10H01L21/2885H01L21/3212H01L21/7684H01L21/76843H01L21/76873H01L21/76877H01L21/76879H01L21/7688H01L23/481H01L23/5226H01L23/53238H01L2924/0002H05K3/06H05K3/107H05K3/423H01L2924/00
    • One embodiment is a method for producing void-free electroplated metallic conductors inside openings by electrochemical deposition (ECD), said method including steps of: forming at least one opening in a substrate, said at least one opening having an aspect ratio in a range from 8:1 to 28:1; forming at least one barrier layer over the sidewalls of the at least one opening; depositing at least one seed layer over the at least one barrier layer; immersing the substrate in an electrolyte contained in an ECD cell, the ECD cell including at least one anode and a cathode, wherein the electrolyte includes plating metallic ions and at least one inhibitor additive; providing agitation of the electrolyte across the surface of the substrate by moving multiple non-contacting wiping blades relative to the substrate, wherein the agitation facilitates a limiting current density larger by at least an order of magnitude than a limiting current density without the agitation; and applying an average electroplating current density on the substrate, wherein the agitation, the concentrations of the metallic ions and the inhibitor additive, and the average electroplating current density are such as to produce void-free, electroplated metallic filling inside the at least one opening.
    • 一个实施方案是一种通过电化学沉积(ECD)在开口内产生无空隙的电镀金属导体的方法,所述方法包括以下步骤:在基底中形成至少一个开口,所述至少一个开口的纵横比范围从 8:1到28:1; 在所述至少一个开口的侧壁上形成至少一个阻挡层; 在所述至少一个阻挡层上沉积至少一个种子层; 将所述衬底浸入包含在ECD电池中的电解质中,所述ECD电池包括至少一个阳极和阴极,其中所述电解质包括电镀金属离子和至少一种抑制剂添加剂; 通过相对于基底移动多个非接触式擦拭刮板来提供电解质跨过衬底的表面的搅动,其中搅拌有助于极限电流密度比不受搅拌的极限电流密度大至少一个数量级; 以及在所述衬底上施加平均电镀电流密度,其中所述搅拌,所述金属离子和所述抑制剂添加剂的浓度以及所述平均电镀电流密度在所述至少一个开口内部产生无空隙的电镀金属填充物 。