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1. 发明授权

US08962879B2 Perfluoropolyvinyl modified aryl intermediates/monomers 有权
标题翻译：全氟聚乙烯基改性芳基中间体/单体
公开(公告)号：US08962879B2
公开(公告)日：2015-02-24
申请号：US14068603
申请日：2013-10-31
申请人： E I Du Pont De Nemours and Company
发明人： Neville Everton Drysdale
IPC分类号： C07C69/62 , C07C69/653
CPC分类号： C07C69/653
摘要： A compound of formula (I) wherein Rf is —CF3, —C2F5, —CF2CFXCF3; X to —F, or —OC3F7; Y is —H, —Cl, or —Br; R is —O—C(O)—R1, —(CH2)nO—C(O)—R1, —(OCH2CH2)mOC(O)—R1; —(CH2)n(OCH2CH2)mO—R1; n is 1 to 10; m is 1 to 10; R1 is —C(R3)═CH2; R3 is H or CH3; a is 1 to 5; and b is 1 to 5.
摘要翻译：式（I）的化合物，其中R f为-CF 3，-C 2 F 5，-CF 2 CFXCF 3; X至-F或-OC 3 F 7; Y是-H，-Cl或-Br; R是-O-C（O）-R1， - （CH2）nO-C（O）-R1， - （OCH2CH2）mOC（O）-R1; - （CH 2）n（OCH 2 CH 2）m O-R 1; n为1〜10; m为1〜10; R 1是-C（R 3）= CH 2; R3是H或CH3; a是1到5; b为1〜5。

2. 发明授权

US07297811B2 Precursors to fluoroalkanol-containing olefin monomers and associated methods of synthesis and use 有权
标题翻译：含氟链烷醇的烯烃单体的前体和相关的合成和使用方法
公开(公告)号：US07297811B2
公开(公告)日：2007-11-20
申请号：US10729453
申请日：2003-12-04
申请人： Gregory Breyta , Richard Anthony DiPietro , Daniel Joseph Dawson
发明人： Gregory Breyta , Richard Anthony DiPietro , Daniel Joseph Dawson
IPC分类号： C07C69/13 , C07C69/62 , C07C69/65 , C07C69/003
CPC分类号： C07C69/653 , C07C31/42 , C07C35/48 , C07C35/52 , C07C69/65 , C07C2601/04 , C07C2601/08 , C07C2602/42
摘要： The invention provides alkene fluoroalkanol and fluorinated polyol precursors to fluoroalkanol-substituted α,β-unsaturated esters. The fluoroalkanol-substituted α,β-unsaturated esters are olefins that can be readily polymerized to provide fluoroalkanol-substituted polymers useful in lithographic photoresist compositions. Also provided are methods for synthesizing the alkene fluoroalkanol and fluorinated polyol precursors.
摘要翻译：本发明提供氟链烷醇取代的α，β-不饱和酯的烯烃氟烷醇和氟化多元醇前体。氟烷醇取代的α，β-不饱和酯是可以容易地聚合以提供用于平版印刷光刻胶组合物的氟代烷醇取代的聚合物的烯烃。还提供了用于合成烯烃氟烷醇和氟化多元醇前体的方法。

3. 发明申请

US20070265423A1 Bifunctional phenylene ether oligomer, its derivatives, its use and process for the production thereof 有权
标题翻译：双官能亚苯基醚低聚物，其衍生物，其用途及其制备方法
公开(公告)号：US20070265423A1
公开(公告)日：2007-11-15
申请号：US11812892
申请日：2007-06-22
申请人： Akikazu Amagai , Kenzi Ishii , Kiyonari Hiramatsu , Makoto Miyamoto , Daisuke Ohno , Katsutoshi Yamazaki , Yasumasa Norisue
发明人： Akikazu Amagai , Kenzi Ishii , Kiyonari Hiramatsu , Makoto Miyamoto , Daisuke Ohno , Katsutoshi Yamazaki , Yasumasa Norisue
IPC分类号： C08G63/66 , C07C69/52 , C07C69/62
CPC分类号： C08G59/063 , C08G65/44 , C08G65/485 , C08G2650/20 , C08L2312/00 , H05K1/0326 , Y10T428/24994 , Y10T428/31511
摘要： A bifunctional phenylene ether oligomer of the formula (1), obtained by oxidation polymerization of a bivalent phenol of the formula (2) and a monovalent phenol of the formula (3), wherein —X— is represented by the formula (2′), and Y—O— is represented by the formula (3), R2, R3, R4, R8, R9, R10 and R11 in the formula (2′) and the formula (3′) being required not to be a hydrogen atom, and its use.
摘要翻译：通过式（2）的二价苯酚和式（3）的一价苯酚的氧化聚合获得的式（1）的双功能亚苯基醚低聚物，其中-X-由式（2'）表示，，YO-由式（3）表示，式（2'）和式（3'）中的R2，R3，R4，R8，R9，R10和R11不为氢原子，其使用。

4. 发明申请

US20050171375A1 Process for producing acrylic ester compound 有权
标题翻译：制备丙烯酸酯化合物的方法
公开(公告)号：US20050171375A1
公开(公告)日：2005-08-04
申请号：US10995334
申请日：2004-11-24
申请人： Satoru Miyazawa , Yusuke Kuramoto , Satoru Kobayashi , Kazuhiko Maeda
发明人： Satoru Miyazawa , Yusuke Kuramoto , Satoru Kobayashi , Kazuhiko Maeda
IPC分类号： C07C67/14 , C07C69/653 , C07C69/62
CPC分类号： C07C67/14 , C07C69/653
摘要： A process for producing an acrylic ester compound includes reacting in the presence of alkene an alcohol represented by the formula (1), wherein R1 represents a hydrogen atom, a fluorine atom, a straight-chain or branched hydrocarbon group, a fluorine-containing alkyl group, or an aromatic or aliphatic ring and optionally contains oxygen, sulfur or a carbonyl bond, with an acid halide represented by the formula (2), wherein R2 represents a hydrogen atom, a halogen atom, a hydrocarbon group, or a fluorine-containing alkyl group, and X represents a halogen atom.
摘要翻译：丙烯酸酯化合物的制造方法包括在烯烃存在下使式（1）表示的醇反应，其中R 1表示氢原子，氟原子，直链或支链烃基，含氟烷基或芳族或脂族环，并且任选地含有氧，硫或羰基键，与式（2）表示的酰基卤，其中R 2表示氢原子，卤素原子，烃基或含氟烷基，X表示卤素原子。

5. 发明授权

US5380462A Cyclohexyl alkenoate compounds 失效
标题翻译：环烯基烯酸酯化合物
公开(公告)号：US5380462A
公开(公告)日：1995-01-10
申请号：US140350
申请日：1993-10-20
申请人： Stephen Kelly , Martin Schadt
发明人： Stephen Kelly , Martin Schadt
IPC分类号： C07C69/52 , C07C69/013 , C07C69/527 , C07C69/533 , C07C69/62 , C07C69/63 , C07C69/75 , C07C69/753 , C07C69/757 , C07C69/76 , C07C69/773 , C07C69/86 , C07C69/92 , C07C255/46 , C07C255/54 , C07C255/55 , C07C255/57 , C07D213/30 , C07D239/26 , C07D319/06 , C09K19/20 , C09K19/30 , C09K19/34 , G02F1/13 , C07D213/28
CPC分类号： C07D213/30 , C07C69/013 , C07C69/533 , C07D239/26 , C09K19/3003 , C09K19/3028 , C09K19/3068 , C09K19/3441
摘要： Compounds having the Formula: ##STR1## wherein R.sup.1 denotes an alkenyl group;A.sup.1 and A.sup.2 each independently represent 1,4-phenylene, which is unsubstituted or substituted with halogen and in which, when it is unsubstituted, optionally 1 or 2 CH group(s) is/are replaced by nitrogen, or trans-1,4-cyclohexylene or trans-1,3-dioxane-2,5-diyl;Z.sup.1 and Z.sup.2 each independently signify a single covalent bond, --CH.sub.2 CH.sub.2 --, --COO--, --OOC--, --OCH.sub.2 --, --CH.sub.2 O--, --C.dbd.C--, --(CH.sub.2).sub.4 --, --O(CH.sub.2).sub.3 --, --(CH.sub.2).sub.3 O-- or the trans form of --OCH.sub.2 CH.dbd.CH--, --CH.dbd.CHCH.sub.2 O--, --(CH.sub.2).sub.2 CH.dbd.CH-- or --CH.dbd.CH(CH.sub.2).sub.2 --;n is either 0, 1 or 2; andR.sup.2 is halogen, cyano or alkyl with 1 to 12 carbon atoms, which is optionally substituted with fluorine and in which optionally 1 --CH.sub.2 -- group or 2 non-adjacent --CH.sub.2 -- groups is/are replaced by oxygen, --COO--, --OOC--, --CO-- and/or a --CH.sub.2 --CH.sub.2 -- group is replaced by --CH.dbd.CH--,are useful in electro-optical applications. Liquid crystalline mixtures containing such compounds are especially suitable for use in commercial applications, such as electro-optic cells.
摘要翻译：具有下式的化合物：其中R 1表示烯基; A1和A2各自独立地表示1,4-亚苯基，其未被取代或被卤素取代，并且其中当未被取代时，任选地1或2个CH基团被氮取代，或反式-1,4 环己基或反式-1,3-二恶烷-2,5-二基; Z 1和Z 2各自独立地表示单个共价键，-CH 2 CH 2 - ， - COO - ， - OOC-， - OCH 2 - ， - CH 2 O - ， - C≡C - ， - （CH 2）4 - ， - O - （CH 2）3 O-或-OCH 2 CH = CH-，-CH = CHCH 2 O - ， - （CH 2）2 CH = CH-或-CH = CH（CH 2）2 - 的反式; n是0，1或2; 并且R 2是卤素，氰基或具有1至12个碳原子的烷基，其任选被氟取代，并且其中任选地1个-CH 2 - 基团或2个不相邻的-CH 2 - 基团被氧，-COO-， -OOC-，-CO-和/或-CH 2 -CH 2 - 基团被-CH = CH-取代，可用于电光学应用。含有这些化合物的液晶混合物尤其适用于商业应用，如电光电池。

6. 发明授权

US4324903A Malonic esters 失效
标题翻译：丙二酸酯
公开(公告)号：US4324903A
公开(公告)日：1982-04-13
申请号：US698063
申请日：1976-06-21
申请人： Magda Huhn , Eva Somfai , Gabor Szabo , Gabor Resovszki , Livia Gneth nee Zalantai
发明人： Magda Huhn , Eva Somfai , Gabor Szabo , Gabor Resovszki , Livia Gneth nee Zalantai
IPC分类号： C07C69/017 , C07C67/00 , C07C69/38 , C07C69/62 , C07D213/55 , C07D307/54 , C07D333/24 , C07C69/76 , C07C79/46 , C07C101/447
CPC分类号： C07D307/54 , C07C69/38
摘要： A process for the preparation of new malonic esters of the formula: ##STR1## wherein R is a substituted or unsubstituted C.sub.1 to C.sub.6 alkyl, a substituted or unsubstituted aromatic ring, a heterocyclic ring, a cycloalkyl group, or a fused ring system; R.sup.1 is hydrogen, lower alkyl, aralkyl, aralkyl substituted by halogen or alkyl or a substituted aromatic, cycloaliphatic or heterocyclic ring; and X is halogen.
摘要翻译：一种制备下式的新型丙二酸酯的方法：其中R为取代或未取代的C1至C6烷基，取代或未取代的芳环，杂环，环烷基或稠环体系; R 1为氢，低级烷基，芳烷基，被卤素或烷基或取代的芳族，脂环族或杂环取代的芳烷基; X为卤素。

7. 发明授权

US4309439A Substituted-acetic acid ester 失效
标题翻译：取代的乙酸酯
公开(公告)号：US4309439A
公开(公告)日：1982-01-05
申请号：US882155
申请日：1978-02-28
申请人： Nobuo Ohno , Isao Ohno , Toshio Nishioka , Hisami Takeda , Kiyoshi Kasamatsu
发明人： Nobuo Ohno , Isao Ohno , Toshio Nishioka , Hisami Takeda , Kiyoshi Kasamatsu
IPC分类号： C07C69/612 , A01N37/00 , A01N37/10 , A01N37/38 , A01N37/42 , A01N37/48 , A01N43/06 , A01N43/08 , A01N43/12 , A01N43/30 , A01N43/32 , A01N43/90 , C07C51/00 , C07C59/46 , C07C59/48 , C07C67/00 , C07C69/62 , C07C69/73 , C07C69/76 , C07C69/767 , C07C69/95 , C07C201/00 , C07C205/56 , C07C253/00 , C07C255/50 , C07C255/57 , C07C313/00 , C07C323/62 , C07D307/00 , C07D307/40 , C07D307/54 , C07D307/79 , C07D307/80 , C07D317/60 , C07D333/24 , C07D333/28 , C07D333/60 , C07D333/78 , C08K5/34 , A61K31/235 , A61K31/60 , C07C69/614 , C07D323/02
CPC分类号： C07D307/79 , C07C205/56 , C07C323/00 , C07C67/14 , C07C69/65 , C07D307/54 , C07D317/60 , C07D333/24 , C07D333/28 , C07D333/60
摘要： A novel substituted-arylacetic acid ester of the formula, ##STR1## wherein R.sub.1 and R.sub.2 are each hydrogen or a halogen atom, a C.sub.1 -C.sub.4 alkyl, C.sub.2 -C.sub.4 alkenyl, C.sub.1 -C.sub.4 alkoxy, cyano, nitro, methylthio, C.sub.1 -C.sub.4 alkanoyl, C.sub.1 -C.sub.4 alkanoyloxy, or C.sub.1 -C.sub.4 alkoxycarbonyl group, or R.sub.1 and R.sub.2, taken together, may form methylenedioxy, a C.sub.3 -C.sub.5 alkylene or butadienylene (--CH.dbd.CH--CH.dbd.CH--) ring; R.sub.3 is a C.sub.2 -C.sub.4 alkyl, C.sub.2 -C.sub.4 alkenyl, propargyl, C.sub.3 -C.sub.6 cycloalkyl or cyclopropylmethyl group; R.sub.4 is hydrogen or a halogen atom, methyl or ethyl group; R.sub.5 is allyl, propargyl, 3-butenyl, 3-butynyl, phenyl or benzyl group; and A is oxygen or sulfur atom or --CH.dbd.CH-- group, which possesses various useful insecticidal and acaricidal activities and can be prepared by reacting a substituted-arylacetic acid of the formula: ##STR2## wherein R.sub.1, R.sub.2, R.sub.3 and A are each as defined above, or a reactive derivative thereof with an alcohol, or halide or sulfonate thereof of the formula, ##STR3## wherein R.sub.4 and R.sub.5 are each as defined above and X is hydroxy group, a halogen atom, alkylsulfonyloxy or arylsulfonyloxy group.
摘要翻译：一种新颖的下式的取代芳基乙酸酯，其中R 1和R 2各自为氢或卤原子，C 1 -C 4烷基，C 2 -C 4烯基，C 1 -C 4烷氧基，氰基，硝基，甲硫基，C 1 -C 4烷酰基，C 1 -C 4烷酰氧基或C 1 -C 4烷氧基羰基，或者R 1和R 2一起可以形成亚甲二氧基，C 3 -C 5亚烷基或亚丁二烯基（-CH = CH-CH = CH-）环; R3是C2-C4烷基，C2-C4烯基，炔丙基，C3-C6环烷基或环丙基甲基; R4是氢或卤素原子，甲基或乙基; R5是烯丙基，炔丙基，3-丁烯基，3-丁炔基，苯基或苄基; 并且A是氧或硫原子或-CH = CH-基团，其具有各种有用的杀虫和杀螨活性，并且可以通过使下式的取代芳基乙酸反应来制备：其中R1，R2，R3和A是或其与醇或其卤化物或磺酸盐的反应性衍生物，其分子式如下：其中R 4和R 5各自如上所定义，X为羟基，卤素原子，烷基磺酰氧基或芳基磺酰氧基。

8. 发明授权

US4259350A Iodopropargyl derivatives, their use and preparation 失效
标题翻译：碘代炔丙基衍生物，其用途和制备方法
公开(公告)号：US4259350A
公开(公告)日：1981-03-31
申请号：US20165
申请日：1979-03-13
申请人： Yasuhiro Morisawa , Kiyoshi Konishi , Mitsuru Kataoka
发明人： Yasuhiro Morisawa , Kiyoshi Konishi , Mitsuru Kataoka
IPC分类号： A01N37/00 , A01N37/02 , A01N37/06 , A01N37/08 , A01N37/10 , A01N37/34 , A01N37/40 , A01N37/48 , A01N39/02 , A01N41/04 , A01N43/00 , A01N43/06 , A01N43/40 , A01N47/06 , A01N53/00 , A01N57/00 , A61K31/195 , B27K3/34 , C07C69/007 , C07C69/612 , C07C69/614 , C07C69/62 , C07C69/63 , C07C69/96 , C07C205/18 , C07C255/13 , C07C309/63 , C07C309/65 , C07C309/73 , C07C309/75 , C07D213/55 , C07D213/65 , C07D213/79 , C07D307/16 , C07D307/68 , C07D333/16 , C07D333/24 , C07D333/38 , A01N43/02
CPC分类号： C07D213/79 , A01N37/02 , A01N37/06 , A01N37/08 , A01N37/10 , A01N39/02 , A01N41/04 , A01N43/06 , A01N43/40 , A01N47/06 , A01N53/00 , C07C255/00 , C07C309/65 , C07C309/73 , C07C309/75 , C07C69/63 , C07C69/76 , C07C69/78 , C07C69/96 , C07D213/55 , C07D213/65 , C07D307/16 , C07D307/68 , C07D333/16 , C07D333/24 , C07D333/38
摘要： Iodopropargyl derivatives of formula:IC.tbd.CCH.sub.2 OR[wherein R represents an alkanoyl group (which may be unsubstituted or have one or more halogen, cyano, substituted or unsubstituted .alpha.-phenoxy or phenyl substituents) an alkenoyl group (optionally phenyl-substituted), a substituted or unsubstitutd alkoxycarbonyl group, a cycloalkanoyl group, a substituted or unsubstituted benzoyl group, a substituted or unsubstituted phenoxycarbonyl group, a substituted or unsubstituted benzyloxycarbonyl group, a heterocyclic carbonyl group, an alkylsulphonyl group, a substituted or unsubstituted benzenesulphonyl group, a naphthyloxycarbonyl group, an iodopropargyloxycarbonyl group, a substituted or unsubstituted cycloalkoxycarbonyl group, a heterocyclic methoxycarbonyl group, a 3-pyridyloxycarbonyl group (which may be unsubstituted or have one or more halogen substituents) or an alkenyloxycarbonyl group] are, except where R represents an acetyl or an unsubstituted benzoyl group, new compounds and are useful for the preservation of a variety or organic materials, including the protection of these materials against fungal or insect attack. The derivatives may be prepared by reacting 3-hydroxy-1-iodo-1-propyne with a compound of formula RX (in which R is as defined above and X represents a halogen atom) or, where R in the desired compound contains an oxycarbonyl group, reacting the 3-hydroxy-1-iodo-1-propyne with phosgene and then reacting the product with an appropriate hydroxy-containing compound.
摘要翻译：其中R表示烷酰基（其可以是未取代的或具有一个或多个卤素，氰基，取代或未取代的α-苯氧基或苯基取代基）烯酰基（任选被苯基取代的），一个取代或未取代的烷氧基羰基，环烷酰基，取代或未取代的苯甲酰基，取代或未取代的苯氧基羰基，取代或未取代的苄氧基羰基，杂环羰基，烷基磺酰基，取代或未取代的苯磺酰基，萘氧基羰基，碘代炔丙氧基羰基，取代或未取代的环烷氧基羰基，杂环甲氧基羰基，3-吡啶氧基羰基（其可以是未取代的或具有一个或多个卤素取代基）或烯氧基羰基]，其中R表示乙酰基或未取代的苯甲酰基，新化合物并且可用于保存各种或有机材料，包括保护这些材料免受真菌或昆虫的攻击。衍生物可以通过使3-羟基-1-碘-1-丙炔与式RX化合物（其中R如上定义并且X表示卤素原子）反应制备，或其中所需化合物中的R含有氧羰基将3-羟基-1-碘-1-丙炔与光气反应，然后使产物与合适的含羟基化合物反应。

9. 发明授权

US4138359A Liquid crystal composition and method for making same 失效
标题翻译：液晶组合物及其制造方法
公开(公告)号：US4138359A
公开(公告)日：1979-02-06
申请号：US771991
申请日：1977-02-25
申请人： Yutaka Mizukuchi
发明人： Yutaka Mizukuchi
IPC分类号： C07C67/00 , C07C69/76 , C07C69/773 , C07C201/00 , C07C205/57 , C07C253/00 , C07C255/57 , C09K19/20 , G02F1/13 , C09K3/34 , C07C69/62 , C07C69/78 , C07C79/46
CPC分类号： C09K19/2007 , C07C205/57
摘要： A new and novel liquid crystal composition having broad temperature and chemical stability is disclosed. The liquid crystal composition comprises a compound having the general formula: ##STR1## wherein R represents an alkyl or alkoxyl group and X represents an alkyl, alkoxyl, nitro or cyano group. The method for making the liquid crystal compound includes the methylation of 4-phenyl-2-chlorophenol and like compounds.
摘要翻译：公开了具有宽温度和化学稳定性的新颖且新颖的液晶组合物。液晶组合物包含具有以下通式的化合物：其中R表示烷基或烷氧基，X表示烷基，烷氧基，硝基或氰基。制备液晶化合物的方法包括4-苯基-2-氯苯酚等化合物的甲基化。

10. 发明授权

US4092337A Bromine substituted carboxylic acid esters 失效
标题翻译：溴取代羧酸酯
公开(公告)号：US4092337A
公开(公告)日：1978-05-30
申请号：US701457
申请日：1976-06-30
申请人： Horst Jager , Peter Rohringer
发明人： Horst Jager , Peter Rohringer
IPC分类号： C07C69/62 , C07C31/36 , C07C69/66 , D06M13/236 , C09F7/00 , C11C3/00
CPC分类号： C07C31/36 , C07C67/08 , C07C67/14 , C07C67/287 , C07C69/63 , C07C69/65 , D06M13/236
摘要： New bromine compounds are provided. They correspond to the formulaH -- X' -- COO -- (X--OOC).sub.t-1 -- X" -- Hin which t is 1 or 2 and X, X' and X" are brominated alkylene. The new compounds are useful as flameproofing agents for synthetic fibers.
摘要翻译：提供新的溴化合物。它们对应于其中t为1或2且X，X'和X“为溴化亚烷基的式H-X'-COO-（X-OOC）t-1-X”-H。新化合物可用作合成纤维的防火剂。

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