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    • 21. 发明申请
    • THERMALLY-CONDUCTIVE ORGANIC ADDITIVE, RESIN COMPOSITION, AND CURED PRODUCT
    • 导热有机添加剂,树脂组合物和固化产品
    • US20120175549A1
    • 2012-07-12
    • US13395914
    • 2010-04-26
    • Shusuke YoshiharaKazuaki Matsumoto
    • Shusuke YoshiharaKazuaki Matsumoto
    • C09K5/00C07C69/78C07C291/08C07C69/353
    • C08L67/02C09K5/14C09K19/3804F28F21/06
    • The present invention provides a thermally-conductive organic additive which (i) is an organic polymer, unlike a thermally-conductive inorganic filler such as ceramic, metal and a carbon material, (ii) is capable of imparting thermal conductivity to plastic by being added thereto, (iii) can reduce the weight of a composition even when added to a resin in a large amount, without causing abrasion on molds and deteriorating an electrical insulation property of the composition, and (iv) provides the composition with excellent molding processability. The present thermally-conductive organic additive includes a liquid crystalline thermoplastic resin which has a mainly-chain structure, wherein a main chain of the liquid crystalline thermoplastic resin contains mainly a repeating unit represented by the general formula (1): -M-Sp-  (1) wherein M represents a mesogenic group; and Sp represents a spacer, the liquid crystalline thermoplastic resin itself having thermal conductivity of not less than 0.45 W/(m·K).
    • 本发明提供一种导热性有机添加剂,其与(i)为有机聚合物不同于陶瓷,金属和碳材料等导热性无机填料,(ii)能够通过添加赋予塑料导热性 (iii)即使在大量添加到树脂中也可以降低组合物的重量,而不会造成模具磨损并降低组合物的电绝缘性,(iv)提供具有优异成型加工性的组合物。 本发明的导热性有机添加剂包括具有主链结构的液晶性热塑性树脂,其中液晶热塑性树脂的主链主要包含由通式(1)表示的重复单元:-M-Sp- (1)其中M表示介晶基团; Sp表示间隔物,液晶热塑性树脂本身的导热率不低于0.45W /(m·K)。
    • 28. 发明申请
    • New family of conducting liquid crystals
    • 新系列导电液晶
    • US20030160212A1
    • 2003-08-28
    • US10149460
    • 2003-01-13
    • Neville BodenRichard James BushbyGareth HeaddockOwen Roger LozmanAndrew WoodEkaterina Olegovna ArikainenAndrew Paul McNeillZhibao LuQuanying Liu
    • C09K019/32
    • C07D487/22C09K19/32C09K19/3441C09K19/3452C09K19/3804C09K19/3833C09K2019/328Y10T428/10
    • A mixture comprising a molecule of formula (I); in which A1, A2, A3, A4, A5 and A6, which may be the same or different, are each N or nullCH; Y1, Y2, Y3, Y4, Y5 and Y6, which may be the same or different, are each hydrogen or C1 to C12 alkoxy; X1, X2, X3, X4, X5 and X6, which may be the same or different, are each hydrogen, C1 to C12 alkoxy or alkyl C1 to C12; and R7. R8, R9, R10, R11 and R12 are each hydrogen, or each of R7 and R8, R9 and R10 and R11 and R12 may form a bond; and a molecule of formula (II); in which R1, R2, R3, R4, R5 and R6, which may be the same or different, are each alkyl or substituted (and/or chiral) alkyl C1 to C16, acyl C1 to C16, polyethyleneoxy, a flexible connection to a polymer backbone or part of a polymer backbone in homopolymers, copolymers or block copolymers; and B1, B2, B3, B4, B5 and B6a, which may be the same or different, are each, hydrogen, alkyl C1 to C16, alkoxy C1 to C16, nitro, halogeno, cyano, amido, diazo or ester, e.g. alkyl C1 to C16 ester.
    • 包含式(I)分子的混合物; 其中可以相同或不同的A1,A2,A3,A4,A5和A6各自为N或-CH; Y1,Y2,Y3,Y4,Y5和Y6可以相同或不同,分别为氢或C1〜C12烷氧基; 可以相同或不同的X 1,X 2,X 3,X 4,X 5和X 6各自为氢,C 1至C 12烷氧基或C 1至C 12烷基; 和R7。 R 8,R 9,R 10,R 11和R 12各自为氢,R 7和R 8,R 9和R 10和R 11和R 12可以形成键; 和式(II)的分子; 其中可以相同或不同的R 1,R 2,R 3,R 4,R 5和R 6各自为烷基或取代的(和/或手性)C 1至C 16烷基,C 1至C 16的酰基,聚乙烯氧基,与 聚合物主链或部分聚合物主链在均聚物,共聚物或嵌段共聚物中; 和B1,B2,B3,B4,B5和B6a可以相同或不同,分别为氢,C1至C16烷基,烷氧基C1至C16,硝基,卤代,氰基,酰氨基,重氮或酯。 烷基C1至C16酯。