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    • 1. 发明授权
    • Multilevel variable resistance memory cell utilizing crystalline programming states
    • 利用晶体编程状态的多电平可变电阻存储单元
    • US08363446B2
    • 2013-01-29
    • US12578638
    • 2009-10-14
    • Wolodymyr CzubatyjTyler LowreyCharles DennisonCarl Schell
    • Wolodymyr CzubatyjTyler LowreyCharles DennisonCarl Schell
    • G11C11/00
    • G11C11/56G11C11/5678G11C13/0004G11C13/0069G11C2013/0092
    • A method of programming an electrical variable resistance memory device. When applied to variable resistance memory devices that incorporate a phase-change material as the active material, the method utilizes a plurality of crystalline programming states. The crystalline programming states are distinguishable on the basis of resistance, where the resistance values of the different states are stable with time and exhibit little or no drift. As a result, the programming scheme is particularly suited to multilevel memory applications. The crystalline programming states may be achieved by stabilizing crystalline phases that adopt different crystallographic structures or by stabilizing crystalline phases that include mixtures of two or more distinct crystallographic structures that vary in the relative proportions of the different crystallographic structures. The programming scheme incorporates at least two crystalline programming states and further includes at least a third programming state that may be a crystalline, amorphous or mixed crystalline-amorphous state.
    • 一种编程电可变电阻存储器件的方法。 当应用于包含相变材料作为活性材料的可变电阻存储器件时,该方法利用多个晶体编程状态。 结晶编程状态可以根据电阻进行区分,其中不同状态的电阻值随时间稳定并且表现出很小的或没有漂移。 因此,编程方案特别适用于多层存储器应用。 晶体编程状态可以通过稳定采用不同晶体结构的结晶相或通过稳定结晶相来实现,所述结晶相包括两种或更多种不同结晶学结构的混合物,其在不同结晶学结构的相对比例中变化。 编程方案包含至少两个晶体编程状态,并且还包括至少第三编程状态,其可以是晶体,无定形或混合晶体 - 非晶状态。
    • 4. 发明授权
    • Variable resistance materials with superior data retention characteristics
    • 具有优异数据保留特性的可变电阻材料
    • US08685291B2
    • 2014-04-01
    • US12775078
    • 2010-05-06
    • Carl SchellWolodymyr Czubatyj
    • Carl SchellWolodymyr Czubatyj
    • H01B1/02H01B1/06H01L21/06
    • H01L45/1625H01L45/06H01L45/1233H01L45/144
    • Variable resistance memory compositions and devices exhibiting superior data retention characteristics at elevated temperature. The compositions are composite materials that include a variable resistance component and an inert component. The variable resistance component may include a phase-change material and the inert component may include a dielectric material. The phase-change material may include Ge, Sb, and Te, where the atomic concentration of Sb is between 3% and 16% and/or the Sb/Ge ratio is between 0.07 and 0.68 and/or the Ge/Te ratio is between 0.6 and 1.1 and/or the concentration of dielectric component (expressed as the sum of the atomic concentrations of the constituent elements thereof) is between 5% and 50%. The compositions exhibit high ten-year data retention temperatures and long data retention times at elevated temperatures.
    • 可变电阻记忆组合物和在升高的温度下表现出优异的数据保留特性的装置。 组合物是包含可变电阻组分和惰性组分的复合材料。 可变电阻部件可以包括相变材料,并且惰性部件可以包括电介质材料。 相变材料可以包括Ge,Sb和Te,其中Sb的原子浓度在3%和16%之间,和/或Sb / Ge比在0.07和0.68之间和/或Ge / Te比在 0.6和1.1和/或介电成分的浓度(以其构成元素的原子浓度之和表示)在5%至50%之间。 该组合物在高温下表现出十年以上的数据保存温度和较长的数据保留时间。