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1. 发明授权

US09969907B2 Controlled peel laminate adhesive films 有权
公开(公告)号：US09969907B2
公开(公告)日：2018-05-15
申请号：US14346770
申请日：2012-09-06
申请人： Julie R. Hatlewick , Robert L. McGee , Stephen J. Skapik, III , Sarah K. Gassner
发明人： Julie R. Hatlewick , Robert L. McGee , Stephen J. Skapik, III , Sarah K. Gassner
IPC分类号： C09J7/29 , C09J7/02 , B32B7/06 , B32B15/08 , B32B27/08 , B32B27/32 , B32B1/08 , H01B7/02 , H01B7/18
CPC分类号： C09J7/29 , B32B1/08 , B32B7/06 , B32B15/08 , B32B27/08 , B32B27/32 , B32B2405/00 , C09J7/35 , C09J2201/128 , C09J2201/162 , C09J2203/302 , C09J2423/04 , C09J2423/046 , C09J2423/106 , C09J2433/00 , H01B7/02 , H01B7/188 , Y10T428/2804 , Y10T428/2848
摘要： A multilayer adhesive film comprising surface adhesive layers, an internal Controlled Bond Layer (“CBL”) comprising a propylene-based polymer strippably adhered to an adjacent layer; an internal Strong Bond Layer (“SBL”) different than the CBL having a facial surface in adhering contact to the CBL and; optionally, one or more different internal Filler Layer(s) located between the SBL and the adhesive surface layer on the side of the SBL opposite to the adhered CBL. In preferred embodiments the adhesive comprises an ethylene/ethylenically unsaturated carboxylic acid copolymer. The adhesive films are used in cable shielding structures.

2. 发明申请

US20150237877A1 METHODS OF HANDLING PERSIMMONS 审中-公开
标题翻译：处理方法
公开(公告)号：US20150237877A1
公开(公告)日：2015-08-27
申请号：US14430109
申请日：2013-09-13
申请人： Fernando K. EDAGI , Nazir MIR , Evan McCaskey , Robert L. McGee , Bruce Menning , AGROFRESH INC. , DOW GLOBAL TECHNOLOGIES LLC
发明人： Fernando K. Edagi , Nazir Mir , Evan McCaskey , Robert L. McGee , Bruce Menning
IPC分类号： A23B7/144
CPC分类号： A23B7/144 , A23L3/3409
摘要： Provided is a method of storing persimmons comprising the step of exposing persimmons to an atmosphere that contains a cyclopropene compound, wherein either (a) the persimmons are in a modified-atmosphere package during exposure to the cyclopropene compound, or (b) the persimmons are placed into a modified-atmosphere package after exposure to the cyclopropene compound, and the persimmons remain in the modified atmosphere package for at least two hours. In some embodiments, the modified-atmosphere package is constructed so that the transmission rate of oxygen for the entire package is from 200 to 40,000 cubic centimeters per day per kilogram of persimmons.
摘要翻译：提供了一种储存柿子的方法，包括将柿子暴露于含有环丙烯化合物的气氛的步骤，其中（a）在暴露于环丙烯化合物期间，（a）柿子处于改性气氛包装中，或（b）柿子是在暴露于环丙烯化合物之后置于改性气氛包装中，并且柿子保持在改性气氛包装中至少2小时。在一些实施方案中，改性气氛包装被构造成使得整个包装的氧的透过率为每公斤柿子每天200至40,000立方厘米。

3. 发明授权

US07939169B2 Thermoplastic olefin polymer blend and adhesive films made therefrom 有权
标题翻译：热塑性烯烃聚合物共混物和由其制成的粘合膜
公开(公告)号：US07939169B2
公开(公告)日：2011-05-10
申请号：US12305312
申请日：2007-05-17
申请人： Robert L. McGee , Allen W. Ross
发明人： Robert L. McGee , Allen W. Ross
IPC分类号： B32B7/12 , B32B5/16 , B29C59/00
CPC分类号： B32B7/12 , B32B27/08 , B32B27/32 , B32B2323/043 , B32B2323/046 , B32B2405/00 , B32B2571/00 , C08L23/06 , C08L23/0815 , C08L23/0869 , C09J7/241 , C09J7/29 , C09J7/385 , C09J2201/162 , C09J2203/31 , C09J2423/00 , C09J2423/006 , C09J2433/00 , Y10T156/10 , Y10T428/25 , Y10T428/28 , Y10T428/2848 , Y10T428/31794 , C08L2666/06
摘要： Disclosed is a multilayer film having: (A) an adhesive layer comprising at least about 40 weight percent of an ethylene/alkyl acrylate copolymer and at least about 20 weight percent of a low density polyethylene, and at most about 7 weight percent filler; (C) a barrier layer comprising at least about 90 weight percent high density polyethylene; and (B) a core layer comprising at least about 20 weight percent linear low density polyethylene, at least about 20 weight percent low density polyethylene, at least about 10 weight percent high density polyethylene and at most about 5 weight percent filler. Such a film is useful to protect surfaces and preferably adheres when needed for protection and is removable after protection is no longer desired.
摘要翻译：公开了一种多层膜，其具有：（A）包含至少约40重量％的乙烯/丙烯酸烷基酯共聚物和至少约20重量％的低密度聚乙烯和至多约7重量％的填料的粘合剂层; （C）包含至少约90重量％的高密度聚乙烯的阻挡层; 和（B）核心层，其包含至少约20重量％的线性低密度聚乙烯，至少约20重量％的低密度聚乙烯，至少约10重量％的高密度聚乙烯和至多约5重量％的填料。这种膜可用于保护表面并且优选在需要时粘附以进行保护，并且在不再需要保护之后是可移除的。

4. 发明申请

US20100215877A1 MULTILAYER COEXTRUDED SHRINK LABELS OF ORIENTED POLYSTYRENE FILM CONTAINING SMALL RUBBER PARTICLES AND LOW RUBBER PARTICLE GEL CONTENT AND BLOCK COPOLYMERS 失效
标题翻译：包含小橡胶颗粒和低橡胶颗粒凝胶含量和嵌段共聚物的定向聚苯乙烯薄膜的多层共缩合收缩标签
公开(公告)号：US20100215877A1
公开(公告)日：2010-08-26
申请号：US12680862
申请日：2008-09-18
申请人： Robert L. McGee , Stephen J. Skapik, III , Julie R. Hatlewick
发明人： Robert L. McGee , Stephen J. Skapik, III , Julie R. Hatlewick
IPC分类号： B65B53/02 , B32B5/16 , B29C47/06 , B29C39/20
CPC分类号： C08L53/02 , B32B1/08 , B32B25/16 , B32B27/08 , B32B27/302 , B32B2307/5825 , B32B2307/736 , B32B2519/00 , C08F257/02 , C08L51/003 , Y10T428/1328 , Y10T428/25 , Y10T428/254 , C08L2666/02
摘要： A multilayer film comprises at least 3 layers including a first outer layer, a second outer layer and between the first and second outer layers at least one core layer. The first and second outer layers each comprise at least about 75 weight percent of (a) at least one high impact polystyrene (HIPS) component. The at least one core layer comprises (b) at least one styrene block copolymer that is present at a concentration of at least about 2 weight percent of the polymers in the film; and-polymers (a), (b) and (c) at least one general purpose polystyrene having a weight-average molecular weight of more than 200,000 grams per mole and 350,000 grams per mole or less and that is present at a concentration of at least about 10 weight percent and up to at most about 50 weight percent of the polymers in the composition account for 100 percent by weight of the polymers in the polymer composition excluding polymeric additives.
摘要翻译：多层膜包括至少3层，包括第一外层，第二外层和第一和第二外层之间的至少一个核心层。第一和第二外层各自包含至少约75重量％的（a）至少一种高抗冲聚苯乙烯（HIPS）组分。至少一个核心层包含（b）至少一种苯乙烯嵌段共聚物，其以至少约2重量％的聚合物的浓度存在于膜中; 聚合物（a），（b）和（c））至少一种通用聚苯乙烯，其重均分子量大于200,000克/摩尔和350,000克/摩尔或更少，并且浓度为组合物中至少约10重量％和至多约50重量％的聚合物占聚合物组合物中除了聚合物添加剂之外的100重量％的聚合物。

5. 发明申请

US20090311472A1 SHRINK LABELS OF ORIENTED POLYSTYRENE FILM CONTAINING SMALL RUBBER PARTICLES AND LOW RUBBER PARTICLE GEL CONTENT AND BLOCK COPOLYMERS 有权
标题翻译：含有小橡胶颗粒和低橡胶颗粒凝胶含量和嵌段共聚物的定向聚苯乙烯薄膜的收缩标签
公开(公告)号：US20090311472A1
公开(公告)日：2009-12-17
申请号：US12306994
申请日：2006-07-27
申请人： Robert L. McGee , Stephen J. Skapik, III
发明人： Robert L. McGee , Stephen J. Skapik, III
IPC分类号： B32B3/10 , G09F3/02 , C08L51/00
CPC分类号： C08L51/003 , C08J5/18 , C08J2325/06 , C08L25/06 , C08L53/02 , Y10T428/24273 , Y10T428/24893 , Y10T428/268 , Y10T428/31909 , Y10T428/31924 , Y10T428/31931 , C08L2666/02 , C08L2666/24 , C08L2666/06
摘要： A polymer composition containing (a) a high impact polystyrene (HIPS) component with a block copolymer grafted to polystyrene, a rubbery conjugated diene content of one to seven weight percent based on HIPS weight, less than 10 weight-percent gel concentration, an average rubber particle size of between one and 0.01 micrometers, about 40 to about 90 volume percent of the rubber particles have diameters of less than about 0.4 microns and from about 10 to about 60 volume percent of the rubber particles have diameters between about 0.4 and about 2.5 microns, a majority of rubber particles with a core/shell morphology and a concentration that accounts for 10 to 70 weight-percent of the total polymer composition weight and one to five weight-percent rubbery diene based on total polymer composition weight; (b) from 10 to 70 weight percent of a general purpose polystyrene and from about 2 to about 80 weight-percent of a styrene block copolymer component, both based on total polymer composition weight. In a film, preferably oriented, wherein the polymer composition accounts for at least 95 weight-percent of the film, with the balance of the film or film composition weight being additives. Shrink labels are made from the film.
摘要翻译：一种聚合物组合物，其包含（a）具有接枝到聚苯乙烯的嵌段共聚物的高抗冲聚苯乙烯（HIPS）组分，基于HIPS重量的1至7重量％的橡胶状共轭二烯含量，小于10重量％的凝胶浓度，平均橡胶颗粒尺寸为1至0.01微米，约40至约90体积％的橡胶颗粒具有小于约0.4微米的直径，并且约10至约60体积％的橡胶颗粒具有约0.4至约2.5的直径基于总聚合物组合物重量，具有核/壳形态和占总聚合物组合物重量的10至70重量％和1-5重量％橡胶二烯的浓度的大多数橡胶颗粒; （b）基于总聚合物组合物重量，10至70重量％的通用聚苯乙烯和约2-约80重量％的苯乙烯嵌段共聚物组分。在薄膜中，优选取向，其中聚合物组合物占薄膜的至少95重量％，其余的薄膜或薄膜组合物重量为添加剂。收缩标签由电影制作。

6. 发明授权

US06361926B1 Acid functional polymers based on benzocyclobutene 有权
标题翻译：基于苯并环丁烯的酸官能聚合物
公开(公告)号：US06361926B1
公开(公告)日：2002-03-26
申请号：US09177819
申请日：1998-10-23
申请人： Ying H. So , Robert A. DeVries , Mitchell G. Dibbs , Robert L. McGee , Edward O. Shaffer, II , Michael J. Radler , Richard P. DeCaire
发明人： Ying H. So , Robert A. DeVries , Mitchell G. Dibbs , Robert L. McGee , Edward O. Shaffer, II , Michael J. Radler , Richard P. DeCaire
IPC分类号： G03F7038
CPC分类号： C08G61/06 , C08G77/04 , G03F7/0045 , G03F7/027 , G03F7/0755 , G03F7/0757 , G03F7/095
摘要： The invention is a curable cyclobutarene based polymer comprising acid functional pendant groups. The cured polymer displays excellent qualities of toughness, adhesion, dielectric constant, and low stress. The preferred system is soluble in an aqueous base and can be used to generate patterned films with excellent resolution without the need to handle organic developer solvents.
摘要翻译：本发明是一种包含酸官能侧基的可固化的基于环丁烷的聚合物。固化的聚合物显示出优异的韧性，粘合性，介电常数和低应力性质。优选的体系可溶于碱性水溶液，可用于产生具有优异分辨率的图案化膜，而不需要处理有机显影剂溶剂。

7. 发明申请

US20140262426A1 CONTROLLED PEEL LAMINATE ADHESIVE FILMS 有权
标题翻译：控制层压板胶粘膜
公开(公告)号：US20140262426A1
公开(公告)日：2014-09-18
申请号：US14346770
申请日：2012-09-06
申请人： Julie R. Hatlewick , Robert L. McGee , Stephen J. Skapik , Sarah K. Gassner
发明人： Julie R. Hatlewick , Robert L. McGee , Stephen J. Skapik , Sarah K. Gassner
IPC分类号： C09J7/02 , H01B7/18 , H01B7/02
CPC分类号： C09J7/29 , B32B1/08 , B32B7/06 , B32B15/08 , B32B27/08 , B32B27/32 , B32B2405/00 , C09J7/35 , C09J2201/128 , C09J2201/162 , C09J2203/302 , C09J2423/04 , C09J2423/046 , C09J2423/106 , C09J2433/00 , H01B7/02 , H01B7/188 , Y10T428/2804 , Y10T428/2848
摘要： Disclosed is a multilayer adhesive film comprising surface adhesive layers, an internal Controlled Bond Layer (“CBL”) comprising a propylene-based polymer strippably adhered to an adjacent layer; an internal Strong Bond Layer (“SBL”) different than the CBL having a facial surface in adhering contact to the CBL and; optionally, one or more different internal Filler Layer(s) located between the SBL and the adhesive surface layer on the side of the SBL opposite to the adhered CBL. In preferred embodiments the adhesive comprises an ethylene/ethylenically unsaturated carboxylic acid copolymer. The adhesive films are used in calbe shielding structures.
摘要翻译：公开了一种包括表面粘合剂层的多层粘合剂膜，包含可剥离地粘附到相邻层上的基于丙烯的聚合物的内部受控粘结层（“CBL”）; 与CBL不同的内部强粘合层（“SBL”），其具有与CBL的粘合接触的面部表面; 可选地，一个或多个不同的内部填料层位于SBL与SBL的与粘附的CBL相对侧的粘合剂表面层之间。在优选的实施方案中，粘合剂包含乙烯/烯属不饱和羧酸共聚物。粘合膜用于卡氏屏蔽结构。

8. 发明授权

US08581094B2 Electronic device module comprising polyolefin copolymer 有权
标题翻译：包含聚烯烃共聚物的电子器件模块
公开(公告)号：US08581094B2
公开(公告)日：2013-11-12
申请号：US11857208
申请日：2007-09-18
申请人： Rajen M. Patel , Shaofu Wu , Mark T. Bernius , Mohamed Esseghir , Robert L. McGee , Michael H. Mazor , John Naumovitz
发明人： Rajen M. Patel , Shaofu Wu , Mark T. Bernius , Mohamed Esseghir , Robert L. McGee , Michael H. Mazor , John Naumovitz
IPC分类号： H02N6/00 , H01L31/042 , H01L31/00
CPC分类号： H01L31/0481 , B32B17/10018 , B32B17/10678 , B32B2457/12 , C08L51/06 , H01L31/18 , Y02E10/50 , C08L2666/02 , C08L2666/04
摘要： An electronic device module comprising: A. At least one electronic device, e.g., a solar cell, and B. A polymeric material in intimate contact with at least one surface of the electronic device, the polymeric material comprising (1) a polyolefin copolymer with at least one of (a) a density of less than about 0.90 g/cc, (b) a 2% secant modulus of less than about 150 megaPascal (mPa) as measured by ASTM D-882-02), (c) a melt point of less than about 95 C, (d) an α-olefin content of at least about 15 and less than about 50 wt % based on the weight of the polymer, (e) a Tg of less than about −35 C, and (f) a SCBDI of at least about 50, (2) optionally, free radical initiator, e.g., a peroxide or azo compound, or a photoinitiator, e.g., benzophenone, and (3) optionally, a co-agent. Typically, the polyolefin copolymer is an ethylene/α-olefin copolymer. Optionally, the polymeric material can further comprise a vinyl silane and/or a scorch inhibitor, and the copolymer can remain uncrosslinked or be crosslinked.
摘要翻译：一种电子设备模块，包括：A.至少一个电子设备，例如太阳能电池和B.与所述电子设备的至少一个表面紧密接触的聚合材料，所述聚合材料包含（1）聚烯烃共聚物，（a）小于约0.90g / cc的密度，（b）通过ASTM D-882-02测量的小于约150兆帕（mPa）的2％割线模量中的至少一个），（c）熔点低于约95℃，（d）基于聚合物重量，至少约15-小于约50重量％的α-烯烃含量，（e）小于约-35℃的Tg，和（f）至少约50的SCBDI，（2）任选的自由基引发剂，例如过氧化物或偶氮化合物，或光引发剂，例如二苯甲酮，和（3）任选的助剂。通常，聚烯烃共聚物是乙烯/α-烯烃共聚物。任选地，聚合物材料还可以包含乙烯基硅烷和/或焦烧抑制剂，并且共聚物可保持未交联或交联。

9. 发明授权

US08207265B2 Adhesives films 有权
标题翻译：粘合剂胶片
公开(公告)号：US08207265B2
公开(公告)日：2012-06-26
申请号：US12444313
申请日：2007-10-16
申请人： Robert L. McGee , Julie R. Hatlewick
发明人： Robert L. McGee , Julie R. Hatlewick
IPC分类号： C08B15/08 , C08L23/04 , C08L37/00 , C08L53/00 , C09J151/06 , C09J123/06
CPC分类号： C08L23/06 , B32B7/12 , B32B15/08 , C08L23/0815 , C08L51/06 , C08L2666/02 , C08L2666/04 , C08L2666/24 , C09J7/10 , C09J7/22 , C09J7/35 , C09J151/06 , C09J153/00 , C09J2423/00 , C09J2451/00 , Y10T428/249991 , Y10T428/31692 , C08L2666/06
摘要： This invention comprises a film useful as an adhesive, a composition useful to make the film, and a laminate comprising the film contiguous with at least one metal substrate, at least one foam substrate or combination thereof. The composition comprises (a) at least one anhydride grafted olefin polymer, (b) at least one high density polyethylene, and (c) at least one elastomer which preferably has a tensile elongation at break of at least about 585%, a density of at most about 0.900 g/cm3 or a combination thereof. The anhydride grafted olefin polymer or combination thereof is preferably present in an amount of from about 20 to about 40 weight percent, the high density polyethylene or combination thereof is preferably present in an amount of from about 40 to about 60 weight percent, and the elastomer or combination thereof is preferably present in an amount of from about 17 to about 30 weight percent. Each anhydride grafted olefin polymer is independently most preferably a maleic anhydride grafted high density polyethylene. The high density polyethylene preferably has a melt index at most about 30 dg/min. The elastomer is preferably a substantially linear ethylene polymer or olefin block copolymer.
摘要翻译：本发明包括可用作粘合剂的膜，可用于制备膜的组合物，以及包含与至少一种金属基材，至少一种泡沫基材或其组合相邻的膜的层压体。组合物包含（a）至少一种酸酐接枝的烯烃聚合物，（b）至少一种高密度聚乙烯，和（c）至少一种弹性体，其优选的拉伸断裂伸长率至少为约585％，密度为至多约0.900g / cm 3或其组合。酸酐接枝的烯烃聚合物或其组合优选以约20至约40重量％的量存在，高密度聚乙烯或其组合优选以约40至约60重量％的量存在，弹性体或其组合优选以约17至约30重量％的量存在。每个酸酐接枝的烯烃聚合物独立地最优选马来酸酐接枝的高密度聚乙烯。高密度聚乙烯优选具有至多约30dg / min的熔体指数。弹性体优选为基本上线性的乙烯聚合物或烯烃嵌段共聚物。

10. 再颁专利

USRE40728E1 Acid functional polymers based on benzocyclobutene 有权
公开(公告)号：USRE40728E1
公开(公告)日：2009-06-09
申请号：US10808270
申请日：2004-03-24
申请人： Ying H. So , Robert A. DeVries , Mitchell G. Dibbs , Robert L. McGee , Edward O. Shaffer, II , Michael J. Radler , Richard P. DeCaire
发明人： Ying H. So , Robert A. DeVries , Mitchell G. Dibbs , Robert L. McGee , Edward O. Shaffer, II , Michael J. Radler , Richard P. DeCaire
IPC分类号： G03F7/038 , G03F7/039 , G03F7/021 , G03F7/023
CPC分类号： C08G61/06 , C08G77/04 , G03F7/0045 , G03F7/027 , G03F7/0755 , G03F7/0757 , G03F7/095
摘要： The invention is a curable cyclobutarene based polymer comprising acid functional pendant groups. The cured polymer displays excellent qualities of toughness, adhesion, dielectric constant, and low stress. The preferred system is soluble in an aqueous base and can be used to generate patterned films with excellent resolution without the need to handle organic developer solvents.

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