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    • 4. 发明申请
    • Apparatus and method to measure a molecular diffusion coefficient in a porous powder
    • 测量多孔粉末中分子扩散系数的装置和方法
    • US20160091409A1
    • 2016-03-31
    • US14530754
    • 2014-11-02
    • Fei WangDezheng WangYao Wang
    • Fei WangDezheng WangYao Wang
    • G01N15/08
    • G01N15/0826G01N33/00G01N2033/0091
    • An apparatus and method for measuring molecular diffusivity in porous powders or minerals, e.g., the microporous synthetic minerals used for gas separation and chemical catalysis, were invented that allows a varying pressure in the gas around the powder during the measurement. This obviates the need for the pressure to be constant and the attendant complicated component parts. A mass balance model equation of the sample cell with the diffusivity as an adjustable parameter is used to deduce the sample cell pressure change versus time (uptake curve) until the equilibration of gas diffusion into the powder. A numerical analysis method is used to solve the mathematical model to compute a simulated uptake curve. Curve fitting of the simulated and measured uptake curves is used to optimize the diffusivity parameter, which gives the measured diffusivity. The apparatus and method are simple, easy to use, and automation is also simple.
    • 发明了用于测量多孔粉末或矿物质中的分子扩散率的装置和方法,例如用于气体分离和化学催化的微孔合成矿物质,其允许在测量期间在粉末周围的气体中变化的压力。 这避免了压力恒定的需要和附带复杂的部件。 使用具有扩散率作为可调参数的样品池的质量平衡模型方程来推导样品池压力变化对时间(吸收曲线),直到气体扩散到粉末中的平衡。 使用数值分析方法来求解模拟吸收曲线的数学模型。 使用模拟和测量的吸收曲线的曲线拟合来优化扩散系数参数,这给出了测量的扩散系数。 该设备和方法简单,易于使用,自动化也很简单。