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    • 4. 发明申请
    • PROCESS AND APPARATUS FOR SEPARATING AND RECOVERING WASTE ALKALI FROM CYCLOHEXANE OXIDATION SOLUTION
    • 从环己烷氧化溶液中分离和回收废物碱的工艺和装置
    • US20100126938A1
    • 2010-05-27
    • US12358004
    • 2009-01-22
    • Zhishan BAIZhuoqun QianJi MaPing ZhouYanhong ZhangHualin Wang
    • Zhishan BAIZhuoqun QianJi MaPing ZhouYanhong ZhangHualin Wang
    • B01D21/00
    • C07C45/33B01D17/0214C07C2601/14Y10S210/908C07C49/403
    • The present invention relates to a process and an apparatus for separating and recovering the waste alkali from a cyclohexane oxidation solution, and provides a process and an apparatus for separating and recovering the waste alkali from a cyclohexane oxidation solution. According to the invention, a gradient combination of the gravity separation technique, the vortex separation technique and the coalescence separation technique is used to carry out fine separation of the waste alkali liquor from the cyclohexane oxidation solution. The purified cyclohexane oxidation solution is fed into a down-stream apparatus. Most of the waste alkali liquor thus separated is recycled, while the remaining is expelled. The expelled waste alkali liquor is incinerated in an incinerator, followed by recovering the molten species using a pneumatic pulverization process. According to the invention, the content of Na+ in the cyclohexane oxidation solution fed into the alkane tower can be lowered to less than 3 mg/L, and the molten species resulting from incineration can be recovered 100%. Thus, risk of environmental pollution by the waste alkali liquor is substantially eliminated. While the invention is well suited to separate and recover the waste alkali liquor from a cyclohexane oxidation solution, it may be adapted to other chemical engineering systems for separating and recovering waste alkali liquor as well.
    • 本发明涉及从环己烷氧化溶液中分离回收废碱的方法和装置,提供了从环己烷氧化溶液中分离回收废碱的方法和装置。 根据本发明,使用重力分离技术,涡流分离技术和聚结分离技术的梯度组合来进行废碱液与环己烷氧化溶液的精细分离。 将纯化的环己烷氧化溶液进料到下游装置中。 大部分如此分离的废碱液体被回收,而其余的被排出。 将排出的废碱液在焚化炉中焚烧,然后使用气动粉碎法回收熔融物质。 根据本发明,进料到烷烃塔中的环己烷氧化溶液中的Na +含量可以降低到小于3mg / L,焚烧产生的熔融物质可以回收100%。 因此,废碱液的环境污染的风险基本上被消除。 尽管本发明非常适合于从环己烷氧化溶液中分离和回收废碱液体,但是也可以适用于用于分离和回收废碱液的其它化学工程系统。