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1. 发明授权

US11905296B2 Process for the synthesis of buprenorphine 有权
公开(公告)号：US11905296B2
公开(公告)日：2024-02-20
申请号：US17790042
申请日：2021-01-27
申请人： AZAD PHARMA AG
发明人： Hartmut Zinser , Tamar Danielyan , Meri Grigoryan , Mariam Gharibyan , Mikayel Movsisyan , Kristine Nerkararyan
IPC分类号： C07D489/12 , C07B49/00 , C07B43/08 , C07B43/04 , C07B31/00 , C07B37/12 , C07D498/12 , A61P25/36 , A61P25/04
CPC分类号： C07D489/12 , A61P25/04 , A61P25/36 , C07B31/00 , C07B37/12 , C07B43/04 , C07B43/08 , C07B49/00 , C07D498/12 , C07D489/12 , C07B49/00 , C07D489/12 , C07B43/08 , C07D489/12 , C07B43/04 , C07D489/12 , C07B31/00 , C07D489/12 , C07B37/12
摘要： The present invention relates to a novel route of synthesis for the opioid receptor antagonist Buprenorphine or a pharmaceutically acceptable salt thereof, starting from thebaine, wherein the route comprises the reaction of thebaine with a dienophile; forming an alkylated reaction product by reaction with a Grignard-reagent; formation of an cyanamide; deprotection of the cyanamide- and the phenolic-oxygen-moiety, wherein the cleavage of one or both groups is performed in the presence of an alkali or alkaline earth sulfide; followed by derivatization with a cyclopropyl-halogen and hydrogenation to yield Buprenorphine.

2. 发明授权

US10562927B2 Bismuth perfluoroalkylphosphinates as lewis acid catalysts 有权
公开(公告)号：US10562927B2
公开(公告)日：2020-02-18
申请号：US15762880
申请日：2016-09-07
申请人： MERCK PATENT GMBH
发明人： Berthold Theo Hoge , Sven Joerg-Ruediger August Solyntjes , Nikolai (Mykola) Ignatiev
IPC分类号： C07F9/00 , C07F9/94 , B01J31/02 , C07B37/02 , C07B37/04 , C07B41/06 , C07B41/12 , C07B43/08 , C07F9/30 , C07B37/12
摘要： The invention relates to bismuth perfluoroalkylphosphinates as Lewis acid catalysts, the compounds, and processes for the preparation thereof. ArxBi[OP(O)(Rf)2]3-x (Ia), Ar3Bi[OP(O)(Rf)2]2 (Ib).

3. 发明授权

US10245617B2 Synthesis of surface-functionalized polyamides 有权
公开(公告)号：US10245617B2
公开(公告)日：2019-04-02
申请号：US15741300
申请日：2016-07-06
申请人： BASF SE
发明人： Gijsbrecht Jacobus Maria Habraken , Johannes Klaus Sprafke , Marion da Silva
IPC分类号： B05D1/36 , B05D3/00 , B05D3/10 , B05D7/00 , B05D7/02 , C08J7/12 , C07B37/12 , C08G69/48 , C08L77/06
摘要： The present invention relates to a process for producing a surface-functionalized molding (oF) having a functionalized surface (fO). In this process a surface (O) of a molding (F) is brought into contact with a dienophile-containing solution (dL). The surface (O) comprises a polyamide (P) which comprises furan units. These furan units are able to react with the at least one dienophile present in the dienophile-containing solution (dL) to give the surface-functionalized molding (oF) having the functionalized surface (fO).

4. 发明授权

US10751344B2 Carbon monoxide-releasing molecules for therapeutic applications and methods for the preparation and use thereof 有权
公开(公告)号：US10751344B2
公开(公告)日：2020-08-25
申请号：US16423094
申请日：2019-05-27
申请人： Georgia State University Research Foundation, Inc.
发明人： Binghe Wang , Danzhu Wang , Xingyue Ji , Alexander Draganov , Chaofeng Dai , Krishna Damera , Didier Merlin , Emilie Viennois , Yueqin Zheng
IPC分类号： A61K31/122 , A61K31/5375 , A61K31/015 , A61K31/216 , C07B37/12 , C01B32/40 , A61K47/54 , A61K47/61 , A61K31/166 , A61K31/235
摘要： Carbon monoxide-releasing organic molecules are described herein. The molecules can be synthesized prior to administration (e.g., ex vivo) or formed in vivo. In those embodiments where the molecules are formed in vivo, reactants are administered under physiological conditions and undergo a cycloaddition reaction to form a product which releases carbon monoxide. In applying such reactions for therapeutic applications in vivo, the cycloaddition and CO release typically occur only under near-physiological or physiological conditions. For example, in some embodiments, the cycloaddition reaction and/or release of carbon monoxide occur at a temperature of about 37° C. and pH of about 7.4. Pharmaceutical compositions and methods for release carbon monoxide are also described.

5. 发明申请

US20050123831A1 Pentacyclic anion salts or tetrazapentalene derivatives and their uses as ionic conducting materials 有权
标题翻译：五环阴离子盐或四氮杂蒽衍生物及其用作离子导电材料
公开(公告)号：US20050123831A1
公开(公告)日：2005-06-09
申请号：US10926283
申请日：2004-08-25
申请人： Christophe Michot , Michel Armand , Michel Gauthier , Yves Choquette
发明人： Christophe Michot , Michel Armand , Michel Gauthier , Yves Choquette
IPC分类号： C07D233/58 , B01F1/00 , B01J31/02 , B01J31/04 , B01J31/06 , B01J31/12 , B01J31/18 , B01J31/22 , C01B31/02 , C04B41/83 , C07B37/02 , C07B37/12 , C07B41/06 , C07B61/00 , C07C45/46 , C07C45/69 , C07C67/00 , C07C255/05 , C07C255/10 , C07C255/13 , C07C255/17 , C07C255/27 , C07C255/31 , C07C255/46 , C07C255/65 , C07C257/14 , C07C309/80 , C07C311/03 , C07C311/04 , C07C311/09 , C07C311/48 , C07C317/04 , C07C317/08 , C07C317/14 , C07C317/22 , C07C317/24 , C07C317/34 , C07C317/44 , C07D207/44 , C07D207/452 , C07D213/76 , C07D219/10 , C07D231/18 , C07D233/56 , C07D233/90 , C07D239/60 , C07D241/46 , C07D241/48 , C07D249/04 , C07D249/08 , C07D249/10 , C07D249/12 , C07D251/66 , C07D251/70 , C07D253/06 , C07D277/64 , C07D277/82 , C07D279/20 , C07D285/00 , C07D285/12 , C07D285/125 , C07D285/135 , C07D285/15 , C07D285/16 , C07D303/34 , C07D303/36 , C07D307/54 , C07D307/64 , C07D311/52 , C07D311/58 , C07D311/72 , C07D311/80 , C07D311/82 , C07D319/06 , C07D333/16 , C07D333/20 , C07D333/24 , C07D405/06 , C07D407/04 , C07D409/12 , C07D417/10 , C07D417/14 , C07D487/22 , C07F1/02 , C07F1/06 , C07F7/10 , C07F7/18 , C07F9/6584 , C07F11/00 , C07F15/00 , C07F17/02 , C08F2/00 , C08F2/48 , C08F4/00 , C08F4/04 , C08F4/46 , C08F4/60 , C08F12/22 , C08F12/26 , C08F12/30 , C08F16/14 , C08F216/14 , C08F222/30 , C08F228/02 , C08G59/68 , C08G65/22 , C08G65/334 , C08G73/00 , C08G73/02 , C08G75/00 , C08G75/14 , C08G77/04 , C08G77/388 , C08G85/00 , C08J3/20 , C08J3/24 , C08J3/28 , C08J7/04 , C08L101/00 , C09B47/04 , C09B57/00 , C09B69/00 , C09B69/02 , C09B69/10 , C09C1/56 , C09C3/10 , C09D11/00 , C09K9/02 , C25B9/00 , G02F1/15 , H01B1/04 , H01B1/06 , H01B1/12 , H01B3/20 , H01G9/02 , H01G11/54 , H01M4/00 , H01M4/02 , H01M4/131 , H01M4/133 , H01M4/134 , H01M4/40 , H01M4/48 , H01M4/485 , H01M4/50 , H01M4/505 , H01M4/52 , H01M4/525 , H01M4/58 , H01M4/60 , H01M4/62 , H01M4/66 , H01M4/96 , H01M6/00 , H01M6/04 , H01M6/06 , H01M6/16 , H01M6/18 , H01M8/00 , H01M10/052 , H01M10/0525 , H01M10/0565 , H01M10/0567 , H01M10/0568 , H01M10/36 , H01B1/00
CPC分类号： B01J31/0224 , B01J31/0215 , B01J31/0222 , B01J31/0225 , B01J31/0227 , B01J31/0235 , B01J31/0239 , B01J31/0247 , B01J31/0251 , B01J31/0252 , B01J31/0267 , B01J31/0271 , B01J31/0281 , B01J31/0288 , B01J31/0289 , B01J31/04 , B01J31/06 , B01J31/068 , B01J31/124 , B01J31/1815 , B01J31/2208 , B01J2231/122 , B01J2231/14 , B01J2231/326 , B01J2231/341 , B01J2231/348 , B01J2231/4205 , B01J2231/543 , B01J2531/35 , B01J2531/824 , C07B37/02 , C07B37/12 , C07C45/46 , C07C45/69 , C07C67/00 , C07C255/10 , C07C255/17 , C07C255/27 , C07C255/46 , C07C255/65 , C07C257/14 , C07C311/03 , C07C311/04 , C07C311/09 , C07C311/48 , C07C317/04 , C07C317/08 , C07C317/14 , C07C317/22 , C07C317/24 , C07C317/34 , C07C317/44 , C07C2601/10 , C07C2602/42 , C07D207/452 , C07D213/76 , C07D219/10 , C07D231/18 , C07D233/90 , C07D239/60 , C07D241/42 , C07D249/04 , C07D249/10 , C07D249/12 , C07D251/70 , C07D277/64 , C07D277/82 , C07D285/125 , C07D285/135 , C07D285/15 , C07D285/16 , C07D303/34 , C07D307/54 , C07D307/64 , C07D311/52 , C07D311/58 , C07D311/82 , C07D319/06 , C07D333/16 , C07D333/24 , C07D405/06 , C07D409/12 , C07D417/10 , C07D417/14 , C07F17/02 , C08F4/04 , C08G65/3344 , C09B69/00 , C09B69/02 , C09B69/10 , G02F1/1525 , G02F2001/151 , H01B1/122 , H01B1/128 , H01G9/022 , H01G9/038 , H01G11/02 , H01G11/62 , H01M4/00 , H01M4/02 , H01M4/131 , H01M4/133 , H01M4/134 , H01M4/382 , H01M4/405 , H01M4/48 , H01M4/485 , H01M4/505 , H01M4/525 , H01M4/5815 , H01M4/5825 , H01M4/60 , H01M4/625 , H01M4/661 , H01M6/00 , H01M6/04 , H01M6/164 , H01M6/166 , H01M6/168 , H01M6/181 , H01M6/183 , H01M10/052 , H01M10/0525 , H01M10/0565 , H01M10/0567 , H01M10/0568 , Y02E60/13 , Y10S430/127 , Y10T29/49108 , Y10T428/2918 , C07C49/84 , C07C49/553
摘要： The invention relates to ionic compounds in which the anionic load has been delocalized. A compound disclosed by the invention includes an anionic portion combined with at least one cationic portion Mm+ in sufficient numbers to ensure overall electronic neutrality; the compound is further comprised of M as a hydroxonium, a nitrosonium NO+, an ammonium —NH4+, a metallic cation with the valence m, an organic cation with the valence m, or an organometallic cation with the valence m. The anionic load is carried by a pentacyclical nucleus of tetrazapentalene derivative bearing electroattractive substituents. The compounds can be used notably for ionic conducting materials, electronic conducting materials, colorant, and the catalysis of various chemical reactions.
摘要翻译：本发明涉及其中阴离子负荷已经离域的离子化合物。本发明公开的化合物包括足够数量的与至少一个阳离子部分M + H +结合的阴离子部分以确保整体电子中性; 该化合物进一步包含作为氢氧化物的M，亚硝酸铵，铵，铵，铵，价铵的金属阳离子 m，m价的有机阳离子或m价的有机金属阳离子。阴离子负载由带有电吸引取代基的四嗪基衍生物的五环核承载。这些化合物可以特别用于离子导电材料，电子导电材料，着色剂和各种化学反应的催化。

6. 发明授权

US6120696A Proton conductors in liquid form 有权
标题翻译：液体形式的质子导体
公开(公告)号：US6120696A
公开(公告)日：2000-09-19
申请号：US125792
申请日：1998-08-28
申请人： Michel Armand , Christophe Michot , Bruno Kapfer
发明人： Michel Armand , Christophe Michot , Bruno Kapfer
IPC分类号： C07D233/58 , B01F1/00 , B01J31/02 , B01J31/04 , B01J31/06 , B01J31/12 , B01J31/18 , B01J31/22 , C01B31/02 , C04B41/83 , C07B37/02 , C07B37/12 , C07B41/06 , C07B61/00 , C07C45/46 , C07C45/69 , C07C67/00 , C07C255/05 , C07C255/10 , C07C255/13 , C07C255/17 , C07C255/27 , C07C255/31 , C07C255/46 , C07C255/65 , C07C257/14 , C07C309/80 , C07C311/03 , C07C311/04 , C07C311/09 , C07C311/48 , C07C317/04 , C07C317/08 , C07C317/14 , C07C317/22 , C07C317/24 , C07C317/34 , C07C317/44 , C07D207/44 , C07D207/452 , C07D213/76 , C07D219/10 , C07D231/18 , C07D233/56 , C07D233/90 , C07D239/60 , C07D241/46 , C07D241/48 , C07D249/04 , C07D249/08 , C07D249/10 , C07D249/12 , C07D251/66 , C07D251/70 , C07D253/06 , C07D277/64 , C07D277/82 , C07D279/20 , C07D285/00 , C07D285/12 , C07D285/125 , C07D285/135 , C07D285/15 , C07D285/16 , C07D303/34 , C07D303/36 , C07D307/54 , C07D307/64 , C07D311/52 , C07D311/58 , C07D311/72 , C07D311/80 , C07D311/82 , C07D319/06 , C07D333/16 , C07D333/20 , C07D333/24 , C07D405/06 , C07D407/04 , C07D409/12 , C07D417/10 , C07D417/14 , C07D487/22 , C07F1/02 , C07F1/06 , C07F7/10 , C07F7/18 , C07F9/6584 , C07F11/00 , C07F15/00 , C07F17/02 , C08F2/00 , C08F2/48 , C08F4/00 , C08F4/04 , C08F4/46 , C08F4/60 , C08F12/22 , C08F12/26 , C08F12/30 , C08F16/14 , C08F216/14 , C08F222/30 , C08F228/02 , C08G59/68 , C08G65/22 , C08G65/334 , C08G73/00 , C08G73/02 , C08G75/00 , C08G75/14 , C08G77/04 , C08G77/388 , C08G85/00 , C08J3/20 , C08J3/24 , C08J3/28 , C08J7/04 , C08L101/00 , C09B47/04 , C09B57/00 , C09B69/00 , C09B69/02 , C09B69/10 , C09C1/56 , C09C3/10 , C09D11/00 , C09K9/02 , C25B9/00 , G02F1/15 , H01B1/04 , H01B1/06 , H01B1/12 , H01B3/20 , H01G9/02 , H01G11/54 , H01M4/00 , H01M4/02 , H01M4/131 , H01M4/133 , H01M4/134 , H01M4/40 , H01M4/48 , H01M4/485 , H01M4/50 , H01M4/505 , H01M4/52 , H01M4/525 , H01M4/58 , H01M4/60 , H01M4/62 , H01M4/66 , H01M4/96 , H01M6/00 , H01M6/04 , H01M6/06 , H01M6/16 , H01M6/18 , H01M8/00 , H01M10/052 , H01M10/0525 , H01M10/0565 , H01M10/0567 , H01M10/0568 , H01M10/36 , B02F1/15
CPC分类号： B01J31/0224 , B01J31/0215 , B01J31/0222 , B01J31/0225 , B01J31/0227 , B01J31/0235 , B01J31/0239 , B01J31/0247 , B01J31/0251 , B01J31/0252 , B01J31/0267 , B01J31/0271 , B01J31/0281 , B01J31/0288 , B01J31/0289 , B01J31/04 , B01J31/06 , B01J31/068 , B01J31/124 , B01J31/1815 , B01J31/2208 , C07B37/02 , C07B37/12 , C07C255/10 , C07C255/17 , C07C255/27 , C07C255/46 , C07C255/65 , C07C257/14 , C07C311/03 , C07C311/04 , C07C311/09 , C07C311/48 , C07C317/04 , C07C317/08 , C07C317/14 , C07C317/22 , C07C317/24 , C07C317/34 , C07C317/44 , C07C45/46 , C07C45/69 , C07C67/00 , C07D207/452 , C07D213/76 , C07D219/10 , C07D231/18 , C07D233/90 , C07D239/60 , C07D241/42 , C07D249/04 , C07D249/10 , C07D249/12 , C07D251/70 , C07D277/64 , C07D277/82 , C07D285/125 , C07D285/135 , C07D285/15 , C07D285/16 , C07D303/34 , C07D307/54 , C07D307/64 , C07D311/52 , C07D311/58 , C07D311/82 , C07D319/06 , C07D333/16 , C07D333/24 , C07D405/06 , C07D409/12 , C07D417/10 , C07D417/14 , C07F17/02 , C08F4/04 , C08G65/3344 , C09B69/00 , C09B69/02 , C09B69/10 , H01B1/122 , H01B1/128 , H01G11/02 , H01G11/62 , H01G9/022 , H01G9/038 , H01M10/052 , H01M10/0525 , H01M10/0565 , H01M10/0567 , H01M10/0568 , H01M4/00 , H01M4/382 , H01M4/5815 , H01M4/625 , H01M6/00 , H01M6/166 , H01M6/181 , H01M6/183 , B01J2231/122 , B01J2231/14 , B01J2231/326 , B01J2231/341 , B01J2231/348 , B01J2231/4205 , B01J2231/543 , B01J2531/35 , B01J2531/824 , C07C2101/10 , C07C2102/42 , G02F1/1525 , G02F2001/151 , H01M4/02 , H01M4/131 , H01M4/133 , H01M4/134 , H01M4/405 , H01M4/48 , H01M4/485 , H01M4/505 , H01M4/525 , H01M4/5825 , H01M4/60 , H01M4/661 , H01M6/04 , H01M6/164 , H01M6/168 , Y02E60/13 , Y10S430/127 , Y10T29/49108 , Y10T428/2918
摘要： The invention is a proton conductor in liquid form, comprising a mixture of the following components: (a) an acid addition salt of a nitrogen base, having the formula: ##STR1## wherein: Z.sub.1, Z.sub.2, Z.sub.3 and Z.sub.4, identical or different, each represent a group --N.dbd. or --C(Y.sub.i).dbd. in which Y.sub.i represents a hydrogen atom, a linear or branched alkyl group having 1 to 20 carbon atoms, a fluoroalkyl radical having 1 to 20 carbon atoms, or an oxoalkyl or azaalkyl radical having 1 to 20 carbon atoms, with the proviso that at least one and at most two of the groups Z.sub.1, Z.sub.2, Z.sub.3 and Z.sub.4 represents --N.dbd., two adjacent carbon atoms being optionally hydrogenated and the nitrogen base optionally being part of a polymeric network, and X.sup.- represents an anion derived from an acid selected from the group consisting of sulfonic acids of formula R.sub.F SO.sub.3 H, sulfonimides of formula (R.sub.F SO.sub.2) (R'.sub.F SO.sub.2)NH and methylides of formula (R.sub.F SO.sub.2) (R'.sub.F SO.sub.2) CH.sub.2 or (R.sub.F S.sub.2) (R'.sub.F SO.sub.2) (R".sub.F SO.sub.2)CH, in which R.sub.F, R'.sub.F and R".sub.F each represents a radical F(CF.sub.2).sub.n --, n being comprised between 0 and 6, the acid optionally being part of a polymeric network; and (b) a nitrogen base having the formula: ##STR2## in which Z.sub.1, Z.sub.2, Z.sub.3 and Z.sub.4 have the aforesaid meanings, the nitrogen base optionally being part of a polymeric network; components (a) and (b) being present in proportions to form a composition having a melting point lower than 25.degree. C. The proton conductor is useful as an electrolyte in various electrochemical systems.
摘要翻译： PCT No.PCT / CA97 / 01012 Sec。 371日期1998年8月28日 102（e）1998年8月28日PCT 1997年12月30日PCT PCT。出版物WO98 / 29877 日期：1998年7月9日本发明是液体形式的质子导体，其包含以下组分的混合物：（a）具有下式的氮碱的酸加成盐：其中：Z1，Z2，Z3和Z4相同或不同的，各自表示基团-N =或-C（Yi）=，其中Yi表示氢原子，具有1至20个碳原子的直链或支链烷基，具有1至20个碳原子的氟烷基，或具有1至20个碳原子的氧代烷基或氮杂烷基，条件是基团Z1，Z2，Z3和Z4中的至少一个和最多两个表示-N =，两个相邻的碳原子任选被氢化，并且氮基任选地为 X-表示衍生自选自式RFSO 3 H的磺酸，式（RFSO 2）（R'FSO 2）NH的亚磺酰亚胺和式（RFSO 2）的甲基化物（R' FSO 2）CH 2或（RFS 2）（R'FSO 2）（R“FSO 2）CH，其中RF，R'F和R''F各自表示基团F（CF 2）n - ，n在0和6之间，酸可选地是聚合物网络的一部分; 和（b）具有下式的氮碱：其中Z 1，Z 2，Z 3和Z 4具有上述含义，氮基任选地是聚合物网络的一部分; 组分（a）和（b）以比例存在以形成熔点低于25℃的组合物。质子导体可用作各种电化学系统中的电解质。

7. 发明授权

US5886234A Process for producing cyclic unsaturated aldehydes 失效
标题翻译：环状不饱和醛的制备方法
公开(公告)号：US5886234A
公开(公告)日：1999-03-23
申请号：US973555
申请日：1997-12-22
申请人： Takashi Ohno , Toshiyuki Tsubouchi
发明人： Takashi Ohno , Toshiyuki Tsubouchi
IPC分类号： B01J21/12 , B01J21/16 , B01J27/16 , C07B37/12 , C07B61/00 , C07C45/69 , C07C47/445 , C07C45/45
CPC分类号： C07C45/69
摘要： A process for producing a cyclic unsaturated aldehyde is herein disclosed which comprises the step of reacting a cyclic conjugated diene compound with an aldehyde represented by the general formula (I)R--CH.dbd.CH--CHO (I)wherein R is an alkyl group having 1 to 3 carbon atoms,in the presence of a solid acid catalyst in accordance with the Diels-Alder reaction.According to the process of the present invention, the cyclic unsaturated aldehydes useful as the raw materials of traction oils and the like can efficiently and industrially advantageously be produced through the Diels-Alder reaction at a low cost without causing the corrosion of an apparatus and without requiring any treatment after the reaction.
摘要翻译： PCT No.PCT / JP96 / 01720 Sec。 371 1997年12月22日第 102（e）日期1997年12月22日PCT提交1996年6月21日PCT公布。公开号WO97 / 00844 日本1997年1月9日本文公开了一种制备环状不饱和醛的方法，其包括使环状共轭二烯化合物与通式（I）R-CH = CH-CHO（I）表示的醛反应的步骤，其中R 是在根据Diels-Alder反应的固体酸催化剂的存在下，具有1至3个碳原子的烷基。根据本发明的方法，用作牵引油等的原料的环状不饱和醛可以通过Diels-Alder反应在低成本下有效地和工业上有效地生产，而不会引起装置的腐蚀和没有需要反应后进行任何治疗。

8. 发明授权

US5169943A Chiral reaction medium for organic reactions 失效
标题翻译：有机反应的CHIRAL REACTION MEDIUM
公开(公告)号：US5169943A
公开(公告)日：1992-12-08
申请号：US623707
申请日：1990-12-14
申请人： Andre Lubineau , Hugues Bienayme , Yves Queneau
发明人： Andre Lubineau , Hugues Bienayme , Yves Queneau
IPC分类号： C07H15/203 , C07B37/12 , C07B53/00 , C07C45/69 , C07C49/753 , C07H15/10
CPC分类号： C07H15/10 , C07C45/69
摘要： The invention concerns a chiral reaction medium for organic reactions and consists of concentrated aqueous solution of at least one carbohydrate selected from among the mono-, di- and tri-saccharides and their alkylglucosides of which the alkyl group comprises from 1 to 4 C atoms.
摘要翻译： PCT No.PCT / FR90 / 00267 Sec。 371 1990年12月14日第 102（e）1990年12月14日日期PCT提交1990年4月12日PCT公布。 WO90 / 12773 PCT出版物 1990年11月1日。本发明涉及用于有机反应的手性反应介质，其由选自单糖，二糖和三糖中的至少一种碳水化合物及其烷基葡糖苷的浓水溶液组成，其烷基包括 1至4个C原子。

9. 发明授权

US09452425B2 Compositions containing ionic liquids and their uses, in particular in organic synthesis 有权
标题翻译：含有离子液体的组合物及其用途，特别是在有机合成中
公开(公告)号：US09452425B2
公开(公告)日：2016-09-27
申请号：US12463027
申请日：2009-05-08
申请人： Michel Vaultier , Said Gmouh
发明人： Michel Vaultier , Said Gmouh
IPC分类号： C07C409/44 , B01J31/02 , B01J31/04 , B01J31/30 , C07B37/02 , C07B37/04 , C07B37/12 , C07C67/03 , C07C67/343 , C07C67/347
CPC分类号： B01J31/0281 , B01J31/0224 , B01J31/0239 , B01J31/0288 , B01J31/04 , B01J31/30 , B01J2231/326 , B01J2231/341 , B01J2231/4211 , B01J2231/4261 , B01J2231/4266 , C07B37/02 , C07B37/04 , C07B37/12 , C07C67/03 , C07C67/343 , C07C67/347 , C07C2602/42 , C07C69/732 , C07C69/65 , C07C69/734 , C07C69/753 , C07C69/618 , C07C69/76
摘要： An ionic liquid is used as liquid matrix for organic synthesis in homogeneous phase on soluble support, the ionic liquid being presented in liquid or solid form at ambient temperature, of formula A1+X1−, A1+ representing a cation, functional or non-functional, or a mixture of cations in which either none of the cations is functional or at least one of the cations is functional, and X1− an anion, functional or non-functional, or a mixture of anions in which either none of the anions is functional or at least one of the anions is functional.
摘要翻译：离子液体用作液体基质，用于在可溶性载体上均相的有机合成，离子液体在环境温度下以液体或固体形式存在，式A1 + X1-，A1 +表示阳离子，官能或非官能的，或阳离子的混合物，其中阳离子中的任一个不是功能性的或至少一种阳离子是有功能的，X1-阴离子，功能性或非功能性的阴离子或阴离子的混合物，其中阴离子都不是功能性的或至少一种阴离子是有功能的。

10. 发明授权

US06977312B2 Phosphor, arsenic and antimony compounds based upon diaryl-anellated bicyclo[2.2.n] parent substances and catalysts containing same 失效
标题翻译：基于二芳基 - 苯氧基双环[2.2.n]母体物质和含有它们的催化剂的磷光体，砷和锑化合物
公开(公告)号：US06977312B2
公开(公告)日：2005-12-20
申请号：US10203296
申请日：2001-02-09
申请人： Wolfgang Ahlers , Michael Röper , Peter Hofmann , Daniel C. M. Warth , Rocco Paciello
发明人： Wolfgang Ahlers , Michael Röper , Peter Hofmann , Daniel C. M. Warth , Rocco Paciello
IPC分类号： B01J31/16 , B01J31/18 , B01J31/22 , B01J31/24 , C07B37/12 , C07C2/50 , C07C13/44 , C07C13/64 , C07C13/68 , C07C45/50 , C07C51/14 , C07C253/10 , C07F9/46 , C07F9/50 , C07F9/6561 , C07F9/6571 , C07F9/6574 , C07F15/00 , C07F15/04 , C07F15/06 , C08F4/42 , C07F9/02
CPC分类号： C07F9/65746 , B01J31/1658 , B01J31/185 , B01J31/1865 , B01J31/1875 , B01J31/2457 , B01J2231/12 , B01J2231/20 , B01J2231/321 , B01J2231/323 , B01J2231/543 , B01J2231/645 , B01J2531/821 , B01J2531/822 , B01J2531/824 , B01J2531/827 , B01J2531/828 , B01J2531/845 , B01J2531/847 , C07C45/50 , C07C253/10 , C07F9/46 , C07F9/5027 , C07F9/6561 , C07F9/65719 , C07C47/02 , C07C255/04
摘要： Novel compounds of phosphorus, of arsenic and of antimony can be used as ligands to form complexes of metals of transition group VIII which can be used in catalysts for hydroformylation, hydrocyanation, carbonylation, hydrogenations, oligomerization and polymerization of olefins and for metathesis.
摘要翻译：可以使用磷，砷和锑的新型化合物作为配体，形成可用于加氢甲酰化，氢化氰化，羰基化，氢化，烯烃低聚和聚合的复合催化剂的过渡基团VIII的金属络合物和复分解。

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