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    • 7. 发明申请
    • COATING COMPOSITION, AND A PROCESS FOR PRODUCING THE SAME
    • 涂料组合物及其制造方法
    • US20110207850A1
    • 2011-08-25
    • US13083078
    • 2011-04-08
    • Charles S. KanRebecca S. OrtizJohn A. Roper, IIIJane E. WeierTimothy J. YoungGary E. SpilmanRay E. Drumright
    • Charles S. KanRebecca S. OrtizJohn A. Roper, IIIJane E. WeierTimothy J. YoungGary E. SpilmanRay E. Drumright
    • C09D167/00C09D163/00C09D133/08C09D131/04
    • C09D167/08C08J3/03C08J3/05C08J2367/08C09D5/022Y10T428/31786Y10T428/31938
    • The present invention provides a coating composition, a process for producing the same, one or more coating layers derived therefrom, and articles comprising one or more such coating layers. The coating composition according to the present invention comprises: (a) from 10 to 90 percent by weight of an aqueous, high-solid, solvent-free alkyd dispersion comprising: (i) from 40 to 70 percent by weight of one or more alkyds based on the total weight of the dispersion, wherein each said one or more alkyds has an acid value of less than 20 and a molecular weight (Mn) in the range of greater than 1000 Dalton; (ii) from less than 10 percent by weight of one or more surfactants, based on the total weight of the dispersion; and (iii) from 30 to 55 percent by weight of water, based on the total weight of the dispersion; wherein said aqueous, high-solid, solvent-free alkyd dispersion has an average particle size diameter in the range of from 0.05 to 5 μm; (b) from 10 to 90 one or more second dispersions, one or more second emulsions, or combinations thereof; wherein said coating composition has a solid content of in the range of from 25 to 65 percent by weight of solid content, based on the total weight of the coating composition, and the coating composition has a pH in the range of from 7 to 11, and wherein the coating composition has a volume average particle size in the range of from 0.03 to 5 μm, and wherein the coating composition has a viscosity in the range of from 100 to 10,000 cP.
    • 本发明提供一种涂料组合物,其制备方法,由其衍生的一种或多种涂层,以及包含一种或多种这样的涂层的制品。 根据本发明的涂料组合物包含:(a)10至90重量%的水性,高固体,无溶剂的醇酸树脂分散体,其包含:(i)40至70重量%的一种或多种醇酸树脂 基于分散体的总重量,其中每个所述一种或多种醇酸树脂的酸值小于20,分子量(Mn)在大于1000道尔顿范围内; (ii)基于分散体的总重量,少于10重量%的一种或多种表面活性剂; 和(iii)基于分散体的总重量的30至55重量%的水; 其中所述水性,高固体,无溶剂的醇酸树脂分散体的平均粒度直径在0.05至5μm的范围内; (b)10至90个一种或多种第二分散体,一种或多种第二乳液或其组合; 其中所述涂料组合物的固体含量为固体含量的25至65重量%,基于涂料组合物的总重量,并且涂料组合物的pH为7至11, 并且其中所述涂料组合物的体积平均粒径在0.03至5μm的范围内,并且其中所述涂料组合物的粘度在100至10000cP的范围内。
    • 9. 发明授权
    • Low volatiles coatings, sealants and binders from renewable oils
    • 低挥发性涂料,密封剂和可再生油的粘合剂
    • US08486526B2
    • 2013-07-16
    • US12597061
    • 2008-04-10
    • Gary E. SpilmanJohn N. ArgyropoulosDebkumar BhattacharjeePaul J. PopaWilliam A. Koonce
    • Gary E. SpilmanJohn N. ArgyropoulosDebkumar BhattacharjeePaul J. PopaWilliam A. Koonce
    • B32B7/12B32B27/00B32B27/40B05D3/02C08G63/08
    • C08G18/4288C08G18/3851C08G18/4063C08G18/6229C08G18/755C08K5/1515C08K5/29C08K5/34922C09D175/04Y10T428/2852
    • A composition comprises (a) a binder component which comprises (1) 5 to 100 weight percent of at least one natural oil derived polyol having at least about 50 percent primary hydroxyl groups and (2) sufficient additional polyol different from a natural oil derived polyol to make 100 percent wherein the natural oil derived polyol has an average of from 1.5 to 3 hydroxyl groups per molecule and an equivalent weight of from 200 to 5000; and (b) a crosslinking component reactive with hydroxyl groups. Furthermore, a process for producing a coating, adhesive, binder or combination thereof on the surface of a substrate, comprises in any order: (a) admixing binder and crosslinking components of a composition to form an admixture, wherein a binder component comprises (1) 5 to 100 weight percent of at least one natural oil derived polyol having at least about 50 percent primary hydroxyl groups and (2) sufficient additional polyol different from a natural oil derived polyol to make 100 percent wherein the natural oil derived polyol has an average of from 1.5 to 3 hydroxyl groups per molecule and an equivalent weight of from 200 to 5000; and (b) applying a layer of said admixture on said surface. The invention includes coatings, adhesives, binders and combinations thereof prepared from any composition of the invention, substrates coated by the process of the invention or coated using a composition of the invention and articles, including laminates, comprising a coating, adhesive, binder or combination thereof of the invention.
    • 组合物包含(a)粘合剂组分,其包含(1)5至100重量%的至少一种具有至少约50%伯羟基的天然油衍生的多元醇和(2)与天然油衍生的多元醇不同的足够的另外的多元醇 以制备100%,其中天然油衍生的多元醇的平均值为每分子1.5至3个羟基,当量为200至5000; 和(b)与羟基反应的交联组分。 此外,在基材表面上制备涂料,粘合剂,粘合剂或其组合的方法包括以下任意顺序:(a)混合粘合剂和组合物的交联组分以形成混合物,其中粘合剂组分包含(1 )5至100重量%的至少一种具有至少约50%伯羟基的天然油衍生的多元醇,和(2)与天然油衍生的多元醇不同的足够额外的多元醇以制备100%,其中天然油衍生的多元醇具有平均值 每个分子为1.5至3个羟基,当量为200至5000; 和(b)在所述表面上施加一层所述混合物。 本发明包括由本发明的任何组合物制备的涂料,粘合剂,粘合剂及其组合,通过本发明的方法涂覆的基材或使用本发明的组合物涂覆的基材和包括层压材料的制品,其包括涂料,粘合剂,粘合剂或组合 的本发明。