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1. 发明申请

US20170253481A1 PRODUCTION OF AMMONIA MAKE-UP SYNGAS WITH CRYOGENIC PURIFICATION 审中-公开
公开(公告)号：US20170253481A1
公开(公告)日：2017-09-07
申请号：US15601690
申请日：2017-05-22
申请人： Casale SA
发明人： Ermanno FILIPPI , Geoffrey Frederick SKINNER
IPC分类号： C01B3/34 , C01B3/38 , F25J3/04 , C01B3/50 , C01B3/58 , F25J3/02 , C01B3/02 , C01B3/48
CPC分类号： C01B3/34 , C01B3/025 , C01B3/38 , C01B3/382 , C01B3/48 , C01B3/506 , C01B3/586 , C01B2203/0216 , C01B2203/0233 , C01B2203/0283 , C01B2203/0445 , C01B2203/046 , C01B2203/047 , C01B2203/0475 , C01B2203/068 , C01B2203/1241 , F25J3/0209 , F25J3/0219 , F25J3/0276 , F25J3/04539 , F25J3/04587 , F25J2200/02 , F25J2200/74 , F25J2210/20 , F25J2210/42 , F25J2270/904 , F25J2290/80 , Y02C10/12 , Y10T29/49716
摘要： A process and a related equipment for making ammonia make-up synthesis gas are disclosed, where: a hydrocarbon feedstock is reformed obtaining a raw ammonia make-up syngas stream; said raw syngas is purified in a cryogenic purification section refrigerated by a nitrogen-rich stream produced in an air separation unit; the nitrogen-rich stream at output of said cryogenic section is further used for adjusting the hydrogen/nitrogen ratio of the purified make-up syngas; an oxygen-rich stream is also produced in said air separation unit and is fed to the reforming section.

2. 发明申请

US20170009983A1 Polygeneration Production of Power and Fertilizer Through Emissions Capture 审中-公开
标题翻译：电力和化肥通过排放捕获生产多联产
公开(公告)号：US20170009983A1
公开(公告)日：2017-01-12
申请号：US15216432
申请日：2016-07-21
申请人： Grannus LLC
发明人： James Kelly Merritt, JR.
IPC分类号： F23L7/00 , C01B3/04 , C01B3/58 , F23J15/02 , C01C1/04 , C07C273/10 , B01D53/00 , B01D53/14 , C01B3/36 , C01B3/02
CPC分类号： F23L7/007 , B01D53/002 , B01D53/1431 , B01D53/1475 , C01B3/025 , C01B3/042 , C01B3/36 , C01B3/583 , C01B3/586 , C01B2203/025 , C01B2203/0415 , C01B2203/044 , C01B2203/0445 , C01B2203/047 , C01B2203/0475 , C01B2203/0495 , C01B2203/068 , C01B2203/1235 , C01B2203/147 , C01C1/0488 , C07C273/10 , F23J15/02 , F23J2219/70 , Y02E60/364 , Y02P20/52 , Y02P30/30
摘要： Method for the production of ammonia, and optionally urea, from a flue gas effluent from an oxy-fired process, wherein the production of ammonia and optionally urea includes a net power production. Also provided is a method to effect cooling in an oxy-fired process with air separation unit exit gases utilizing either closed or open cooling loop cycles.
摘要翻译：用于从来自氧烧制方法的烟道气流出物生产氨和任选的尿素的方法，其中生产氨和任选的尿素包括净功率产生。还提供了使用空气分离单元出口气体在使用封闭或开放冷却循环循环的情况下在氧烧制过程中进行冷却的方法。

3. 发明申请

US20160121289A1 REACTOR 有权
标题翻译：反应堆
公开(公告)号：US20160121289A1
公开(公告)日：2016-05-05
申请号：US14787120
申请日：2014-04-17
申请人： JOHNSON MATTHEY PUBLIC LIMITED COMPANY
发明人： Gary Bevan COMBES
IPC分类号： B01J8/06 , C01B3/16 , B01J8/02
CPC分类号： B01J8/065 , B01D53/0431 , B01J8/0214 , B01J8/06 , B01J2208/00884 , B01J2208/021 , C01B3/16 , C01B3/586 , C01B2203/0283 , C01B2203/0445 , C01B2203/047
摘要： A reactor includes: a shell with first and second ends, an fluid inlet at the first end for receiving a process fluid, and an outlet at the second end for discharging a reacted process fluid, and a plurality of elongate containment units within the shell for containing a particulate catalyst or sorbent, each containment unit including two perforate members defining a space in which the particulate catalyst or sorbent may be placed, the perforate members mounted between two fluid-impermeable end members, wherein one end member extends across the containment unit to provide a closed end and the other end member closes the space thereby providing an open end through which a process fluid may enter or exit the containment unit, and a header assembly connected to the open ends of the containment units and either the fluid inlet or fluid outlet. A process using the reactor is also described.
摘要翻译：反应器包括：具有第一和第二端的壳体，在第一端处的流体入口用于接收过程流体，以及在第二端处的出口用于排放反应的过程流体，以及在壳体内的多个细长的容纳单元，每个容纳单元包括两个穿孔构件，其限定可以放置颗粒状催化剂或吸附剂的空间，所述穿孔构件安装在两个不透液体的端部构件之间，其中一个端部构件延伸穿过容纳单元至提供封闭端，而另一端构件封闭空间，从而提供开口端，通过该开口端，过程流体可以通过该开口端进入或离开容纳单元，以及连接到容纳单元的开口端的集管组件以及流体入口或流体出口。还描述了使用反应器的方法。

4. 发明申请

US20150291438A1 Polygeneration Production of Power and Fertilizer Through Emissions Capture 审中-公开
标题翻译：电力和化肥通过排放捕获生产多联产
公开(公告)号：US20150291438A1
公开(公告)日：2015-10-15
申请号：US14406020
申请日：2013-06-21
申请人： Grannus LLC
发明人： James Kelly Merritt
IPC分类号： C01C1/04 , C01B3/36 , C01B3/02
CPC分类号： F23L7/007 , B01D53/002 , B01D53/1431 , B01D53/1475 , C01B3/025 , C01B3/042 , C01B3/36 , C01B3/583 , C01B3/586 , C01B2203/025 , C01B2203/0415 , C01B2203/044 , C01B2203/0445 , C01B2203/047 , C01B2203/0475 , C01B2203/0495 , C01B2203/068 , C01B2203/1235 , C01B2203/147 , C01C1/0488 , C07C273/10 , F23J15/02 , F23J2219/70 , Y02E60/364 , Y02P20/52 , Y02P30/30
摘要： Method for the production of ammonia, and optionally urea, from a flue gas effluent from an oxygen-fired, process, wherein the production of ammonia and optionally urea includes a net power production. Also provided is a method to effect cooling in an oxygen-fired process with air separation unit exit gases utilizing either closed or open cooling loop cycles.
摘要翻译：用于从来自氧燃烧方法的烟道气流出物生产氨和任选的尿素的方法，其中氨和任选的尿素的生产包括净功率产生。还提供了利用空气分离单元出口气体利用封闭或开放冷却循环循环来在氧气烧制过程中进行冷却的方法。

5. 发明申请

US20150246347A1 CO-SELECTIVE METHANATION CATALYST 有权
标题翻译：选择性甲烷催化剂
公开(公告)号：US20150246347A1
公开(公告)日：2015-09-03
申请号：US14425589
申请日：2013-08-26
申请人： University of Yamanashi
发明人： Toshihiro Miyao , Kazutoshi Higashiyama , Weihua Shen , Hisao Yamashita , Noboru Hashimoto , Shigehito Deki , Masahiro Watanabe
IPC分类号： B01J29/76 , B01J23/847 , B01J35/04 , B01J35/00
CPC分类号： B01J29/76 , B01J21/063 , B01J21/08 , B01J23/755 , B01J23/78 , B01J23/8472 , B01J29/0308 , B01J29/0333 , B01J35/0006 , B01J35/04 , B01J35/1014 , B01J35/1061 , B01J37/03 , B01J37/04 , C01B3/586 , C01B37/02 , C01B2203/0233 , C01B2203/0445 , C01B2203/047 , C01B2203/066 , C01B2203/1258 , C10L3/08 , H01M8/0612 , H01M8/0668 , Y02E60/50
摘要： The first object is to increase the life of a selective CO methanation catalyst, and the second object is to enhance the CO removal rate of a selective CO methanation catalyst to reduce the outlet CO concentration in a wide temperature range. Provided a selective CO methanation catalyst including a supported metal catalyst which selectively methanizes CO in a hydrogen-rich gas containing CO and CO2 and a coating layer which covers a surface of the supported metal catalyst, has many pores, and is configured to reduce a CO concentration on the surface of the supported metal catalyst.
摘要翻译：第一个目的是增加选择性CO甲烷化催化剂的寿命，第二个目的是提高选择性CO甲烷化催化剂的CO去除速率，以便在宽温度范围内降低出口CO浓度。提供一种选择性CO甲烷化催化剂，其包括负载金属催化剂，其选择性地使含CO和CO 2的富氢气体中的CO甲烷化，并且覆盖所述负载型金属催化剂的表面的涂层具有许多孔，并且被配置为减少CO 负载金属催化剂表面的浓度。

6. 再颁专利

USRE45317E1 Rapid solar-thermal conversion of biomass to syngas 有权
标题翻译：将生物质快速太阳热转化为合成气
公开(公告)号：USRE45317E1
公开(公告)日：2015-01-06
申请号：US13855617
申请日：2013-04-02
申请人： The Regents of the University of Colorado
发明人： Alan W. Weimer , Christopher Perkins , Dragan Mejic , Paul Lichty
IPC分类号： B01J7/00 , C01B3/36 , C01B6/24
CPC分类号： C10B19/00 , B01J19/127 , C01B3/10 , C01B3/12 , C01B3/586 , C01B2203/0283 , C01B2203/0445 , C01B2203/047 , C10B53/02 , C10J3/485 , C10J3/506 , C10J2300/0916 , C10J2300/092 , C10J2300/0973 , C10J2300/0983 , C10J2300/1284 , C10J2300/1292 , C22B5/10 , C22B5/12 , C22B7/001 , F24S90/00 , Y02E10/40 , Y02E50/14 , Y02E50/32 , Y02E60/36 , Y02P10/122 , Y02P10/214 , Y02P20/134 , Y02P20/145
摘要： Methods for carrying out high temperature reactions such as biomass pyrolysis or gasification using solar energy. The biomass particles are rapidly heated in a solar thermal entrainment reactor. The residence time of the particles in the reactor can be 5 seconds or less. The biomass particles may be directly or indirectly heated depending on the reactor design. Metal oxide particles can be fed into the reactor concurrently with the biomass particles, allowing carbothermic reduction of the metal oxide particles by biomass pyrolysis products. The reduced metal oxide particles can be reacted with steam to produce hydrogen in a subsequent process step.
摘要翻译：使用太阳能进行生物质热解或气化的高温反应的方法。生物质颗粒在太阳能热夹带反应器中快速加热。颗粒在反应器中的停留时间可以为5秒或更短。生物质颗粒可以根据反应器设计直接或间接加热。金属氧化物颗粒可以与生物质颗粒同时进料到反应器中，通过生物质热解产物使金属氧化物颗粒发生碳热还原。还原的金属氧化物颗粒可以与蒸汽反应以在随后的工艺步骤中产生氢。

7. 发明授权

US08927772B2 Tertiary amine preparation process 有权
标题翻译：叔胺制备方法
公开(公告)号：US08927772B2
公开(公告)日：2015-01-06
申请号：US13976365
申请日：2011-12-27
申请人： Masahiko Watanabe , Gosuke Tateno , Hirofumi Mizukoshi
发明人： Masahiko Watanabe , Gosuke Tateno , Hirofumi Mizukoshi
IPC分类号： C07C209/16 , C01B3/58
CPC分类号： C07C209/16 , C01B3/586 , C01B2203/0445 , C01B2203/047 , C07C211/08
摘要： The present invention relates to a process for producing a tertiary amine, including the following steps (1) and (2):Step (1); introducing an alcohol having 1 to 36 carbon atoms and a raw amine represented by the following general formula (I) into a first reaction vessel to react with each other in the presence of a catalyst and hydrogen, and then continuing the reaction while discharging water produced in the reaction and a hydrogen-containing gas out of a reaction system in the first reaction vessel: R1R2NH (I) wherein R1 and R2 are each independently a hydrogen atom or a hydrocarbon group having 1 to 36 carbon atoms; and Step (2): introducing the hydrogen-containing gas discharged from the first reaction vessel into a second reaction vessel to reduce an amount of carbon monoxide contained in the hydrogen-containing gas, and then introducing a part or whole of the hydrogen-containing gas into the first reaction vessel.
摘要翻译：本发明涉及一种制备叔胺的方法，包括以下步骤（1）和（2）：步骤（1）; 将具有1至36个碳原子的醇和由以下通式（I）表示的原料胺引入第一反应容器中以在催化剂和氢气存在下彼此反应，然后在排出水的同时继续反应在第一反应容器中的反应体系中含有氢的气体：R1R2NH（I）其中R1和R2各自独立地为氢原子或具有1至36个碳原子的烃基; 和步骤（2）：将从第一反应容器排出的含氢气体引入第二反应容器中以减少含氢气体中所含的一氧化碳的量，然后将含氢气体的一部分或全部气体进入第一反应容器。

8. 发明授权

US08636828B2 Hydrogen purification membranes, components and fuel processing systems containing the same 失效
标题翻译：氢气净化膜，组件和含有相同的燃料处理系统
公开(公告)号：US08636828B2
公开(公告)日：2014-01-28
申请号：US13598295
申请日：2012-08-29
申请人： David J. Edlund , William A. Pledger , R. Todd Studebaker
发明人： David J. Edlund , William A. Pledger , R. Todd Studebaker
IPC分类号： B01D53/22 , C01B3/26
CPC分类号： C01B3/32 , B01D53/22 , B01D53/229 , B01D63/06 , B01D63/08 , B01D69/02 , B01D2313/20 , B01D2313/22 , B01D2313/42 , B01D2325/22 , B01J8/006 , B01J8/009 , B01J8/0257 , B01J8/0285 , B01J8/04 , B01J8/0465 , B01J8/0469 , B01J8/0496 , B01J8/062 , B01J8/067 , B01J19/2475 , B01J2208/00061 , B01J2208/00088 , B01J2208/00106 , B01J2208/00132 , B01J2208/00141 , B01J2208/00256 , B01J2208/00309 , B01J2208/00371 , B01J2208/00415 , B01J2208/00495 , B01J2208/00504 , B01J2208/0053 , B01J2208/00539 , B01J2208/00548 , C01B3/323 , C01B3/38 , C01B3/382 , C01B3/384 , C01B3/503 , C01B3/505 , C01B3/586 , C01B2203/0227 , C01B2203/0233 , C01B2203/0244 , C01B2203/0261 , C01B2203/0283 , C01B2203/0405 , C01B2203/041 , C01B2203/044 , C01B2203/0445 , C01B2203/047 , C01B2203/0475 , C01B2203/066 , C01B2203/0811 , C01B2203/0816 , C01B2203/0822 , C01B2203/0827 , C01B2203/0844 , C01B2203/085 , C01B2203/0866 , C01B2203/0877 , C01B2203/0883 , C01B2203/0888 , C01B2203/1011 , C01B2203/1041 , C01B2203/1058 , C01B2203/1076 , C01B2203/1217 , C01B2203/1223 , C01B2203/1235 , C01B2203/1241 , C01B2203/1247 , C01B2203/1258 , C01B2203/1276 , C01B2203/1288 , C01B2203/142 , C01B2203/146 , C01B2203/1604 , C01B2203/1628 , C01B2203/1633 , C01B2203/1657 , C01B2203/1676 , C01B2203/169 , C01B2203/1695 , C01B2203/82 , H01M8/0612 , H01M8/0618 , H01M8/0631 , H01M8/0687 , Y02P20/128 , Y02P20/129 , Y10S48/05
摘要： Hydrogen-producing fuel processing systems, hydrogen purification membranes, hydrogen purification devices, fuel processing and fuel cell systems that include hydrogen purification devices, and methods for operating the same. In some embodiments, operation of the fuel processing system is initiated by heating at least the reforming region of the fuel processing system to at least a selected hydrogen-producing operating temperature. In some embodiments, an electric heater is utilized to perform this initial heating. In some embodiments, use of the electric heater is discontinued after startup, and a burner or other combustion-based heating assembly combusts a fuel to heat at least the hydrogen producing region, such as due to the reforming region utilizing an endothermic catalytic reaction to produce hydrogen gas.
摘要翻译：氢气生产燃料处理系统，氢气净化膜，氢气净化装置，燃料处理和包括氢气净化装置的燃料电池系统及其操作方法。在一些实施例中，燃料处理系统的操作是通过将至少燃料处理系统的重整区域加热至至少选择的产氢操作温度而启动的。在一些实施例中，使用电加热器来执行该初始加热。在一些实施例中，在启动之后停止使用电加热器，并且燃烧器或其它基于燃烧的加热组件燃烧燃料至少加热产氢区域，例如由于重整区域利用吸热催化反应产生氢气。

9. 发明申请

US20120219870A1 HYDROGEN-PURIFICATION APPARATUS AND FUEL-CELL SYSTEM USING SAME 有权
标题翻译：使用相同的氢气净化装置和燃料电池系统
公开(公告)号：US20120219870A1
公开(公告)日：2012-08-30
申请号：US13503606
申请日：2011-08-24
申请人： Tomoyuki Nakajima , Hidenobu Wakita , Seiji Fujihara , Yukimune Kani
发明人： Tomoyuki Nakajima , Hidenobu Wakita , Seiji Fujihara , Yukimune Kani
IPC分类号： H01M8/06 , G05B1/11 , B01J8/00
CPC分类号： H01M8/0662 , C01B3/38 , C01B3/48 , C01B3/58 , C01B3/586 , C01B2203/0233 , C01B2203/0283 , C01B2203/0445 , C01B2203/066 , C01B2203/0833 , C01B2203/0838 , C01B2203/1076 , C01B2203/1088 , C01B2203/16 , Y02E60/50
摘要： A hydrogen purifier (100) includes: a shift conversion catalyst (5a) which reduces, through a shift reaction, carbon monoxide contained in a hydrogen-containing gas; and a methanation catalyst (6a) which reduces, through a methanation reaction, carbon monoxide contained in the hydrogen-containing gas that has passed through the shift conversion catalyst (5a). The shift conversion catalyst (5a) and the methanation catalyst (6a) are heat exchangeable with each other via a first partition wall (8), and a flow direction of the hydrogen-containing gas that passes through the shift conversion catalyst (5a) is opposite to a flow direction of the hydrogen-containing gas that passes through the methanation catalyst (6a).
摘要翻译：氢净化器（100）包括：通过变换反应将包含在含氢气体中的一氧化碳减少的换档转换催化剂（5a）和甲烷化催化剂（6a），其通过甲烷化反应将通过所述换算转化催化剂（5a）的含氢气体中所含的一氧化碳还原。换档催化剂（5a）和甲烷化催化剂（6a）可以通过第一分隔壁（8）彼此热交换，并且通过换流转换催化剂（5a）的含氢气体的流动方向为与通过甲烷化催化剂（6a）的含氢气体的流动方向相反。

10. 发明申请

US20120108683A1 CATALYST FOR SELECTIVE METHANIZATION OF CARBON MONOXIDE 有权
标题翻译：一氧化碳选择性甲基化催化剂
公开(公告)号：US20120108683A1
公开(公告)日：2012-05-03
申请号：US13285045
申请日：2011-10-31
申请人： Jochen STEINER , Markus Hölzle , Heiko Urtel
发明人： Jochen STEINER , Markus Hölzle , Heiko Urtel
IPC分类号： C07C27/00
CPC分类号： B01J23/63 , B01J23/002 , B01J23/462 , B01J37/0009 , C01B3/586 , C01B2203/0205 , C01B2203/0283 , C01B2203/0445 , C01B2203/047 , C01B2203/066 , C07C1/0435 , C07C1/26 , C07C17/10 , C07C2529/40 , H01M8/0668 , C07C9/00 , C07C19/075
摘要： The invention relates to a catalytic composition and to a process for selective methanization of carbon monoxide in hydrogen- and carbon dioxide-containing streams, wherein the active component used is ruthenium and the support material is a lanthanum-cerium-zirconium oxide, and to the use thereof in fuel cell systems.
摘要翻译：本发明涉及一种催化组合物和一种含氢和二氧化碳气流中一氧化碳选择性甲烷化的方法，其中使用的活性组分是钌，载体材料是镧 - 铈 - 氧化锆，在燃料电池系统中的应用。

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