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    • 3. 发明授权
    • Resin compositions for coating
    • 用于涂层的树脂组合物
    • US6121386A
    • 2000-09-19
    • US101851
    • 1998-07-20
    • Yoshihiro OhtsukaYoshihiro Oshino
    • Yoshihiro OhtsukaYoshihiro Oshino
    • C08G59/34C08J7/04C09D163/00C09D163/08C08G65/32
    • C08G59/027C08J7/047C09D163/08C08J2463/00
    • A resin composition for coating suitable as, for example, a surface coating material capable of improving the coatability, etc., of olefin resin films, etc., which contains an epoxidized block copolymer (A) and an organic compound (B) carrying a functional group reacting with an epoxy group and having a number-average molecular weight of from 150 to 150,000, wherein the weight ratio (A)/(A+B) ranges from 1/100 to 99/100. Another resin composition for coating which contains an epoxidized block copolymer (A), an organic compound (B) carrying a functional group reacting with an epoxy group and having a number-average molecular weight of from 150 to 150,000, and an epoxy ring opening promoter (C), wherein the weight ratio (A)/(A+B) ranges from 1/100 to 99/100 and the content of the above component (C) ranges from 0.1 to 10 parts by weight per 100 parts by weight of (A+B).
    • PCT No.PCT / JP96 / 03386 Sec。 371日期:1998年7月20日 102(e)1998年7月20日PCT PCT 1996年11月19日PCT公布。 公开号WO98 / 22546 日期1998年5月28日一种涂料用树脂组合物,适合作为例如能够改善包含环氧化嵌段共聚物(A)和有机化合物(A)的烯烃树脂膜等的涂布性等的表面涂料, B)携带与环氧基反应并且数均分子量为150〜150,000的官能团,其中重量比(A)/(A + B)为1/100至99/100。 另一种涂料用树脂组合物,其含有环氧化嵌段共聚物(A),带有与环氧基反应的数均分子量为150〜150,000的官能团的有机化合物(B)和环氧化开环促进剂 (C)中,其中,重量比(A)/(A + B)为1/100〜99/100,上述成分(C)的含量为0.1〜10重量份,相对于100重量份 (A + B)。
    • 5. 发明授权
    • Liquid ebonite anticorrosive coating for metals
    • 金属液体硬橡胶防腐涂料
    • US5766687A
    • 1998-06-16
    • US754216
    • 1996-11-20
    • Leonid Rappoport
    • Leonid Rappoport
    • B05D7/24B05D3/02B32B9/00B32B9/04B32B15/08C08G59/50C08G59/58C09D115/00C09D163/08C23C26/00
    • C09D115/00C08G59/50C08G59/58C09D163/08
    • A mixture comprising epoxidized liquid rubbers, amine hardeners and sulfur applied to a metal and cured produces a coating that is highly durable and provides strong anticorrosive protection to the metal. The amine hardeners serve to activate and dissolve the sulfur, speed up the curing time, and also bond to the rubbers to create a continuous molecular matrix. The activated sulfur also links the rubber molecules together, as well as anchoring the polymer matrix to the metal substrate via chemical bonds. In a preferred embodiment, the formulation also includes two types of accelerators which act synergistically to further reduce the curing time to less than one hour. The addition of micronized aluminum oxides provides increased uniformity of heating during curing and results in a more uniform coating. The addition of calcium oxide together with the presence of amines and aluminum oxide provides a complete absorption of acidic gases produced during curing. The addition of high molecular butadiene nitrile rubber increases the coatings impact resistance, low-temperature flexibility, and adhesion.
    • 包含环氧化液体橡胶,胺硬化剂和施加到金属上的硫并且固化的混合物产生高度耐用的涂层,并为金属提供强烈的防腐蚀保护。 胺固化剂用于活化和溶解硫,加速固化时间,并且还结合到橡胶上以产生连续的分子基质。 活化的硫还将橡胶分子连接在一起,以及通过化学键将聚合物基质锚定到金属基底上。 在优选的实施方案中,制剂还包括两种类型的促进剂,其协同作用以进一步将固化时间减少至少于1小时。 添加微粉化的氧化铝在固化期间提供加热的均匀性,并且导致更均匀的涂层。 加入氧化钙以及胺和氧化铝的存在提供了在固化期间产生的酸性气体的完全吸收。 添加高分子丁二烯丁腈橡胶增加了涂料的耐冲击性,低温柔韧性和粘附性。