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序号	专利名	申请号	申请日	公开（公告）号	公开（公告）日	发明人
101	GRAPHENE FIBER MANUFACTURED BY JOULE HEATING AND METHOD OF MANUFACTURING THE SAME	US16651806	2018-09-28	US20200248337A1	2020-08-06	Tae Hee HAN; Sung Hyun NOH
A method of manufacturing a graphene fiber is provided. The method includes preparing a source solution including graphene oxide, supplying the source solution into a coagulation solution to form a graphene oxide fiber, reducing the graphene oxide fiber to form a primary graphene fiber, and Joule-heating the primary graphene fiber to form a secondary graphene fiber.
102	CARBON NANOFIBER CATALYST SUBSTRATE PRODUCTION PROCESS	US16143532	2018-09-27	US20190036129A1	2019-01-31	Mark S. Sulek; Kevin James Rhodes; James A. Adams; James Waldecker
A method of forming a fuel cell catalyst layer. The method includes spinning a composition including a base polymer, a solvent, and a catalyst precursor into a non-woven fiber mat having the catalyst precursor embedded therein. The method further includes carbonizing the non-woven fiber mat to form a carbon fiber substrate. The method also includes reacting the catalyst precursor to form a plurality of individual catalyst particles embedded in the carbon fiber substrate.
103	Carbon Nanofiber Catalyst Substrate	US14991366	2016-01-08	US20170200955A1	2017-07-13	Mark S. SULEK; Kevin James RHODES; James A. ADAMS; James WALDECKER
Fuel cell catalyst layers and methods of making the same are disclosed. The fuel cell catalyst layer may include a catalyst substrate including a non-woven mat of carbon nanofibers, each having a surface portion and a bulk portion bounded by the surface portion. A plurality of catalyst particles may be included in the catalyst layer, at least a first portion of which are fully embedded within the bulk portion of each of the carbon nanofibers. The method may include spinning a composition including a base polymer, a solvent, and a catalyst precursor into a non-woven fiber mat having the catalyst precursor embedded therein. The mat may then be carbonized to form a carbon fiber substrate and the catalyst precursor may be reacted to form catalyst particles embedded in the substrate. Embedding the catalyst particles may anchor them within the substrate and inhibit them from migrating during fuel cell operation.
104	Highly electroconductive graphite continuous filament and process for preparation thereof	US12840	1987-02-10	US4808475A	1989-02-28	Kiichiro Matsumura; Akio Takahashi; Jun Tsukamoto
A highly electroconductive graphite continuous filament is described, which is composed of a carbon filament as a substrate and a graphite layer having a layer spacing d (0,0,2) of not larger than 3.363 angstroms as an outer skin layer The graphite continuous filament is prepared by depositing easily graphitizable carbon on the substrate and heat-treating the carbon-deposited substrate at a temperature of at least 2,500.degree. C.
105	Process for disposing of carbon fibers	US378980	1982-05-17	US4411880A	1983-10-25	Christopher B. Brogna
A simple and efficient process is provided for disposing of easily airborne carbon fibers by subjecting them to an aqueous solution of an alkali metal or alkaline earth metal hypohalogenite at an elevated temperature for a period of time sufficient to substantially destroy the fibrous configuration of said fibers. In a preferred embodiment, carbon fibers are contacted with a solution of sodium hypochlorite (approximately 5 to 6 percent active chlorine concentration by weight based on the weight of the solution) at a temperature of between about 50.degree. and about 60.degree. C. for between about 1 and about 12 hours.
106	Apparatus for vapor deposition on tubular substrate	US822824	1977-08-08	US4134360A	1979-01-16	Ronald Fisher; Norman Smith
In the production of all-carbon composite articles by the cracking of a hydrocarbon gas to deposit carbon on a fibrous carbon substrate the substrate is held in the furnace by a ram movable in the furnace to engage the substrate. The gas is introduced inside the annular substrate and evacuated at a position spaced laterally from the substrate so that the gas is forced to disperse through the substrate wall.
107	Method of making a fibre of aluminium phosphate	US516777	1974-10-21	US4008299A	1977-02-15	James Derek Birchall; John Edward Cassidy
A method is provided for preparing a fibre from a solution of a halogen-containing complex phosphate of aluminium. The complex contains at least one chemically-bound molecule of a hydroxy compound R-OH, where R is a hydrogen atom or an organic group. The complex is dissolved in water or an organic solvent. The solution is fibrized and then dried to produce the fibre.
108	Carbon-boron surfaced carbon filament	US22895372	1972-02-24	US3867191A	1975-02-18	GALASSO FRANCIS S; VELTRI RICHARD D
A high strength composite filament suitable for use as a reinforcement in metal matrices comprises a filamentary carbon substrate having a continuous essentially amorphous carbon alloy coating adhered thereto, the coating consisting essentially of approximately 43-60 atomic percent carbon, remainder boron.
109	Carbon fiber reinforced nickel matrix composite having an intermediate layer of metal carbide	US27026072	1972-07-10	US3807996A	1974-04-30	SARA R
Composite articles having a nickel base metal matrix reinforced with a plurality of high strength, high modulus carbon fibers having a thin, intermediate layer of a metal carbide disposed upon at least a portion of the fiber surfaces. Such composites are characterized by improved thermal cycling characteristics and are produced by coating a plurality of carbon fibers first with a thin, continuous layer of nickel, and then with a second thin, continuous overcoating of a metal capable of diffusing through the nickel coating and reacting with carbon to form a metal carbide; and then hot pressing the dual-coated fibers for a time and at a temperature and pressure sufficient to bond them together and diffuse at least a portion of the carbide-forming metal surface layer through the nickel undercoating and effect reaction between said carbide-forming metal and said carbon fibers to produce a metal carbide coating on at least a portion of the surface of the fibers.
110	Bamboo-inspired nanostructure design for flexible, foldable and twistable energy storage devices	US15149631	2016-05-09	US09842707B2	2017-12-12	Yongming Sun; Yi Cui
A flexible all-solid state supercapacitor is provided that includes a first electrode and a second electrode, and a flexible nanofiber web, where the flexible nanofiber web connects the first electrode to the second electrode, where the flexible nanofiber web includes a plurality of flexible nanofibers, where the flexible nanofiber includes a hierarchal structure of macropores, mesopores and micropores through a cross section of the flexible nanofiber, where the mesopores and the micropores form a graded pore structure, where the macropores are periodically distributed along the flexible nanaofiber and within the graded pore structure.
111	Carbon nanotube mediated membrane extraction	US12437789	2009-05-08	US09169579B2	2015-10-27	Kamilah Hylton; Somenath Mitra
The present disclosure provides an improved membrane or substrate having carbon nanotubes introduced and/or immobilized therein, and an improved method for introducing and/or immobilizing carbon nanotubes in membranes or substrates. More particularly, the present disclosure provides for improved systems and methods for fabricating membranes or substrates having carbon nanotubes immobilized therein. In one embodiment, the present disclosure provides for systems and methods for introducing and/or immobilizing functionalized carbon nanotubes into the pore structure of a polymeric membrane or substrate, thereby dramatically improving the performance of the polymeric membrane or substrate. In exemplary embodiments, the present disclosure provides for systems and methods for the fabrication of nanotube immobilized membranes by incorporating CNTs in a membrane or substrate.
112	Three-dimensional nanotube structure	US10773004	2004-02-04	US20050169831A1	2005-08-04	Stephen Montgomery; William Berry; Ven Holalkere; Ravi Prasher
Embodiments of the invention provide a three-dimensional nanotube structure. For one embodiment, a connector molecule is created that has bonding sites capable of bonding with one end of an open-ended nanotube segment and bonding sites capable of bonding with the corresponding bonding sites of a plurality of other connector molecules. For one embodiment, the connector molecule is cone-shaped, with base of the cone determined so as to bond with the edge of the open-ended nanotube and the point of the cone comprising a single molecule capable of bonding with the corresponding molecules of two or more other connector molecules. In one embodiment, the three-dimensional nanotube structures are incorporated into a polymer matrix to form a composite polymer having improved thermal conductivity. For one embodiment, the composite polymer is used to form efficient and cost-effective heat dissipation devices.
113	Electrochemical method of surface treating carbon; carbon, in particular carbon fibers, treated by the method, and composite material including such fibers	US126791	1987-12-01	US4844781A	1989-07-04	Manuel Sanchez; Georges Desarmot; Blandine Barbier
The method is of the type in which carbon (3) is put into contact with a solution (2) of an amine compound in a bipolar solvent with the carbon being positively polarized relative to a cathode (5). According to the invention, the solvent is an organic compound, preferably an aprotic compound, having a high anode oxidation potential, and the solution is practically free from water.
114	Process of making a loosely formed non-woven mat of aligned carbon fibers	US941895	1986-12-15	US4816195A	1989-03-28	William P. Hettinger, Jr.; Larry D. Veneziano
A large number of melt blown carbon fibers from petroleum pitch through a multi-orifice die under continuous formation, are fed onto the periphery of a continuously moving endless conveyor surface whose surface speed is matched to the linear velocity of the melt blown carbon fibers to cause the fibers to be deposited in parallel alignment on the conveyor surface and to be maintained in fiber axial alignment to form a non-woven mat of aligned carbon fibers. The speed of the conveyor surface may be slightly less than the linear speed of the fibers to form a loose fiber mat to facilitate subsequent fiber oxidation and carbonization by permitting gas flow through the aligned fiber mat. The endless conveyor may comprise a cylindrical drum whose surface is perforated to facilitate gas flow and oxidation of the carbon fibers subsequent to non-woven mat formation. The drum circumference may be set to the desired fiber length and the mat severed transversely to permit removal of the aligned fibers of desired length in bundle form.
115	Method for producing a carbon filament and derivatives thereof	US299604	1981-09-04	US4435375A	1984-03-06	Shohei Tamura; Mizuka Sano; Hiroo Inokuchi; Koshiro Toriumi; Naoki Sato
A novel type of carbon filaments grow from a purified graphite material when the purified graphite material is heated in a plasma. The carbon filaments thus obtained can be converted into softer graphite filaments. Both the carbon filaments and the graphite filaments as such are extremely useful due to their excellent mechanical strengths. In addition, from each of them, intercalation compounds with an alkali metal can be obtained, which are useful not only as a highly conductive material but also as a catalyst for various reactions.
116	Process for the surface modification of carbon fibers	US222790	1981-01-05	US4374114A	1983-02-15	Sang N. Kim; Paul E. McMahon; John P. Riggs; John M. Rhodes
An improved continuous hot gas surface modification process for carbon fibers is provided. The carbon fibers undergoing such processing are passed for a relatively brief residence time through a surface treatment zone to which continuously is fed nitrogen dioxide and air under conditions which have been found to produce a surprisingly effective surface modification. The resulting carbon fibers exhibit a significantly enhanced surface area and an improved ability to bond to a resinous matrix material while retaining a substantial portion of the tensile strength originally exhibited. When incorporated in a resinous matrix material, a fiber reinforced composite article of enhanced interlaminar shear strength is formed.
117	Treatment of carbon fibre	US948293	1978-08-29	US4243646A	1981-01-06	David J. Lind; Valerie J. Coffey; Joyce Hallam
A method of treating carbon fibre in which the fibre is subjected to a surface removal step followed by a surface deactivation step. The surface deactivation step comprises either removing at least some of the functional groups on the surface of the fibre or rendering those functional groups incapable of forming a chemical bond with a resin matrix material. When such treated fibres are incorporated in a resin matrix, the resultant composite material is provided with enhanced strength properties when compared with similar composite materials containing untreated carbon fibres.
118	Phosphates	US517236	1974-10-21	US3960592A	1976-06-01	James Derek Birchall; John Edward Cassidy
There is provided a composition suitable for use as a coating composition which contains a halogen-containing complex phosphate of aluminum, other than a phosphate ester, dissolved in an organic solvent. The complex contains at least one chemically-bound molecule of an alcohol having from one to 10 carbon atoms. The complex is prepared by interacting an aluminum compound, such as aluminum halides, with an alcohol containing one to 10 carbon atoms and with phosphoric acid.
119	CNT FILAMENT FORMATION BY BUOYANCY INDUCED EXTENSIONAL FLOW	PCT/US2021/025931	2021-04-06	WO2021207170A1	2021-10-14	GAILUS, David
The present disclosure provides a method for producing elongated non-entangled nanotube filaments using a vertical upward flow floating catalyst chemical vapor deposition system.
120	HIGH TEMPERATURE, LOW OXIDATION STABILIZATION OF PITCH FIBERS	PCT/US1998/006668	1998-04-01	WO98045386A1	1998-10-15
The present invention provides a process for thermosetting pitch fibers in reduced times, at low concentrations of oxygen and at higher temperatures than previously possible. Additionally, the present invention provides a pitch fiber which has an oxygen diffusion rate to the center of the fiber which is competitive with the rate of oxidation at the fiber's surface. Further, the present invention provides a high density pitch fiber batt which thermosets without loss of fiber structure.

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