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71. 发明授权

US07935517B2 Nanospearing for molecular transportation into cells 有权
标题翻译：纳米粒子用于分子运输到细胞中
公开(公告)号：US07935517B2
公开(公告)日：2011-05-03
申请号：US11233481
申请日：2005-09-22
申请人： Dong Cai , David L. Carnahan
发明人： Dong Cai , David L. Carnahan
IPC分类号： C12M1/42
CPC分类号： C12N15/89 , C12M35/02 , C12N15/87 , Y10S977/746 , Y10S977/748
摘要： A nanostructured molecular delivery vehicle comprising magnetic materials and configured to receive passenger biomolecules. The application of a an appropriate magnetic field having a gradient orients and drives the vehicle into a biological target, which may comprise cells, cell masses, tissue slices, tissues, etc. Under the control of the magnetic field, these vehicles can penetrate cell membranes. Then, the biomolecules carried by the vehicle can be released into the cells to perform their functions. Using this “nanospearing” technique, unprecendented high transfection efficiency has been achieved in several difficult-to-transfect cells. These include, but are not limited to, Bal 17 cells, ex vivo B cells, primary cultured cortical neurons, etc. This method advances the state of the art, providing an improved technique for the introduction of exogenous molecules to cells, with the clinical applications including, but not being limited to, drug delivery, gene therapy, vaccination, etc.
摘要翻译：纳米结构分子递送载体，其包含磁性材料并且构造成接收乘客生物分子。施加具有梯度的合适的磁场使得车辆进入生物靶，其可以包括细胞，细胞块，组织切片，组织等。在磁场的控制下，这些载体可以穿透细胞膜。然后，车辆携带的生物分子可以释放到细胞中以发挥其功能。使用这种“纳米级”技术，在几个难以转染的细胞中已经实现了非常重要的高转染效率。这些方法包括但不限于Bal 17细胞，离体B细胞，原代培养的皮质神经元等。该方法改进了现有技术，提供了一种用于将外源性分子引入细胞的改进技术，其中临床应用包括但不限于药物递送，基因治疗，疫苗接种等

72. 发明申请

US20110086781A1 METHOD FOR FORMING COMPOSITES OF SUB-ARRAYS OF FULLERENE NANOTUBES 有权
标题翻译：形成富勒烯纳米颗粒亚系的复合材料的方法
公开(公告)号：US20110086781A1
公开(公告)日：2011-04-14
申请号：US11508092
申请日：2006-08-22
申请人： Richard E. Smalley , Daniel T. Colbert , Hongjie Dai , Jie Liu , Andrew G. Rinzler , Jason H. Hafner , Ken Smith , Ting Guo , Pavel Nikolaev , Andreas Thess
发明人： Richard E. Smalley , Daniel T. Colbert , Hongjie Dai , Jie Liu , Andrew G. Rinzler , Jason H. Hafner , Ken Smith , Ting Guo , Pavel Nikolaev , Andreas Thess
IPC分类号： C40B50/18 , B82Y30/00
CPC分类号： G11C13/025 , B01J19/081 , B01J19/087 , B01J19/10 , B01J19/121 , B01J19/126 , B01J19/129 , B01J21/185 , B01J23/74 , B01J23/755 , B01J23/8913 , B01J37/0238 , B01J37/349 , B01J2219/00078 , B01J2219/0892 , B82B3/00 , C01B32/152 , C01B32/162 , C01B32/17 , C01B2202/02 , D01F9/12 , D01F9/127 , D21H27/00 , G11B9/1418 , G11B9/1445 , G11B9/1472 , G11B9/149 , G11C13/0014 , G11C13/0019 , G11C2213/16 , G11C2213/71 , G11C2213/81 , H01G9/2059 , H01L31/0352 , H01L31/06 , H01L31/18 , H01M4/133 , H01M4/525 , H01M4/583 , H01M4/587 , H01M4/625 , H01M10/0525 , Y02E10/542 , Y02E60/122 , Y02P70/521 , Y02P70/54 , Y10S977/70 , Y10S977/742 , Y10S977/745 , Y10S977/748 , Y10S977/75 , Y10S977/753 , Y10S977/789 , Y10S977/842 , Y10S977/843 , Y10S977/845 , Y10S977/847 , Y10S977/848 , Y10S977/849 , Y10S977/882 , Y10S977/948 , Y10T428/24058 , Y10T428/2918 , Y10T428/292 , Y10T428/30
摘要： The formation of arrays of fullerene nanotubes is described. A microscopic molecular array of fullerene nanotubes is formed by assembling subarrays of up to 106 fullerene nanotubes into a composite array.
摘要翻译：描述了富勒烯纳米管阵列的形成。通过将多达106个富勒烯纳米管的子阵列组装成复合阵列形成富勒烯纳米管的微观分子阵列。

73. 发明授权

US07923403B2 Method for preparing catalysts supported on carbon nanotubes networks 有权
标题翻译：制备负载在碳纳米管网络上的催化剂的方法
公开(公告)号：US07923403B2
公开(公告)日：2011-04-12
申请号：US11841733
申请日：2007-08-20
申请人： Jun Ma , David Moy , Alan Fischer , Robert Hoch
发明人： Jun Ma , David Moy , Alan Fischer , Robert Hoch
IPC分类号： B01J21/18 , B01J23/00 , B01J23/40 , B01J23/74
CPC分类号： B01J35/06 , B01J21/185 , B01J37/0009 , B01J37/0207 , B01J37/06 , B01J37/30 , B82Y30/00 , C07C209/36 , Y10S977/742 , Y10S977/745 , Y10S977/748 , Y10S977/75 , Y10S977/752 , C07C211/46
摘要： A new method for preparing a supported catalyst is herein provided. The supported catalyst comprises a carbon nanotube network structure containing metal catalysts. The metal catalyst may be loaded onto functionalized carbon nanotubes before forming the carbon nanotube network structure. Alternatively, the metal catalyst may be loaded onto the carbon nanotube network structures themselves.
摘要翻译：本文提供了一种制备负载型催化剂的新方法。载体催化剂包括含有金属催化剂的碳纳米管网络结构。在形成碳纳米管网络结构之前，可以将金属催化剂负载到官能化碳纳米管上。或者，金属催化剂可以被负载到碳纳米管网络结构本身上。

74. 发明申请

US20100285390A1 CATALYTIC MEMBRANES FOR CO OXIDATION USED IN FUEL CELLS 有权
标题翻译：用于燃料电池的氧化催化膜
公开(公告)号：US20100285390A1
公开(公告)日：2010-11-11
申请号：US12787118
申请日：2010-05-25
申请人： Di-Jia LIU , Junbing YANG , Xiaoping WANG
发明人： Di-Jia LIU , Junbing YANG , Xiaoping WANG
IPC分类号： H01M8/10 , H01M4/583 , H01M4/90 , H01M4/88
CPC分类号： H01M4/9008 , H01M4/9083 , H01M2008/1095 , Y10S977/742 , Y10S977/743 , Y10S977/744 , Y10S977/748 , Y10S977/749 , Y10S977/75 , Y10S977/752 , Y10S977/81
摘要： A fuel cell of the present invention comprises a cathode and an anode, one or both of the anode and the cathode including a catalyst comprising a bundle of longitudinally aligned graphitic carbon nanotubes including a catalytically active transition metal incorporated longitudinally and atomically distributed throughout the graphitic carbon walls of said nanotubes. The nanotubes also include nitrogen atoms and/or ions chemically bonded to the graphitic carbon and to the transition metal. Preferably, the transition metal comprises at least one metal selected from the group consisting of Fe, Co, Ni, Mn, and Cr.
摘要翻译：本发明的燃料电池包括阴极和阳极，阳极和阴极中的一个或两个包括催化剂，其包括纵向排列的石墨碳纳米管，其包含纵向和原子分布在整个石墨碳中的催化活性过渡金属所述纳米管的壁。纳米管还包括与石墨碳和过渡金属化学键合的氮原子和/或离子。优选地，过渡金属包含选自Fe，Co，Ni，Mn和Cr中的至少一种金属。

75. 发明申请

US20100276656A1 Devices Comprising Carbon Nanotubes, And Methods Of Forming Devices Comprising Carbon Nanotubes 有权
标题翻译：包含碳纳米管的装置以及包含碳纳米管的成形装置的方法
公开(公告)号：US20100276656A1
公开(公告)日：2010-11-04
申请号：US12235244
申请日：2008-09-22
申请人： Nishant Sinha , Gurtej S. Sandhu , Eugene Marsh , Neil Greeley , John Smythe
发明人： Nishant Sinha , Gurtej S. Sandhu , Eugene Marsh , Neil Greeley , John Smythe
IPC分类号： H01L45/00 , H01L21/02
CPC分类号： H01L51/0591 , B82Y10/00 , G11C13/025 , G11C2213/19 , H01L45/04 , H01L45/1226 , H01L45/1233 , H01L45/149 , H01L45/1608 , H01L45/1675 , H01L45/1683 , H01L51/0048 , Y10S977/712 , Y10S977/721 , Y10S977/745 , Y10S977/748 , Y10S977/764 , Y10S977/765 , Y10S977/781
摘要： Some embodiments include devices that contain bundles of CNTs. An undulating topography extends over the CNTs and within spaces between the CNTs. A global maximum lateral width is defined as the greatest lateral width of any of the spaces. A material is directly over the CNTs, with the material being a plurality of particles that have minimum cross-sectional equatorial widths exceeding the global maximum lateral width. Some embodiments include methods in which a plurality of crossed carbon nanotubes are formed over a semiconductor substrate. The CNTs form an undulating upper topography extending across the CNTs and within spaces between the CNTs. A global maximum lateral width is defined as the greatest lateral width of any of the spaces. A material is deposited over the CNTs, with the material being deposited as particles that have minimum cross-sectional equatorial widths exceeding the global maximum lateral width.
摘要翻译：一些实施方案包括含有CNT束的装置。起伏的形貌在碳纳米管之间和CNT之间的空间内延伸。全局最大横向宽度被定义为任何空间的最大横向宽度。材料直接在碳纳米管之上，其中材料是具有超过全局最大横向宽度的最小横截面赤道宽度的多个颗粒。一些实施例包括在半导体衬底上形成多个交叉碳纳米管的方法。 CNT形成延伸跨过CNT并且在CNT之间的空间内的波状上部形貌。全局最大横向宽度被定义为任何空间的最大横向宽度。材料沉积在CNT上，其中材料被沉积成具有超过全局最大横向宽度的最小横截面赤道宽度的颗粒。

76. 发明授权

US07794683B1 Method of making functionalized carbon nanotubes 失效
标题翻译：制备官能化碳纳米管的方法
公开(公告)号：US07794683B1
公开(公告)日：2010-09-14
申请号：US11417291
申请日：2006-04-14
申请人： Farhad Forohar , Craig Whitaker , William M. Koppes
发明人： Farhad Forohar , Craig Whitaker , William M. Koppes
IPC分类号： D01F9/12
CPC分类号： B82Y40/00 , B82Y30/00 , C01B32/174 , Y10S977/745 , Y10S977/748
摘要： The present invention relates to methods for the preparation of a carbon nanotube from an amino-functionalized carbon nanotube via an amino oxidation reaction. The carbon nanotube includes nitrogen based functional groups that are covalently attached to lattice carbons of the carbon nanotube, directly or via a chemical linker. The synthetic methods of the present invention allow the nitrogen based functional groups to be attached selectively to one of two distinct regions of the carbon nanotube, and thus enable the synthesis of a carbon nanotube having nitrogen based functional groups substantially concentrated on the ends and/or the sidewall of the carbon nanotube.
摘要翻译：本发明涉及通过氨基氧化反应由氨基官能化碳纳米管制备碳纳米管的方法。碳纳米管包括直接或通过化学连接体共价连接到碳纳米管的晶格碳上的氮基官能团。本发明的合成方法允许氮基官能团选择性地连接到碳纳米管的两个不同区域中的一个，从而能够合成具有基本上浓度在末端和/或碳纳米管的侧壁。

77. 发明授权

US07670831B2 Conductive carbon nanotubes dotted with metal and method for fabricating a biosensor using the same 失效
标题翻译：用金属点缀的导电性碳纳米管和使用其的生物传感器的制造方法
公开(公告)号：US07670831B2
公开(公告)日：2010-03-02
申请号：US10860544
申请日：2004-06-03
申请人： Sang Yup Lee , Hee Tae Jung , Dae Hwan Jung , Young Koan Ko , Do Hyun Kim , Seok Jae Lee , Byung Hun Kim , Jae Shin Lee
发明人： Sang Yup Lee , Hee Tae Jung , Dae Hwan Jung , Young Koan Ko , Do Hyun Kim , Seok Jae Lee , Byung Hun Kim , Jae Shin Lee
IPC分类号： C12M1/00 , C12Q1/00 , C12Q1/68 , C12M1/34
CPC分类号： G01N33/5438 , B82Y30/00 , C12Q1/001 , G01N33/551 , Y10S977/742 , Y10S977/745 , Y10S977/746 , Y10S977/747 , Y10S977/748 , Y10T156/10
摘要： Conductive carbon nanotubes (CNTs) obtained by dotting carboxylated CNTs with metal nanocrystals by chemical functional groups, are described, as well as a method for fabricating a pattern or film of the conductive CNTs which involves repeatedly depositing conductive CNTs on a substrate to achieve high surface density. A biosensor is described, in which bioreceptors that bind to target biomolecules are selectively attached to conductive CNTs or a conductive CNT pattern or film. By use of the conductive biosensor, various target biomaterials that bind or react with the bioreceptors can be precisely measured directly or by electrochemical signals at large amounts in one step. Additionally, the biosensor can be used for an electrical detection method capable of providing precise measurement results even with a small amount of source material.
摘要翻译：描述了通过化学官能团将金属纳米晶体的羧化CNT点缀的导电碳纳米管（CNT），以及用于制造导电CNT的图案或膜的方法，其包括在基板上反复沉积导电CNT以实现高表面密度。描述了生物传感器，其中结合靶生物分子的生物感受器选择性地连接到导电CNT或导电CNT图案或膜。通过使用导电生物传感器，可以在一个步骤中直接或通过大量的电化学信号精确测量与生物感受器结合或反应的各种靶生物材料。此外，生物传感器可以用于即使使用少量源材料也能够提供精确测量结果的电检测方法。

78. 发明申请

US20090295372A1 Nanoscopic electrode molecular probes 有权
标题翻译：纳米电极分子探针
公开(公告)号：US20090295372A1
公开(公告)日：2009-12-03
申请号：US12321823
申请日：2009-01-26
申请人： Predrag S. Krstic , Vincent Meunier
发明人： Predrag S. Krstic , Vincent Meunier
IPC分类号： G01R1/06
CPC分类号： G01N33/48721 , B82Y15/00 , Y10S977/748 , Y10S977/848 , Y10S977/941 , Y10S977/946
摘要： The present invention relates to a method and apparatus for enhancing the electron transport property measurements of a molecule when the molecule is placed between chemically functionalized carbon-based nanoscopic electrodes to which a suitable voltage bias is applied. The invention includes selecting a dopant atom for the nanoscopic electrodes, the dopant atoms being chemically similar to atoms present in the molecule, and functionalizing the outer surface and terminations of the electrodes with the dopant atoms.
摘要翻译：本发明涉及当将分子置于施加合适的电压偏置的化学官能化的碳基纳米级电极之间时，增强分子的电子传输性质测量的方法和装置。本发明包括为纳米级电极选择掺杂剂原子，掺杂剂原子与分子中存在的原子化学相似，并且用掺杂剂原子官能化电极的外表面和终端。

79. 发明申请

US20090291041A1 METHODS FOR SEPERATING CARBON NANOTUBES BY ENHANCING THE DENSITY DIFFERENTIAL 失效
标题翻译：通过增强密度差异来分离碳纳米管的方法
公开(公告)号：US20090291041A1
公开(公告)日：2009-11-26
申请号：US12124278
申请日：2008-05-21
申请人： Ali Afzali-Ardakani , James B. Hannon , Cherie R. Kagan , George S. Tulevski
发明人： Ali Afzali-Ardakani , James B. Hannon , Cherie R. Kagan , George S. Tulevski
IPC分类号： D01F9/12
CPC分类号： B03D3/00 , B82Y10/00 , B82Y30/00 , B82Y40/00 , C01B32/172 , C01B32/174 , C01B2202/28 , C01B2202/36 , C01P2004/13 , H01L51/0025 , H01L51/0049 , Y10S977/748 , Y10S977/751 , Y10S977/845 , Y10S977/847
摘要： A method for separating carbon nanotubes comprises: providing a mixture of carbon nanotubes; introducing an organic molecule having an end group capable of being chelated by a metal ion to the mixture of carbon nanotubes to covalently bond the organic molecule to at least one of the mixture of carbon nanotubes; and introducing a metal salt to the mixture of carbon nanotubes to chelate the end group of the organic molecule with the metal ion of the metal salt; and centrifuging the mixture of carbon nanotubes to cause the separation of the carbon nanotubes based on a density differential of the carbon nanotubes.
摘要翻译：分离碳纳米管的方法包括：提供碳纳米管的混合物; 将具有能够被金属离子螯合的端基的有机分子引入到碳纳米管的混合物中，以将有机分子共价键合到至少一种碳纳米管的混合物中; 并将金属盐引入到碳纳米管的混合物中以与金属盐的金属离子螯合有机分子的端基; 并将碳纳米管的混合物离心以根据碳纳米管的密度差来分离碳纳米管。

80. 发明申请

US20090280593A1 MATRIX NANOCOMPOSITE SENSING FILM FOR SAW/BAW BASED HYDROGEN SULPHIDE SENSOR AND METHOD FOR MAKING SAME 有权
标题翻译：基于SAW / BAW的硫化钠传感器的MATRIX纳米复合材料感光膜及其制造方法
公开(公告)号：US20090280593A1
公开(公告)日：2009-11-12
申请号：US12116724
申请日：2008-05-07
申请人： Bogdan-Catalin Serban , Stefan I. Voicu , Stefan-Dan Costea , Cornel P. Cobianu
发明人： Bogdan-Catalin Serban , Stefan I. Voicu , Stefan-Dan Costea , Cornel P. Cobianu
IPC分类号： H01L51/40 , C08K3/22
CPC分类号： G01N29/022 , G01N29/036 , G01N33/0044 , G01N2291/021 , G01N2291/0255 , G01N2291/0257 , G01N2291/0423 , G01N2291/0426 , Y10S977/748 , Y10S977/835 , Y10T29/49002
摘要： A method can be adapted for design and preparation of a matrix nanocomposite sensing film for hydrogen sulphide SAW/BAW detection at room temperature. A matrix nanocomposite can be synthesized by incorporating both single-wall and multi-wall thiolated carbon nanotubes into conductive organic polymers or ceramic nanocrystalline in a properly functionalized manner. A thin organic sensing film can be prepared based on the matrix nanocomposite. The matrix nanocomposite sensing film can be prepared on a surface of a SAW/BAW device by an additive process or a direct printing process. Finally, the sensing film can be consolidated by thermal annealing or laser annealing under ambient conditions in order to obtain the stable sensing film with higher sensitivity and electrical properties for a SAW/BAW based H2S sensor.
摘要翻译：一种方法可以适用于在室温下用于硫化氢SAW / BAW检测的基质纳米复合材料感测膜的设计和制备。可以通过将单壁和多壁硫醇化碳纳米管以适当的官能化方式并入导电有机聚合物或陶瓷纳米晶体中来合成基质纳米复合材料。可以基于基体纳米复合材料制备薄的有机传感膜。可以通过添加方法或直接印刷方法在SAW / BAW装置的表面上制备基质纳米复合材料感测膜。最后，感应膜可以在环境条件下通过热退火或激光退火进行固结，以获得具有更高灵敏度和电气性能的稳定感测膜，用于基于SAW / BAW的H2S传感器。

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