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    • 8. 发明授权
    • Paste and polymer transducer including coating film formed from same as electrolyte film or electrode films
    • 浆料和聚合物换能器,包括与电解质膜或电极膜形成的涂膜
    • US09035533B2
    • 2015-05-19
    • US13825727
    • 2011-09-21
    • Toshinori KatoKatsuei TakahashiTakashi Yamashita
    • Toshinori KatoKatsuei TakahashiTakashi Yamashita
    • H01G9/025C09D5/24C09D7/00C09D7/12H02N1/00H01B1/12H01B1/22H01B1/24C08F8/36C09J153/02
    • H01G9/025C08F8/36C09D5/24C09D7/20C09D7/69C09D7/70C09J153/025H01B1/122H01B1/22H01B1/24H02N1/00Y10S310/80
    • Paste which is prepared by any solid concentration and is excellent in terms of handleability, applicability, and storage stability; an electrolyte film or electrode film which is an even and highly flexible coating film formed in a desired thickness from the paste through a few repetitions of an application/drying step; and a polymer transducer which can be industrially and economically produced and shows excellent performance. The paste comprises: a solid polyelectrolyte (A) consisting of a block copolymer containing; a polymer block (a-1) which is represented by chemical formula (1) and a polymer block (a-2) which has substantially no ionic group and is rubbery at room temperature; an organic solvent (B) having a boiling point at 150° C. or higher; and non-dissociable particles (C) which are insoluble in the organic solvent (B) and have a major-axis length of 1-100 μm and an aspect ratio of 5 or less. The polymer transducer comprises an electrolyte film and a pair of electrode films between which the electrolyte film is sandwiched, wherein the electrolyte film or the pair of electrode films has been formed by drying and solidifying the paste into a film shape.
    • 通过任何固体浓度制备并且在可操作性,适用性和储存稳定性方面优异的浆料; 电解质膜或电极膜,其是通过几次重复的施加/干燥步骤,从浆料形成具有所需厚度的均匀且高度柔性的涂膜; 以及可在工业上和经济地制造并显示出优异性能的聚合物换能器。 该糊状物包括:由嵌段共聚物组成的固体聚电解质(A) 由化学式(1)表示的聚合物嵌段(a-1)和在室温下基本上不具有离子性基团且为橡胶状的聚合物嵌段(a-2) 沸点在150℃以上的有机溶剂(B) 和不溶解的有机溶剂(B)中的长度比为1〜100μm,长径比为5以下的非离解性粒子(C)。 聚合物换能器包括电解质膜和一对电极膜,在该对电极膜之间夹有电解质膜,其中电解质膜或一对电极膜通过干燥并固化成胶片形成。