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    • 9. 发明申请
    • METHOD AND APPARATUS FOR GROWING INDIUM OXIDE (IN2O3) SINGLE CRYSTALS AND INDIUM OXIDE (IN203) SINGLE CRYSTAL
    • 用于生长氧化铟(In2O3)单晶和氧化铟(IN203)单晶的方法和装置
    • US20150125717A1
    • 2015-05-07
    • US14394858
    • 2012-04-24
    • Zbigniew GalazkaRoberto FornariReinhard Uecker
    • Zbigniew GalazkaRoberto FornariReinhard Uecker
    • C30B30/04C30B29/16H01F1/01C30B11/00
    • C30B30/04C30B11/00C30B11/002C30B11/003C30B11/007C30B11/14C30B15/00C30B29/16H01F1/01Y10T117/1004
    • A method and apparatus for growing truly bulk In2O3 single crystals from the melt, as well as melt-grown bulk In2O3 single crystals are disclosed. The growth method comprises a controlled decomposition of initially non-conducting In2O3 starting material (23) during heating-up of a noble metal crucible (4) containing the In2O3 starting material (23) and thus increasing electrical conductivity of the In2O3 starting material with rising temperature, which is sufficient to couple with an electromagnetic field of an induction coil (6) through the crucible wall (24) around melting point of In2O3. Such coupling leads to an electromagnetic levitation of at least a portion (23.1) of the liquid In2O3 starting material with a neck (26) formation acting as crystallization seed. During cooling down of the noble metal crucible (4) with the liquid In2O3 starting material at least one bulk In2O3 single crystal (28.1, 28.2) is formed. We named this novel crystal growth method the “Levitation-Assisted Self-Seeding Crystal Growth Method”. The apparatus for growing bulk In2O3 single crystals from the melt comprises an inductively heated thermal system with a noble metal crucible (4) and evacuation passages (22, 22.1) for gaseous decomposition products of In2O3, while keeping very low temperature gradients. Various configurations of the induction coil (6), the noble metal crucible (4) and a lid (12) covering the crucible can be utilized to obtain very low temperature gradients, sufficient evacuation passages and a high levitation force. The electrical properties of the melt grown In2O3 single crystals can be modified in a wide range by at least one heat treatment in suitable atmospheres and appropriate temperatures.
    • 公开了一种用于从熔体中生长真正体积的In 2 O 3单晶以及熔融生长的本体In 2 O 3单晶的方法和装置。 生长方法包括在含有In 2 O 3起始材料(23)的贵金属坩埚(4)的加热期间初始不导电的In 2 O 3原料(23)的受控分解,从而增加In 2 O 3起始材料的电导率随着上升 温度足以与感应线圈(6)的电磁场通过坩埚壁(24)在In 2 O 3的熔点附近耦合。 这种耦合导致液体In 2 O 3起始材料的至少一部分(23.1)的电磁悬浮,其中颈部(26)形成作为结晶种子。 在使用液体In 2 O 3起始材料冷却贵金属坩埚(4)时,形成至少一个体积的In 2 O 3单晶(28.1,28.2)。 我们将这种新型晶体生长方法命名为“悬浮辅助自种晶体生长法”。 用于从熔体生长大块In2O3单晶的装置包括用于惰性​​金属坩埚(4)的感应加热热系统和用于In 2 O 3气态分解产物的排气通道(22,22.1),同时保持非常低的温度梯度。 可以利用感应线圈(6),贵金属坩埚(4)和覆盖坩埚的盖(12)的各种构造来获得非常低的温度梯度,足够的排气通道和高悬浮力。 熔体生长的In 2 O 3单晶的电性能可以在适当的气氛和合适的温度下通过至少一种热处理在宽范围内进行改性。